arXiv subjects

A. N. Grigorenko

Publications and source records attributed to A. N. Grigorenko.

31 records · Page 2Linked to original sources

arXiv2010

Fluorographene: Two Dimensional Counterpart of Teflon

We report a stoichiometric derivative of graphene with a fluorine atom attached to each carbon. Raman, optical, structural, micromechanical and transport studies show that the material is qualitatively different from the known graphene-based nonstoichiometric derivatives. Fluorographene is a high-quality insulator (resistivity >10^12 Ohm per square) with an optical gap of 3 eV. It inherits the mechanical strength of graphene, exhibiting Young's modulus of 100 N/m and sustaining strains of 15%. Fluorographene is inert and stable up to 400C even in air, similar to Teflon.

cond-mat.mtrl-sci↗

arXiv2010

Surface Enhanced Raman Spectroscopy of Graphene

Surface enhanced Raman scattering (SERS) exploits surface plasmons induced by the incident field in metallic nanostructures to significantly increase the Raman intensity. Graphene provides the ideal prototype two dimensional (2d) test material to investigate SERS. Its Raman spectrum is well known, graphene samples are entirely reproducible, height controllable down to the atomic scale, and can be made virtually defect-free. We report SERS from graphene, by depositing arrays of Au particles of well defined dimensions on graphene/SiO$_2$(300nm)/Si. We detect significant enhancements at 633nm. To elucidate the physics of SERS, we develop a quantitative analytical and numerical theory. The 2d nature of graphene allows for a closed-form description of the Raman enhancement. This scales with the nanoparticle cross section, the fourth power of the Mie enhancement, and is inversely proportional to the tenth power of the separation between graphene and the nanoparticle. One consequence is that metallic nanodisks are an ideal embodiment for SERS in 2d.

cond-mat.mes-hall↗

arXiv2010

Spectroscopic ellipsometry of graphene and an exciton-shifted van Hove peak in absorption

We demonstrate that optical transparency of any two-dimensional system with a symmetric electronic spectrum is governed by the fine structure constant and suggest a simple formula that relates a quasi-particle spectrum to an optical absorption of such a system. These results are applied to graphene deposited on a surface of oxidized silicon for which we measure ellipsometric spectra, extract optical constants of a graphene layer and reconstruct the electronic dispersion relation near the K point using optical transmission spectra. We also present spectroscopic ellipsometry analysis of graphene placed on amorphous quartz substrates and report a pronounced peak in ultraviolet absorption at 4.6 eV because of a van Hove singularity in graphene's density of states. The peak is downshifted by 0.5 eV probably due to excitonic effects.

cond-mat.mes-hall↗

arXiv2010

Sensitivity of Collective Plasmon Modes of Gold Nanoresonators to Local Environment

We present the first experimental study of optical response of collective plasmon resonances in regular arrays of nanoresonators to local environment. Recently observed collective plasmon modes arise due to diffractive coupling of localised plasmons and yield almost an order of magnitude improvement in resonance quality. We measure the response of these modes to tiny variations of the refractive index of both gaseous and liquid media. We show that the phase sensitivity of the collective resonances can be more than two orders of magnitude better than the best amplitude sensitivity of the same nanodot array as well as an order of magnitude better than the phase sensitivity in SPR sensors.

cond-mat.mes-hall↗

arXiv2008

Universal Dynamic Conductivity and Quantized Visible Opacity of Suspended Graphene

We show that the optical transparency of suspended graphene is defined by the fine structure constant, alpha, the parameter that describes coupling between light and relativistic electrons and is traditionally associated with quantum electrodynamics rather than condensed matter physics. Despite being only one atom thick, graphene is found to absorb a significant (pi times alpha=2.3%) fraction of incident white light, which is a consequence of graphene's unique electronic structure. This value translates into universal dynamic conductivity G =e^2/4h_bar within a few percent accuracy.

