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A. Thaler

Publications and source records attributed to A. Thaler.

At least 37 records · Page 2Linked to original sources

Effect of 3d-doping on the electronic structure of BaFe2As2

The electronic structure of BaFe2As2 doped with Co, Ni, and Cu has been studied by a variety of experimental and theoretical methods, but a clear picture of the dopant 3d states has not yet emerged. Herein we provide experimental evidence of the distribution of Co, Ni, and Cu 3d states in the valence band. We conclude that the Co and Ni 3d states provide additional free carriers to the Fermi level, while the Cu 3d states are found at the bottom of the valence band in a localized 3d10 shell. These findings help shed light on why superconductivity can occur in BaFe2As2 doped with Co and Ni but not Cu.

cond-mat.mtrl-sci↗

NMR investigation of vortex dynamics in Ba(Fe0.93Rh0.07)2As2 superconductor

75As NMR spin-lattice relaxation (1/T1) and spin-echo decay (1/T2) rate measurements were performed in a single crystal of Ba(Fe0.93Rh0.07)2As2 superconductor. Below the superconducting transition temperature Tc, when the magnetic field H is applied along the c axes, a peak in both relaxation rates is observed. Remarkably that peak is suppressed for H || ab. Those maxima in 1/T1 and 1/T2 have been ascribed to the flux lines lattice motions and the corresponding correlation times and pinning energy barriers have been derived on the basis of an heuristic model. Further information on the flux lines motion was derived from the narrowing of 75As NMR linewidth below Tc and found to be consistent with that obtained from 1/T2 measurements. All the experimental results are described in the framework of thermally activated vortices motions.

cond-mat.supr-con↗

What controls the phase diagram and superconductivity in Ru substituted BaFe$_2$As$_2$?

We use high resolution angle-resolved photoemission to study the electronic structure of the iron based high-temperature superconductors Ba(Fe$_{1-x}$Ru$_x$)$_2$As$_2$ as a function of Ru concentration. We find that substitution of Ru for Fe is isoelectronic, i. e., it does not change the value of the chemical potential. More interestingly, there are no measured, significant changes in the shape of the Fermi surface or in the Fermi velocity over a wide range of substitution levels ($0<x<0.55$). Given that the suppression of the antiferromagnetic and structural phase has been associated with the emergence of the superconducting state, Ru substitution must achieve this via a mechanism that does not involve changes of the Fermi surface. We speculate that this mechanism relies on magnetic dilution which leads to the reduction of the effective Stoner enhancement.

cond-mat.supr-con↗

Effect of tensile stress on the in-plane resistivity anisotropy in BaFe2As2

The effect of uniaxial tensile stress and the resultant strain on the structural/magnetic transition in the parent compound of the iron arsenide superconductor, BaFe$_2$As$_2$, is characterized by temperature-dependent electrical resistivity, x-ray diffraction and quantitative polarized light imaging. We show that strain induces a measurable uniaxial structural distortion above the first-order magnetic transition and significantly smears the structural transition. This response is different from that found in another parent compound, SrFe$_2$As$_2$, where the coupled structural and magnetic transitions are strongly first order. This difference in the structural responses explains the in-plain resistivity anisotropy above the transition in BaFe$_2$As$_2$. This conclusion is supported by the Ginzburg-Landau - type phenomenological model for the effect of the uniaxial strain on the resistivity anisotropy.

cond-mat.supr-con↗

Physical and magnetic properties of Ba(Fe_(1-x)Mn_x)_2As_2 single crystals

Single crystals of Ba(Fe_(1-x)Mn_x)_2As_2, 0 0.1-0.2. Our measurements show that whereas the structural/magnetic phase transition found in pure BaFe_2As_2 at 134 K is initially suppressed by Mn substitution, superconductivity is not observed at any substitution level. Although the effect of hydrostatic pressure up to 20 kbar in the parent BaFe_2As_2 compound is to suppress the structural/magnetic transition at the approximate rate of 0.9 K/kbar, the effects of pressure and Mn substitution in the x=0.102 compound are not cumulative. Phase diagrams of transition temperature versus substitution concentration, x, based on electrical transport, magnetization and thermopower measurements have been constructed and compared to those of the Ba(Fe_(1-x)TM_x)_2As_2 (TM=Co and Cr) series.

