arXiv subjects

A. Pratt

Publications and source records attributed to A. Pratt.

9 recordsLinked to original sources

arXiv2026

Detection and characterisation of binary asteroid candidates through stellar occultations

Binary asteroids provide key access to fundamental parameters of Solar System remnants and planetary formations. However, the current knowledge of binary asteroids remains strongly biased by observational limitations, and main belt binary systems are still poorly characterised since current techniques preferentially detect either widely separated binaries close and bright systems. In this context, the high-precision astrometry of the Gaia mission has revealed a new population of candidate binaries exhibiting dynamical signatures consistent with unresolved companions. This work is part of the GaiaMoons program, and our aim with it was to characterise a sample of 357 potential binary asteroid targets and confirm or refute their binary nature. The properties of these candidates were derived from the high-precision photometric and astrometric observations provided by Gaia. We adopted stellar occultation as the observational method to study these targets. Between October 2023 and February 2026, we successfully carried out 165 observations for 101 targets. We subsequently analysed these events in the context of the available literature and previously reported observations. Thirty three observation led at least two positives for 24 objects that have undergone unprecedented occultation observation campaigns, with four objects showing indications of binary or contact binary features, namely 1127 Mimi, 35420 1998 AG6, 206 Hersilia, and 36882 2000 SW155. For the vast majority of these objects, the resulting dataset from all reduced observations provides unique physical and astrometric constraints, as they had never been observed through stellar occultations before. GaiaMoons illustrates how stellar occultation campaigns associated with Gaia observations generate a self-improving cycle to find new binary, thereby probing size and shape to constrain future observations.

astro-ph.EP↗

arXiv2024

Physical properties of trans-Neptunian object (143707) 2003 UY117 derived from stellar occultation and photometric observations

Trans-Neptunian objects (TNOs) are considered to be among the most primitive objects in our Solar System. Knowledge of their primary physical properties is essential for understanding their origin and the evolution of the outer Solar System. We predicted a stellar occultation by this TNO for 2020 October 23 UT and ran a specific campaign to investigate this event. We derived the projected profile shape and size from the occultation observations by means of an elliptical fit to the occultation chords. We also performed photometric observations of (143707) 2003 UY117 to obtain the absolute magnitude and the rotational period from the observed rotational light curve. Finally, we combined these results to derive the three-dimensional shape, volume-equivalent diameter, and geometric albedo for this TNO. From the stellar occultation, we obtained a projected ellipse with axes of $(282 \pm 18) \times (184 \pm 32)$ km. The area-equivalent diameter for this ellipse is $D_\textrm{eq,A} = 228 \pm 21$ km. From our photometric $R$ band observations, we derived an absolute magnitude of $H_V = 5.97 \pm 0.07$ mag using $V-R = 0.46 \pm 0.07$ mag, which was derived from a $V$ band subset of these data. The rotational light curve has a peak-to-valley amplitude of $\Delta m = 0.36 \pm 0.13$ mag. We find the most likely rotation period to be $P = 12.376 \pm 0.0033$ hours. By combining the occultation with the rotational light curve results and assuming a triaxial ellipsoid, we derived axes of $a \times b \times c = (332 \pm 24)$ km $\times$ $(216 \pm 24)$ km $\times$ $(180\substack{+28\\-24})$ km for this ellipsoid, and therefore a volume-equivalent diameter of $D_\textrm{eq,V} = 235 \pm 25$ km. Finally, the values for the absolute magnitude and for the area-equivalent diameter yield a geometric albedo of $p_V = 0.139 \pm 0.027$.

astro-ph.EP↗

arXiv2023

pH-dependent water permeability switching and its memory in 1T' MoS$_2$ membranes

Intelligent transport of molecular species across different barriers is critical for various biological functions and is achieved through the unique properties of biological membranes. An essential feature of intelligent transport is the ability to adapt to different external and internal conditions and also the ability to memorise the previous state. In biological systems, the most common form of such intelligence is expressed as hysteresis. Despite numerous advances made over previous decades on smart membranes, it is still a challenge for a synthetic membrane to display stable hysteretic behaviour for molecular transport. Here we show the memory effects and stimuli regulated transport of molecules through an intelligent phase changing MoS$_2$ membrane in response to external pH. We show that water and ion permeation through 1T' MoS$_2$ membranes follows a pH dependent hysteresis with a permeation rate that switches by a few orders of magnitude. We demonstrate that this phenomenon is unique to the 1T' phase of MoS$_2$ due to the presence of surface charge and exchangeable ions on the surface. We further demonstrate the potential application of this phenomenon in autonomous wound infection monitoring and pH-dependent nanofiltration. Our work significantly deepens understanding of the mechanism of water transport at the nanoscale and opens an avenue for developing neuromorphic applications, smart drug delivery systems, point-of-care diagnostics, smart sensors, and intelligent filtration devices.

