Detection of stratospheric HCN and tropospheric CO in Uranus and the implication for their sources
Uranus belongs to the category of ice giants that are common in our Galaxy. However, Uranus is one of the least explored and understood planets in our Solar System. This work aims to constrain the deep oxygen abundance of Uranus to better understand its formation. Another goal concerns the origin of exogeneous species, such as CO and HCN, found in the upper stratospheres of giant planets. We used spectral mapping observations of the CO (J=3-2) and HCN (J=4-3) rotational submillimeter lines obtained with ALMA in 2022 and 2024. We combined them with radiative transfer and thermochemical modeling to determine the tropospheric abundance of CO and the deep O/H ratio of Uranus. We used radiative transfer simulations with physical models of various sources of external CO and HCN to constrain the vertical and meridional distributions of these species and narrow down the nature of their external sources. We also applied a wind retrieval algorithm to search for zonal winds in the stratosphere of Uranus at the levels probed by the CO and HCN lines. We unambiguously detect tropospheric CO for the first time with a mole fraction of 5.8$\pm$0.3 ppb and stratospheric HCN with a mole faction of (1.8$\pm$0.2)$\times10^{-11}$ restricted to pressures lower than 0.2 mbar. Thermochemical calculations suggest that the deep interior of Uranus is enriched in oxygen with respect to the protoplanetary nebula by at least a factor of 52$^{+30}_{-20}$. We also find that the stratospheric CO is rather uniform over the observed latitudes and that the CO lines are best fit by an old comet impact model, in which a large comet hit the planet several centuries ago. CO therefore has a dual origin in Uranus. Finally, we do not detect stratospheric winds from these data, but the CO data indicate that zonal winds in the 10$^\circ$S-10$^\circ$N latitudinal range are likely retrograde at submillibar pressures.