cond-mat.supr-con↗

Gap-like feature in the normal state of $\bf{X(Fe_{1-x}Co_x)_2As_2}$, $\bf{X=Ba,Sr}$ and $\bf{Fe_{1+y}Te}$ revealed by Point Contact Spectroscopy

Point contact spectroscopy reveals a gap-like feature above the magnetic and structural transition temperatures for underdoped $Ba(Fe_{1-x}Co_x)_2As_2$, $SrFe_2As_2$ and $Fe_{1+y}Te$. The conductance spectrum starts showing an enhancement at temperatures as high as 177 K for $BaFe_2As_2$ ($T_N$ $\sim$ 132 K) and 250 K for $SrFe_2As_2$ ($T_N$ $\sim$ 192 K). Possible origins for this enhancement are discussed in light of recent experimental claims of nematicity in these materials. We construct a modified phase diagram for Co-doped Ba122 showing a gap-like feature existing above $T_N$ and $T_S$ for the underdoped regime.

cond-mat.supr-con↗

Combined effects of pressure and Ru substitution on BaFe2As2

The ab-plane resistivity of Ba(Fe1-xRux)2As2 (x = 0.00, 0.09, 0.16, 0.21, and 0.28) was studied under nearly hydrostatic pressures, up to 7.4 GPa, in order to explore the T-P phase diagram and to compare the combined effects of iso-electronic Ru substitution and pressure. The parent compound BaFe2As2 exhibits a structural/magnetic phase transition near 134 K. At ambient pressure, progressively increasing Ru concentration suppresses this phase transition to lower temperatures at the approximate rate of ~5 K/% Ru and is correlated with the emergence of superconductivity. By applying pressure to this system, a similar behavior is seen for each concentration: the structural/magnetic phase transition is further suppressed and superconductivity induced and ultimately, for larger x Ru and P, suppressed. A detailed comparison of the T-P phase diagrams for all Ru concentrations shows that 3 GPa of pressure is roughly equivalent to 10% Ru substitution. Furthermore, due to the sensitivity of Ba(Fe1-xRux)2As2 to pressure conditions, the melting of the liquid media, 4 : 6 light mineral oil : n-pentane and 1 : 1 iso-pentane : n-pentane, used in this study could be readily seen in the resistivity measurements. This feature was used to determine the freezing curves for these media and infer their room temperature, hydrostatic limits: 3.5 and 6.5 GPa, respectively.

cond-mat.supr-con↗

Systematics of the temperature-dependent inter-plane resistivity in Ba(Fe$_{1-x}$T$_x$)$_2$As$_2$ with T= Rh, Ni, and Pd

Temperature-dependent inter-plane resistivity, $ρ_c(T)$, was measured systematically as a function of transition metal substitution in the iron-arsenide superconductors Ba(Fe$_{1-x}$T$_x$)$_2$As$_2$, $T$= Ni, Pd, Rh. The data are compared with the behavior found in Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$, revealing resistive signatures of pseudogap. In all compounds we find resistivity crossover at a characteristic pseudogap temperature $T^*$ from non-metallic to metallic temperature dependence on cooling. Suppression of $T^*$ proceeds very similar in cases of Ni and Pd doping and much faster than in similar cases of Co and Rh doping. In cases of Co and Rh doping an additional minimum in the temperature-dependent $ρ_c$ emerges for high dopings, when superconductivity is completely suppressed. These features are consistent with the existence of a charge gap covering part of the Fermi surface. The part of the Fermi surface affected by this gap is notably larger for Ni and Pd doped compositions than in Co and Rh doped compounds.

