arXiv subjects

A. Malagoli

Publications and source records attributed to A. Malagoli.

8 recordsLinked to original sources

arXiv2017

Investigation of inter-grain critical current density in Bi2Sr2CaCu2O8+d superconducting wires and its relationship with the heat treatment protocol

In this work we investigate the effect of each different heat treatment stage in the fabrication of Bi2Sr2CaCu2O8+d superconducting wires on intra-grain and inter-grain superconducting properties. We measure magnetic critical temperature Tc values and transport critical current density Jc at temperatures from 4 K to 40 K and in fields up to 7 T. From an analysis of the temperature dependence of the self-field critical current density Jc(T) that takes into account weak link behavior and proximity effect, we study the grain boundaries (GB) transparency to supercurrents and we establish a relationship between GB oxygenation in the different steps of the fabrication process and the GB transparency to supercurrents. We find that grain boundary oxygenation starts in the first crystallization stage, but it becomes complete in the plateau at 836 °C and in slow cooling stages, and is further enhanced in the prolonged post annealing step. Such oxygenation makes GBs more conducting, thus improving the inter-grain Jc value and temperature dependence. On the other hand, from the inspection of the Tc values in the framework of the phase diagram dome, we find that grains are oxygenated already in the crystallization step up to the optimal doping, while successive slow cooling and post annealing treatments further enhance the degree of overdoping, especially if carried out in oxygen atmosphere rather than in air.

cond-mat.supr-con↗

arXiv2015

Role of heat and mechanical treatments in the fabrication of superconducting Ba0.6K0.4Fe2As2 ex-situ Powder-In-Tube tapes

Among the recently discovered Fe-based superconducting compounds, the (K,Ba)Fe2As2 phase is attracting large interest within the scientific community interested in conductor developments. In fact, after some years of development, critical current densities Jc of about 105 A/cm2 at fields up to more than 10 T have been obtained in powder in tube (PIT) processed wires and tapes. Here we explore the crucial points in the wire/tape fabrication by means of the ex-situ PIT method. We focus on scaling up processes which are crucial for the industrial fabrication. We analyzed the effects on the microstructure of the different heat and mechanical treatments. By an extensive microstructural analysis correlated with the transport properties we addressed the issues concerning the phase purity, the internal porosity and crack formation in the superconducting core region. Our best conductors with a filling factor of about 30 heat treated at 800 C exhibited Tc = 38 K the highest value measured in such kind of superconducting tape. The microstructure analysis shows clean and well connected grain boundaries but rather poor density: The measured Jc of about 3 x 10^4 A/cm2 in self-field is suppressed by less than a factor 7 at 7 T. Such not yet optimized Jc values can be accounted for by the reduced density while the moderate in-field suppression and a rather high n-factor confirm the high homogeneity and uniformity of these tapes.

cond-mat.supr-con↗

arXiv2015

Exploring the feasibility of Fe(Se,Te) conductors by ex-situ Powder-in-Tube method

In this work, the feasibility condition of Powder-In-Tube (PIT) processed wires of Fe(Se,Te) superconductor has been investigated. We faced several technical issues that are extensively described and discussed. In particular, we tested different metals and alloys as external sheaths (Cu, Ag, Nb, Ta, Ni, Fe, cupronickel, brass) concluding that the only sheath that does not affect substantially the Fe(Se,Te) phase is Fe. On the other hand, Fe sheath introduces excess iron in the Fe(Se,Te) phase, which affects the superconducting properties; we investigated the effects of the thermal treatments and of the powder composition in order to avoid it. The maximum Jc value obtained in our samples is 4*10^2 A/cm2, comparable to other published values of PIT conductors of the 11 family. We conclude that the fabrication of Fe(Se,Te) wires by PIT method is quite challenging and other approaches should be developed.

cond-mat.supr-con↗

arXiv2009

Study of the MgB2 grain size role in ex-situ multifilamentary wires with thin filaments