cond-mat.soft↗

arXiv2022

Physical properties of the trans-Neptunian object (38628) Huya from a multi-chord stellar occultation

Within our international program to obtain accurate physical properties of trans-Neptunian objects (TNOs) we predicted a stellar occultation by the TNO (38628) Huya of the star Gaia DR2 4352760586390566400 (mG = 11.5 mag.) for March 18, 2019. After an extensive observational campaign, we updated the prediction and it turned out to be favorable to central Europe. Therefore, we mobilized half a hundred professional and amateur astronomers, and the occultation was finally detected from 21 telescopes located at 18 sites. This makes the Huya event one of the best ever observed stellar occultation by a TNO in terms of the number of chords. We determine accurate size, shape, and geometric albedo, and we also provide constraints on the density and other internal properties of this TNO. The 21 positive detections of the occultation by Huya allowed us to obtain well-separated chords which permitted us to fit an ellipse for the limb of the body at the moment of the occultation (i.e., the instantaneous limb) with kilometric accuracy. The projected semi-major and minor axes of the best ellipse fit obtained using the occultation data are (a', b') = (217.6 $\pm$ 3.5 km, 194.1 $\pm$ 6.1 km) with a position angle of the minor axis P' = 55.2 $\pm$ 9.1 degrees. From this fit, the projected area-equivalent diameter is 411.0 $\pm$ 7.3 km. This diameter is compatible with the equivalent diameter for Huya obtained from radiometric techniques (D = 406 $\pm$ 16 km). From this instantaneous limb, we obtained the geometric albedo for Huya (p$\rm_V$ = 0.079 $\pm$ 0.004) and we explored possible 3D shapes and constraints to the mass density for this TNO. We did not detect the satellite of Huya through this occultation, but the presence of rings or debris around Huya is constrained using the occultation data. We also derived an upper limit for a putative Pluto-like global atmosphere of about p$_{\rm surf}$ = 10 nbar.

astro-ph.EP↗

arXiv2022

Constraints on the structure and seasonal variations of Triton's atmosphere from the 5 October 2017 stellar occultation and previous observations

A stellar occultation by Neptune's main satellite, Triton, was observed on 5 October 2017 from Europe, North Africa, and the USA. We derived 90 light curves from this event, 42 of which yielded a central flash detection. We aimed at constraining Triton's atmospheric structure and the seasonal variations of its atmospheric pressure since the Voyager 2 epoch (1989). We also derived the shape of the lower atmosphere from central flash analysis. We used Abel inversions and direct ray-tracing code to provide the density, pressure, and temperature profiles in the altitude range $\sim$8 km to $\sim$190 km, corresponding to pressure levels from 9 μbar down to a few nanobars. Results. (i) A pressure of 1.18$\pm$0.03 μbar is found at a reference radius of 1400 km (47 km altitude). (ii) A new analysis of the Voyager 2 radio science occultation shows that this is consistent with an extrapolation of pressure down to the surface pressure obtained in 1989. (iii) A survey of occultations obtained between 1989 and 2017 suggests that an enhancement in surface pressure as reported during the 1990s might be real, but debatable, due to very few high S/N light curves and data accessible for reanalysis. The volatile transport model analysed supports a moderate increase in surface pressure, with a maximum value around 2005-2015 no higher than 23 μbar. The pressures observed in 1995-1997 and 2017 appear mutually inconsistent with the volatile transport model presented here. (iv) The central flash structure does not show evidence of an atmospheric distortion. We find an upper limit of 0.0011 for the apparent oblateness of the atmosphere near the 8 km altitude.