cond-mat.supr-con↗

Incommensurate spin-density wave order in electron-doped BaFe2As2 superconductors

Neutron diffraction studies of Ba(Fe[1-x]Co[x])2As2 reveal that commensurate antiferromagnetic order gives way to incommensurate magnetic order for Co compositions between 0.056 < x < 0.06. The incommensurability has the form of a small transverse splitting (0, +-e, 0) from the nominal commensurate antiferromagnetic propagation vector Q[AFM] = (1, 0, 1) (in orthorhombic notation) where e = 0.02-0.03 and is composition dependent. The results are consistent with the formation of a spin-density wave driven by Fermi surface nesting of electron and hole pockets and confirm the itinerant nature of magnetism in the iron arsenide superconductors.

cond-mat.supr-con↗

Character of the structural and magnetic phase transitions in the parent and electron doped BaFe2As2 compounds

We present a combined high-resolution x-ray diffraction and x-ray resonant magnetic scattering (XRMS) study of as-grown BaFe2As2. The structural/magnetic transitions must be described as a two-step process. At T_S = 134.5 K we observe the onset of a second-order structural transition from the high-temperature paramagnetic tetragonal structure to a paramagnetic orthorhombic phase, followed by a discontinuous step in the structural order parameter that is coincident with a first-order antiferromagnetic (AFM) transition at T_N = 133.75 K. These data, together with detailed high-resolution x-ray studies of the structural transition in lightly doped Ba(Fe{1-x}Co{x})2As2 and Ba(Fe{1-x}Rh{x})2As2 compounds, show that the structural and AFM transitions do, in fact, occur at slightly different temperatures in the parent BaFe2As2 compound, and evolve towards split secondorder transitions as the doping concentration is increased. We estimate the composition for the tricritical point for Co-doping and employ a mean-field approach to show that our measurements can be explained by the inclusion of an anharmonic term in the elastic free energy and magneto-elastic coupling in the form of an emergent Ising-nematic degree of freedom.

cond-mat.supr-con↗

In-plane anisotropy of electrical resistivity in the strain-detwinned SrFe2As2

Intrinsic, in-plane anisotropy of electrical resistivity was studied on mechanically detwinned single crystals of SrFe$_2$As$_2$ above and below the temperature of the coupled structural/magnetic transition, $T_{\textrm{TO}}$. Resistivity is smaller for electrical current flow along the orthorhombic $a_o$ direction (direction of antiferromagnetically alternating magnetic moments) and is larger for transport along the $b_o$ direction (direction of ferromagnetic chains), which is similar to CaFe$_2$As$_2$ and BaFe$_2$As$_2$ compounds. A strongly first order structural transition in SrFe$_2$As$_2$ was confirmed by high-energy x-ray measurements, with the transition temperature, and character unaffected by moderate strain. For small strain levels, which are just sufficient to detwin the sample, we find a negligible effect on the resistivity above $T_{\textrm{TO}}$. With the increase of strain, the resistivity anisotropy starts to develop above $T_{\textrm{TO}}$, clearly showing the relation of anisotropy to an anomalously strong response to strain. Our study suggests that electronic nematicity cannot be observed in the FeAs based compounds in which the structural transition is strongly first order.

cond-mat.supr-con↗

Magnetic ordering and structural distortion in Ru doped BaFe2As2 single crystals studied by Neutron and X-ray diffraction

We present a systematic investigation of the antiferromagnetic ordering and structural distortion for the series of Ba(Fe{1-x}Ru{x})2As2 compounds (0 <= x <= 0.246). Neutron and x-ray diffraction measurements demonstrate that, unlike for the electron-doped compounds, the structural and magnetic transitions remain coincident in temperature. Both the magnetic and structural transitions are gradually suppressed with increased Ru concentration and coexist with superconductivity. For samples that are superconducting, we find strong competition between superconductivity, the antiferromagnetic ordering, and the structural distortion.