The MgB2 superconductor has already demonstrated its applicative potential, in particular for DC applications such as MRI magnets, thanks to the low costs of the raw materials and to its simple production process. However further efforts have still to be made in order to broaden its employment also towards the AC applications such as SFCL, motors, transformers. The main issues are related to the reduction of the AC losses. Some of these can be faced by obtaining multifilamentary conductors with a large number of very fine filaments and, in this context, the powders granulometry can play a crucial role. We have prepared MgB2 starting powders with different granulometries and by the ex-situ P.I.T method we have realized multifilamentary wires with a number of filaments up to 361 and an average size of each filament lowered down to 30 microns. In particular we have studied the relationship between grain and filament size in terms of transport properties and show that the optimization of this ratio is possible in order to obtain suitable conductors for AC industrial applications.

cond-mat.supr-con↗

arXiv2009

Upper critical field and fluctuation conductivity in the critical regime of doped SmFeAsO

We measure magnetotransport of F doped SmFeAsO samples up to 28T and we extract the upper critical fields, using different criteria. In order to circumvent the problem of criterion-dependence Hc2 values, we suggest a thermodynamic estimation of the upper critical field slope dHc2/dT based on the analysis of conductivity fluctuations in the critical regime. A high field slope as large as -12T/K is thus extracted for the optimally doped sample. We find evidence of a two-dimensional lowest Landau level (LLL) scaling for applied fields larger than mu_0H_LLL=8T. Finally, we estimate the coherence length values and we observe that they progressively increase with decreasing Tc. In all cases, the coherence length values along the c axis are smaller than the interplanar distance, confirming the two-dimensional nature of superconductivity in this compound.

cond-mat.supr-con↗

arXiv2008

Effect of grain refinement on enhancing critical current density and upper critical field in undoped MgB2 ex-situ tapes

Ex-situ Powder-In-Tube MgB2 tapes prepared with ball-milled, undoped powders showed a strong enhancement of the irreversibility field H*, the upper critical field Hc2 and the critical current density Jc(H) together with the suppression of the anisotropy of all of these quantities. Jc reached 104 A/cm2 at 4.2 K and 10 T, with an irreversibility field of about 14 T at 4.2 K, and Hc2 of 9 T at 25 K, high values for not-doped MgB2. The enhanced Jc and H* values are associated with significant grain refinement produced by milling of the MgB2 powder, which enhances grain boundary pinning, although at the same time also reducing the connectivity from about 12% to 8%. Although enhanced pinning and diminished connectivity are in opposition, the overall influence of ball milling on Jc is positive because the increased density of grains with a size comparable with the mean free path produces strong electron scattering that substantially increases Hc2, especially Hc2 perpendicular to the Mg and B planes.

cond-mat.supr-con↗

arXiv2004

Upper Critical Fields up to 60T in Dirty Magnesium Diboride Thin Films

Upper critical fields of several magnesium diboride thin films were measured up to 28 T at the Grenoble High Magnetic Field Laboratory (GHMFL) in Grenoble and up to 60 T at the Laboratoire National des Champs Magnetiques Pulses (LNCMP) in Toulouse. The samples were prepared both by pulsed laser deposition (PLD) and hybrid physical chemical vapour deposition (HPCVD) technique; they have critical temperatures between 29 and 39 K and normal state resistivities between 5 and 250 μohmcm; one of them has been intentionally doped with carbon. The measured critical fields were exceptionally high; we obtained the record value of 52 T at 4.2 K in the parallel orientation. In contrast with the BCS predictions, no saturation in Hc2 at low temperature was observed. Furthermore, films with a wide range of resistivity values showed similar critical fields, suggesting that in a two band system resistivity and Hc2 are not trivially linked. The high Hc2 values seem to be related with the expanded c-axis. The structure of one of the samples was carefully investigated with X-ray diffraction at European Synchrotron Radiation Facility (ESRF) in Grenoble.

cond-mat.supr-con↗

arXiv2001

Large transport critical currents in unsintered MgB2 superconducting tapes

The Powder-In-Tube process has been employed to fabricate tape-like conductors with a strong metallic sheath and based on the newly discovered MgB2 superconducting phase. Long superconducting tapes have been prepared by packing reacted MgB2 powders inside pure Ag, Cu and Ni tubes which are then cold worked by drawing and rolling. Such tapes have shown transport properties as good as bulk MgB2 samples sintered in high pressure and high temperature conditions. At 4.2 K, the highest critical current density of 100000 A/cm2 has been achieved on Nickel-sheathed single-filament conductors. A direct correlation between the sheath tensile strength and the critical current of the unsintered tape has been observed.

cond-mat.supr-con↗