astro-ph.EP↗

arXiv2019

The trans-Neptunian object (84922) 2003 VS2 through stellar occultations

We present results from three world-wide campaigns that resulted in the detections of two single-chord and one multi-chord stellar occultations by the Plutino object (84922) 2003~VS$_2$. From the single-chord occultations in 2013 and 2014 we obtained accurate astrometric positions for the object, while from the multi-chord occultation on November 7th, 2014, we obtained the parameters of the best-fitting ellipse to the limb of the body at the time of occultation. We also obtained short-term photometry data for the body in order to derive its rotational phase during the occultation. The rotational light curve present a peak-to-peak amplitude of 0.141 $\pm$ 0.009 mag. This allows us to reconstruct the three-dimensional shape of the body, with principal semi-axes $a = 313.8 \pm 7.1$ km, $b = 265.5^{+8.8}_{-9.8}$ km, and $c = 247.3^{+26.6}_{-43.6}$ km, which is not consistent with a Jacobi triaxial equilibrium figure. The derived spherical volume equivalent diameter of $548.3 ^{+29.5}_{-44.6}$ km is about 5\% larger than the radiometric diameter of 2003~VS$_2$ derived from Herschel data of $523 \pm 35$ km, but still compatible with it within error bars. From those results we can also derive the geometric albedo ($0.123 ^{+0.015}_{-0.014}$) and, under the assumption that the object is a Maclaurin spheroid, the density $ρ= 1400^{+1000}_{-300}$ for the plutino. The disappearances and reappearances of the star during the occultations do not show any compelling evidence for a global atmosphere considering a pressure upper limit of about 1 microbar for a pure nitrogen atmosphere, nor secondary features (e.g. rings or satellite) around the main body.

astro-ph.EP↗

arXiv2018

Electrically controlled water permeation through graphene oxide membranes

Developing 'smart' membranes that allow precise and reversible control of molecular permeation using external stimuli would be of intense interest for many areas of science: from physics and chemistry to life-sciences. In particular, electrical control of water permeation through membranes is a long-sought objective and is of crucial importance for healthcare and related areas. Currently, such adjustable membranes are limited to the modulation of wetting of the membranes and controlled ion transport, but not the controlled mass flow of water. Despite intensive theoretical work yielding conflicting results, the experimental realisation of electrically controlled water permeation has not yet been achieved. Here we report electrically controlled water permeation through micrometre-thick graphene oxide (GO) membranes. By controllable electric breakdown, conductive filaments are created in the GO membrane. The electric field concentrated around such current carrying filaments leads to controllable ionisation of water molecules in graphene capillaries, allowing precise control of water permeation: from ultrafast permeation to complete blocking. Our work opens up an avenue for developing smart membrane technologies and can revolutionize the field of artificial biological systems, tissue engineering and filtration.

cond-mat.mtrl-sci↗

arXiv2017

Ultrathin graphene-based membrane with precise molecular sieving and ultrafast solvent permeation

Graphene oxide (GO) membranes continue to attract intense interest due to their unique molecular sieving properties combined with fast permeation rates. However, the membranes' use has been limited mostly to aqueous solutions because GO membranes appear to be impermeable to organic solvents, a phenomenon not fully understood yet. Here, we report efficient and fast filtration of organic solutions through GO laminates containing smooth two-dimensional (2D) capillaries made from flakes with large sizes of ~ 10-20 micron. Without sacrificing their sieving characteristics, such membranes can be made exceptionally thin, down to ~ 10 nm, which translates into fast permeation of not only water but also organic solvents. We attribute the organic solvent permeation and sieving properties of ultrathin GO laminates to the presence of randomly distributed pinholes that are interconnected by short graphene channels with a width of 1 nm. With increasing the membrane thickness, the organic solvent permeation rates decay exponentially but water continues to permeate fast, in agreement with previous reports. The application potential of our ultrathin laminates for organic-solvent nanofiltration is demonstrated by showing >99.9% rejection of various organic dyes with small molecular weights dissolved in methanol. Our work significantly expands possibilities for the use of GO membranes in purification, filtration and related technologies.

physics.app-ph↗

arXiv2008

Hydrogen Dissociation and Diffusion on Ni and Ti -doped Mg(0001) Surfaces

It is well known, both theoretically and experimentally, that alloying MgH$_2$ with transition elements can significantly improve the thermodynamic and kinetic properties for H$_2$ desorption, as well as the H$_2$ intake by Mg bulk. Here we present a density functional theory investigation of hydrogen dissociation and surface diffusion over Ni-doped surface, and compare the findings to previously investigated Ti-doped Mg(0001) and pure Mg(0001) surfaces. Our results show that the energy barrier for hydrogen dissociation on the pure Mg(0001) surface is high, while it is small/null when Ni/Ti are added to the surface as dopants. We find that the binding energy of the two H atoms near the dissociation site is high on Ti, effectively impeding diffusion away from the Ti site. By contrast, we find that on Ni the energy barrier for diffusion is much reduced. Therefore, although both Ti and Ni promote H$_2$ dissociation, only Ni appears to be a good catalyst for Mg hydrogenation, allowing diffusion away from the catalytic sites. Experimental results corroborate these theoretical findings, i.e. faster hydrogenation of the Ni doped Mg sample as opposed to the reference Mg or Ti doped Mg.

cond-mat.mtrl-sci↗