cond-mat.supr-con↗

Commensurate antiferromagnetic ordering in Ba(Fe{1-x}Co{x})2As2 determined by x-ray resonant magnetic scattering at the Fe K-edge

We describe x-ray resonant magnetic diffraction measurements at the Fe K-edge of both the parent BaFe2As2 and superconducting Ba(Fe0.953Co0.047)2As2 compounds. From these high-resolution measurements we conclude that the magnetic structure is commensurate for both compositions. The energy spectrum of the resonant scattering is in reasonable agreement with theoretical calculations using the full-potential linear augmented plane wave method with a local density functional.

cond-mat.supr-con↗

Antiferromagnetic ordering in the absence of a structural distortion in Ba(Fe{1-x}Mn{x})2As2

Neutron and x-ray diffraction studies of Ba(Fe{1-x}Mn{x})2As2 for low doping concentrations (x <= 0.176) reveal that at a critical concentration, 0.102 < x < 0.118, the tetragonal-to-orthorhombic transition abruptly disappears whereas magnetic ordering with a propagation vector of (1/2 1/2 1) persists. Among all of the iron arsenides this observation is unique to Mn-doping, and unexpected because all models for "stripe-like" antiferromagnetic order anticipate an attendant orthorhombic distortion due to magnetoelastic effects. We discuss these observations and their consequences in terms of previous studies of Ba(Fe{1-x}TM{x})2As2 compounds (TM = Transition Metal), and models for magnetic ordering in the iron arsenide compounds.

cond-mat.supr-con↗

Thermoelectric power of Ba(Fe1-xRux)2As2 and Ba(Fe1-xCox)2As2: possible changes of Fermi surface with and without changes in electron count

Temperature-dependent, in-plane, thermoelectric power (TEP) data are presented for Ba(Fe1-xRux)2As2 (0 < x < 0.36) single crystals. The previously outlined x - T phase diagram for this system is confirmed. The analysis of TEP evolution with Ru-doping suggests significant changes in the electronic structure, correlations and/or scattering occurring near ~7% and ~30% of Ru-doping levels. These results are compared with an extended set of TEP data for the electron-doped Ba(Fe1-xCox)2As2 series.

cond-mat.supr-con↗

Physical and magnetic properties of Ba(Fe$_{1-x}$Ru$_x$)$_2$As$_2$ single crystals

Single crystals of Ba(Fe$_{1-x}$Ru$_x$)$_2$As$_2$, $x<0.37$, have been grown and characterized by structural, magnetic and transport measurements. These measurements show that the structural/magnetic phase transition found in pure BaFe$_2$As$_2$ at 134 K is suppressed monotonically by Ru doping, but, unlike doping with TM=Co, Ni, Cu, Rh or Pd, the coupled transition seen in the parent compound does not detectably split into two separate ones. Superconductivity is stabilized at low temperatures for $x>0.2$ and continues through the highest doping levels we report. The superconducting region is dome like, with maximum T$_c$ ($\sim16.5$ K) found around $x\sim 0.29$. A phase diagram of temperature versus doping, based on electrical transport and magnetization measurements, has been constructed and compared to those of the Ba(Fe$_{1-x}$TM$_x$)$_2$As$_2$ (TM=Co, Ni, Rh, Pd) series as well as to the temperature-pressure phase diagram for pure BaFe$_2$As$_2$. Suppression of the structural/magnetic phase transition as well as the appearance of superconductivity is much more gradual in Ru doping, as compared to Co, Ni, Rh and Pd doping, and appears to have more in common with BaFe$_2$As$_2$ tuned with pressure; by plotting $T_S/T_m$ and $T_c$ as a function of changes in unit cell dimensions, we find that changed in the $c/a$ ratio, rather than changes in $c$, $a$ or V, unify the $T(p)$ and $T(x)$ phase diagrams for BaFe$_2$As$_2$ and Ba(Fe$_{1-x}$Ru$_x$)$_2$As$_2$ respectively.

