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A. Metropoulos

Publications and source records attributed to A. Metropoulos.

2 recordsLinked to original sources

The non-symmetric ion-atom radiative processes in the stellar atmospheres

The aim of this research is to show that the processes of absorption charge-exchange and photo-association in $A+B^{+}$ collisions together with the processes of $AB^{+}$ photo-dissociation in the case of strongly non-symmetric ion-atom systems, significantly influence the opacity of stellar atmospheres in ultraviolet (UV) and extreme UV (EUV) region. In this work, the significance of such processes for solar atmosphere is studied. In the case of the solar atmosphere the absorption processes with $A=$ H and $B=$ Mg and Si are treated as dominant ones, but the cases $A=$ H and $B=$ Al and $A=$ He and $B=$ H are also taken into consideration. The choice of just these species is caused by the fact that, of the species relevant for the used solar-atmosphere model, it was only for them that we could determine the necessary characteristics of the corresponding molecular ions, i.e. the molecular potential curves and dipole matrix elements. It is shown that the efficiency of the examined non-symmetric processes within the rather wide corresponding quasi-molecular absorption bands in the far-UV and EUV regions is comparable and sometimes even greater than the intensity of the known symmetric ion-atom absorption processes, which are included now in the models of the solar atmosphere. Consequently, the presented results suggest that the non-symmetric ion-atom absorption processes also have to be included \emph{ab initio} in the corresponding models of the stellar atmospheres.

astro-ph.SR

Description of the Chemical Reaction Path in the HCO Molecule: A Combined Configuration Interaction and Tight-Binding Approach

It is demonstrated that the reaction path for a polyatomic molecule (applied to the HCO molecule) is easily calculated via ab-initio configuration interaction (CI) total energies. This Hamiltonian not only reproduces the CI calculations accurately and efficiently, but also effectively corrects any CI energies happening to erroneously converge to excited states.

physics.chem-ph