arXiv subjects

A. Tiwari

Publications and source records attributed to A. Tiwari.

At least 19 recordsLinked to original sources

arXiv2026

Imaging of van der Waals Materials via Standing-Wave Photoemission Microscopy: Depth-Resolved Electronic Structure of WS2

Two-dimensional van der Waals materials promise electronic, optoelectronic, and quantum technologies, yet depth-resolved characterization remains challenging. Here, we demonstrate standing-wave photoemission electron microscopy (SW-PEEM) for Angstrom-scale spectromicroscopy of monolayer WS2 on a W/C multilayer substrate. Tuning the X-ray standing wave through the monolayer yields a chemical depth profile and valence-band modulation with enhanced sensitivity to the top and bottom sulfur layers. X-ray optical modeling determines the structure and field distribution. The measurements reveal an ~0.2 eV shift in sulfur-derived valence-band spectral weight between measurements with enhanced sensitivity to the top and bottom sulfur layers. This shift is unlikely to arise from strong direct substrate hybridization and is instead consistent with sulfur-related surface species, as supported by calculations using a representative elemental-sulfur model. These results establish SW-PEEM as a non-destructive depth-resolved probe, highlighting its potential to probe interfacial coupling, chemical reconstruction, and emergent states in van der Waals and moir\'e systems.

cond-mat.mtrl-sci↗

arXiv2025

Coexistence of magnetic and dielectric glassy states in alternating kagome and triangular lattice LuBaCo$_4$O$_7$ cobaltite

To date, the alternating kagome and triangular lattice cobaltites, RBaCo$_4$O$_7$ (R = Ca, Y, and rare earth elements), have been well studied for their large structural distortions, anisotropic exchange interactions, chiral spin liquid states, and giant multiferroic properties. Here, we report the co-existence of magnetic and dielectric glassy states in LuBaCo$_4$O$_7$ below 50 K. AC magnetization studies show an absence of conventional spin-freezing behavior. The cooling and heating in unequal fields (CHUF), thermal cycling, and time-dependent magnetization measurements at low temperature ($T$) show the presence of magnetic glassy state. The $T$-dependent dielectric constant $\epsilon'$ measurements exhibit a strong frequency-independent response at the first-order structural phase transition $T = 160$ K (trigonal $P31c$ to monoclinic $Cc$) and also significant features at the $T = 110$ K (monoclinic $Cc$ to orthorhombic $Pbn2_1$) phase transition. Further, $\epsilon'$ shows a frequency-independent peak at 43 K ($Pbn2_1$) and also dipolar glassy features below 20 K ($Cc$). The non-equilibrium magnetic glassy dynamics and dipolar glassy state at low-$T$ arises from the kinetic arrest of $Cc$ and $Pbn2_1$ phases. From the dielectric probe, we are able to clearly distinguish the kinetically arrested phases at low-$T$ , whereas the bulk magnetization studies are unable to do so as the arrested phases have low magnetic moments.

cond-mat.str-el↗

arXiv2023

Non-equilibrium VLS-grown stable ST12-Ge thin film on Si substrate: A study on strain-induced band-engineering

The current work describes a novel method of growing thin films of stable crystalline ST12-Ge, a high pressure polymorph of Ge, on Si substrate by a non-equilibrium VLS-technique. The study explores the scheme of band engineering of ST12-Ge by inducing process-stress into it as a function of the growth temperature and film thickness. In the present work, ST12-Ge films are grown at 180 C - 250 C to obtain thicknesses of ~4.5-7.5 nm, which possess extremely good thermal stability up to a temperature of ~350 C. Micro-Raman study shows the stress induced in such ST12-Ge films to be compressive in nature and vary in the range of ~0.5-7.5 GPa. The measured direct band gap is observed to vary within 0.688 eV to 0.711 eV for such stresses, and four indirect band gaps are obtained to be 0.583 eV, 0.614-0.628 eV, 0.622-0.63 eV and 0.623-0.632 eV, accordingly. The corresponding band structures for unstrained and strained ST12-Ge are calculated by performing DFT simulation, which shows that a compressive stress transforms the fundamental band gap at M-G valley from indirect to direct one. Henceforth, the possible route of strain induced band engineering in ST12-Ge is explored by analyzing all the transitions in strained and unstrained band structures along with substantiation of the experimental results and theoretical calculations. The investigation shows that unstrained ST12-Ge is a natural n-type semiconductor which transforms into p-type upon incorporation of a compressive stress of ~5 GPa, with the in-plane electron effective mass components at M-G band edge to be ~0.09 me. Therefore, such band engineered ST12-Ge exhibits superior mobility along with its thermal stability and compatibility with Si, which can have potential applications to develop high-speed MOS devices for advanced CMOS technology.

