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A. S. Usenko

Publications and source records attributed to A. S. Usenko.

6 recordsLinked to original sources

Adsorption-induced surface normal relaxation of a solid adsorbent

We investigate adsorption of a gas on the flat surface of a solid deformable adsorbent taking into account thermal fluctuations and analyze in detail the effect of thermal fluctuations on the adsorbent deformation in adsorption. The condition for coexistence of two states of a bistable system of adsorbed particles is derived. We establish the specific properties of the adsorption-induced surface normal relaxation of an adsorbent caused by thermal fluctuations. The mean transition times between two stable states of the bistable system are derived in the parabolic approximation and in the general case.

cond-mat.mtrl-sci

Competitive Adsorption of a Two-Component Gas on a Deformable Adsorbent

We investigate the competitive adsorption of a two-component gas on the surface of an adsorbent whose adsorption properties vary in adsorption due to the adsorbent deformation. The essential difference of adsorption isotherms for a deformable adsorbent both from the classical Langmuir adsorption isotherms of a two-component gas and from the adsorption isotherms of a one-component gas taking into account variations in adsorption properties of the adsorbent in adsorption is obtained. We establish bistability and tristability of the system caused by variations in adsorption properties of the adsorbent in competitive adsorption of gas particles on it. Conditions under which adsorption isotherms of a binary gas mixture have two stable asymptotes are derived. It is shown that the specific features of the behavior of the system under study can be described in terms of a potential of the known explicit form.

cond-mat.mtrl-sci

Adsorption on a Surface with Varying Properties

We propose a self-consistent model taking into account variations in adsorption properties of the adsorbent surface in the process of adsorption--desorption of molecules of gas on it. We introduce a dimensionless coupling parameter that characterizes the interaction of an adsorbed molecule with polarized medium. It is established that the system can be bistable if the coupling parameter is greater than a critical value and the concentration of gas belongs to a certain interval. We show that the adsorption isotherms obtained within the framework of the proposed model essentially differ from the Langmuir isotherms and establish that the Zeldovich hysteresis is possible. The kinetics of the surface coverage is analyzed in detail. We show that taking account of variations in adsorption properties of the surface in the process of adsorption--desorption leads to new phenomena: a "quasistationary" state in the case of the overdamped approximation and self-oscillations of the system in the general case.

cond-mat.mtrl-sci

Retarded Many-Sphere Hydrodynamic Interactions in a Viscous Fluid

An alternative method is suggested for the description of the velocity and pressure fields in an unbounded incompressible viscous fluid induced by an arbitrary number of spheres moving and rotating in it. Within the framework of this approach, we obtain the general relations for forces and torques exerted by the fluid on the spheres. The behavior of the translational, rotational, and coupled friction and mobility tensors in various frequency domains are analyzed up to the terms of the third order in the dimensionless parameter equal to the ratio of a typical radius of a sphere to the penetration depth of transverse waves and a certain power of the dimensionless parameter equal to the ratio of a typical radius of a sphere to the distance between the centers of two spheres. We establish that the retardation effects can essentially affect the character of the hydrodynamic interactions between the spheres.

physics.flu-dyn

Velocity and Pressure Fields Induced by Spheres in an Unbounded Fluid

We propose a procedure for the determination of the time-dependent velocity and pressure fields of an unbounded incompressible viscous fluid in an external force field induced by an arbitrary number of spheres moving and rotating in it as well as the forces and torques exerted by the fluid on the particles. Within the completely linearized scheme, we express the velocity and pressure fields of the fluid in terms of induced surface force densities and derive the explicit form for all quantities contained in these relations not imposing any additional restrictions on the size of particles, distances between them, and the frequency range. We show the incorrectness of similar results obtained earlier by several authors because these results are expressed in terms of nonexistent inverse tensors. We explain the reasons leading to this and propose a procedure for the elimination of divergent quantities. In the stationary case, using the proposed procedure, we obtained the translational, rotational, and coupled friction and mobility tensors for a system containing an arbitrary number of spheres up to, respectively, the second, forth, and third orders in the dimensionless parameter equal to the ratio of a typical radius of a sphere to a typical distance between two spheres. In various particular cases, the results obtained in the present paper agree with the well-known results derived by other methods.

physics.flu-dyn

Third Boundary-Value Problem of the Heat Conduction Equation for a System with Plane-Parallel Boundaries

We obtained a new representation of a solution of the heat conduction equation with boundary condition of the third kind for a layer. The result is presented as a superposition of fundamental solutions for an unbounded system with variable coefficients, the explicit form of which is given. We consider the well-known problem of the evolution of the temperature field initially uniformly distributed in a layer. The distribution of the temperature field is represented in terms of the obtained functions.

math-ph