cond-mat.supr-con↗

Temperature-doping phase diagrams for Ba(Fe1-xTMx)2As2(TM=Ni, Cu, Cu / Co) single crystals

Microscopic, structural, transport and thermodynamic measurements of single crystalline Ba(Fe1-xTMx)2As2 (TM = Ni and Cu) series, as well as two mixed TM = Cu / Co series, are reported. All the transport and thermodynamic measurements indicate that the structural and magnetic phase transitions at 134 K in pure BaFe2As2 are monotonically suppressed and increasingly separated in a similar manner by these dopants. In the Ba(Fe1-xNix)2As2 (x =< 0.072), superconductivity, with Tc up to 19 K, is stabilized for 0.024 =< x =< 0.072. In the Ba(Fe1-xCux)2As2 (x =< 0.356) series, although the structural and magnetic transitions are suppressed, there is only a very limited region of superconductivity: a sharp drop of the resistivity to zero near 2.1 K is found only for the x = 0.044 samples. In the Ba(Fe1-x-yCoxCuy)2As2 series, superconductivity, with Tc values up to 12 K (x ~ 0.022 series) and 20 K (x ~ 0.047 series), is stabilized. Quantitative analysis of the detailed temperature-dopant concentration (T-x) and temperature-extra electrons (T-e) phase diagrams of these series shows that there exists a limited range of the number of extra electrons added, inside which the superconductivity can be stabilized if the structural and magnetic phase transitions are suppressed enough. Moreover, comparison with pressure-temperature phase diagram data, for samples spanning the whole doping range, further reenforces the conclusion that suppression of the structural / magnetic phase transition temperature enhances Tc on the underdoped side, but for the overdoped side Tcmax is determined by e. Therefore, by choosing the combination of dopants that are used, we can adjust the relative positions of the upper phase lines (structural and magnetic phase transitions) and the superconducting dome to control the occurrence and disappearance of the superconductivity in transition metal, electron-doped BaFe2As2.

cond-mat.supr-con↗

$c$-axis charge gap and its critical point in the heavily doped Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$

Temperature-dependent inter-plane resistivity, $ρ_c(T)$, was used to characterise the normal state of the iron-arsenide superconductor Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$ over a broad doping range $0\leq x<0.50$. The data were compared with in-plane resistivity, $ρ_a(T)$, and magnetic susceptibility, $χ(T)$, taken in $H \bot c$, as well as Co NMR Knight shift, $^{59}K$, and spin relaxation rate, $1/T_1T$. The inter-plane resistivity data show a clear correlation with the NMR Knight shift, assigned to the formation of the pseudo-gap. Evolution of $ρ_c(T)$ with doping reveals two characteristic energy scales. The temperature of the cross-over from non-metallic, increasing on cooling, behavior of $ρ_c(T)$ at high-temperatures to metallic behavior at low temperatures, $T^*$, correlates well with an anomaly in all three magnetic measurements. This characteristic temperature, equal to approximately 200~K in the parent compound, $x$=0, decreases with doping and vanishes near $x^* \approx$0.25. For doping levels $x \geq 0.166$, an additional feature appears above $T^*$, with metallic behavior of $ρ_c (T)$ found above the low-temperature resistivity increase. The characteristic temperature of this charge-gap formation, $T_{\rm CG}$, vanishes at $x_{\rm CG} \simeq$0.30, paving the way to metallic, $T$-linear, $ρ_c (T)$ close to $x_{\rm CG}$ and super-linear $T$-dependence for $x>x_{\rm CG}$. None of these features are evident in the in-plane resistivity $ρ_a(T)$. For doping levels $x x_{\rm CG}$.

cond-mat.supr-con↗