Measurement of the scalar polarizability within the 5P1/2-6S1/2, 410 nm transition in atomic indium
We have completed a new measurement of the Stark shift in 115In within the 410 nm 5P1/2- 6S1/2 transition. We measure the Stark shift constant to be kS= - 122.92(33)kHz/(kV/cm)^2, corresponding to a difference in the 6S1/2 and 5P1/2 state polarizabilities, Δα_0, of 1000.2 (2.7) a.u.(in atomic units). This result is a factor of 30 more precise than previous measurements and is in excellent agreement with a new theoretical value based on an ab initio calculation of the wave functions in this three-valence-electron system. The measurement was performed in an indium atomic beam apparatus, used a GaN laser diode system, and exploited an FM spectroscopy technique to extract laser transmission spectra under conditions where our interaction region optical depth was typically less than 10^-3.