cond-mat.mes-hall↗

arXiv2007

Negative Refractive Index in Artificial Metamaterials

We discuss optical constants in artificial metamaterials showing negative magnetic permeability and electric permittivity. Using effective field theory, we calculate effective permeability of nanofabricated media composed of pairs of identical gold nano-pillars with magnetic response in the visible spectrum.

physics.optics↗

arXiv2006

Reply to comment by A.V. Kildishev et al. [physics/0609234] and V. M. Shalaev et al. [Opt. Lett. 30, 3345 (2005)]

We discuss the claims of the comment at arXiv.org:physics/0609234. We show that A.V. Kildishev et al. misread our method of extracting of optical constants of nanostructured films. The theoretical calculations performed in the comment appear to be in a direct contradiction with an experiment. We demonstrate that the theoretical calculations suggested being free from ambiguities (V.M. Shalaev et al., Opt. Lett. 30, 3345 (2005)) require an additional experimental verification, which can be performed by observing physical effects of negative refraction.

physics.optics↗

arXiv2006

Room temperature tunneling anisotropic and collinear magnetoresistance

We report a room temperature tunneling anisotropic magnetoresistance in Co/Al2O3/NiFe junctions containing magnetic electrodes oxidized prior to forming the Al2O3 layer. A significant change in a tunnel magnetoresistance is observed when the layer magnetizations are rotated collinearly in the junction plane by an applied external field. The angular dependence of the tunneling anisotropic magnetoresistance could be explained by the presence of an antiferromagnetic oxide layer formed within the barrier.

cond-mat.other↗

arXiv2006

An antisymmetric plasmon resonance in coupled gold nanoparticles as a sensitive tool for detection of local index of refraction

A nanofabricated regular array of coupled gold nano-pillars is employed to detect local indices of refraction of different liquids using a shift of an antisymmetric plasmon resonance peak observed in the reflection spectra. The peak spectral position is found to be a unique function of the local refractive index for a wide range of indices. We discuss possible applications of the fabricated nanostructured arrays in bio and chemical sensors.

physics.optics↗

arXiv2006

Nanometric laser trapping based on nanostructured substrates

Laser trapping near the surface of a nanostructured substrate is demonstrated. Stable microbubbles with radii of 1-20micrometers have been created and manipulated with sub-micron precision by a focused laser beam in an immersion oil covering arrays of pairs of gold nanopillars deposited on a glass substrate. The threshold for bubble creation and trapping characteristics depended on near-field coupling of nanopillars. The nanometric laser tweezers showed giant trapping efficiency of Q~50 for the trapped microbubbles.

physics.optics↗

arXiv2005

Nanofabricated media with negative permeability at visible frequencies

We report a nanofabricated medium made of electromagnetically coupled pairs of gold dots with geometry carefully designed at a 10-nm level. The medium exhibits strong magnetic response at visible-light frequencies, including bands with negative μ. The magnetism arises due to the excitation of quadrupole plasmon resonances. Our approach shows for the first time the feasibility of magnetism at optical frequencies and paves a way towards magnetic and left-handed components for visible optics.

physics.optics↗

arXiv2002

Crossed-anisotropy films for magnetic tunnel junctions and magnetic memory applications

A prototype of magnetoresistive random access memory (MRAM) based on magnetic tunnel junctions (MTJ) was fabricated with crossed-anisotropy of magnetic layers on either side of the tunnelling barrier layer. It is demonstrated that the introduction of crossed-anisotropy results in smaller switching fields and better switching times compared to the conventional case of aligned anisotropies. The magnetoresistive properties of fabricated devices are in good agreement with the micromagnetic model.

cond-mat.mtrl-sci↗

arXiv2002

Optomagnetic composite medium with conducting nanoelements

A new type of metal-dielectric composites has been proposed that is characterised by a resonance-like behaviour of the effective permeability in the infrared and visible spectral ranges. This material can be referred to as optomagnetic medium. The analytical formalism developed is based on solving the scattering problem for considered inclusions with impedance boundary condition, which yields the current and charge distributions within the inclusions. The presence of the effective magnetic permeability and its resonant properties lead to novel optical effects and open new possible applications.

cond-mat.mes-hall↗