cond-mat.mtrl-sci↗

arXiv2022

Probabilistic prediction of Dst storms one-day-ahead using Full-Disk SoHO Images

We present a new model for the probability that the Disturbance storm time (Dst) index exceeds -100 nT, with a lead time between 1 and 3 days. $Dst$ provides essential information about the strength of the ring current around the Earth caused by the protons and electrons from the solar wind, and it is routinely used as a proxy for geomagnetic storms. The model is developed using an ensemble of Convolutional Neural Networks (CNNs) that are trained using SoHO images (MDI, EIT and LASCO). The relationship between the SoHO images and the solar wind has been investigated by many researchers, but these studies have not explicitly considered using SoHO images to predict the $Dst$ index. This work presents a novel methodology to train the individual models and to learn the optimal ensemble weights iteratively, by using a customized class-balanced mean square error (CB-MSE) loss function tied to a least-squares (LS) based ensemble. The proposed model can predict the probability that Dst<-100 nT 24 hours ahead with a True Skill Statistic (TSS) of 0.62 and Matthews Correlation Coefficient (MCC) of 0.37. The weighted TSS and MCC from Guastavino et al. (2021) is 0.68 and 0.47, respectively. An additional validation during non-Earth-directed CME periods is also conducted which yields a good TSS and MCC score.

physics.space-ph↗

arXiv2021

Air, helium and water leakage in rubber O-ring seals with application to syringes

We study the leakage of fluids (liquids or gases) in syringes with glass barrel, steel plunger and rubber O-ring stopper. The leakrate depends on the interfacial surface roughness and on the viscoelastic properties of the rubber. Random surface roughness is produced by sandblasting the rubber O-rings. We present a very simple theory for gas flow which takes into account both the diffusive and ballistic flow. The theory shows that the interfacial fluid flow (leakage) channels are so narrow that the gas flow is mainly ballistic (the so called Knudsen limit). We compare the leakrate obtained using air and helium. For barrels filled with water we observe no leakage even if leakage occurs for gases. We interpret this as resulting from capillary (Laplace pressure or surface energy) effects.

cond-mat.soft↗

arXiv2021

Air leakage in seals with application to syringes

We study the leakage of air in syringes with Teflon coated rubber stopper and glass barrel. The leakrate depends on the interfacial surface roughness, the viscoelastic properties of the rubber and on the elastoplastic properties of the Teflon coating. The measured leakage rates are compared to the predictions of a simple theory for gas flow, which takes into account both the diffusive and ballistic air flow, and the elastoplastic multiscale contact mechanics which determines the probability distribution of interfacial separations. The theory shows that the interfacial air flow (leakage) channels are so narrow that the gas flow is mainly ballistic (the so called Knudsen limit). The implications for container closure integrity is discussed.

cond-mat.soft↗

arXiv2021

Unconventional transverse transport above and below the magnetic transition temperature in Weyl semimetal EuCd$_2$As$_2$

As exemplified by the growing interest in the quantum anomalous Hall effect, the research on topology as an organizing principle of quantum matter is greatly enriched from the interplay with magnetism. In this vein, we present a combined electrical and thermoelectrical transport study on the magnetic Weyl semimetal EuCd$_2$As$_2$. Unconventional contribution to the anomalous Hall and anomalous Nernst effects were observed both above and below the magnetic transition temperature of EuCd$_2$As$_2$, indicating the existence of significant Berry curvature. EuCd$_2$As$_2$ represents a rare case in which this unconventional transverse transport emerges both above and below the magnetic transition temperature in the same material. The transport properties evolve with temperature and field in the antiferromagnetic phase in a different manner than in the paramagnetic phase, suggesting different mechanisms to their origin. Our results indicate EuCd$_2$As$_2$ is a fertile playground for investigating the interplay between magnetism and topology, and potentially a plethora of topologically nontrivial phases rooted in this interplay.

cond-mat.str-el↗

arXiv2020

Physics of suction cups in air and in water

We present experimental results for the dependency of the pull-off time (failure time) on the pull-off force for suction cups in the air and in water. The results are analyzed using a theory we have developed for the contact between suction cups and randomly rough surfaces. The theory predicts the dependency of the pull-off time (failure time) on the pull-off force, and is tested with measurements performed on suction cups made from a soft polyvinyl chloride (PVC). As substrates we used sandblasted poly(methyl methacrylate) (PMMA). The theory is in good agreement with the experiments in air, except for surfaces with the root-mean-square (rms) roughness below $\approx 1 \ {\rm μm}$, where we observed lifetimes much longer than predicted by the theory. We show that this is due to out-diffusion of plasticizer from the soft PVC, which block the critical constrictions along the air flow channels. In water some deviation between theory and experiments is observed which may be due to capillary forces. We discuss the role of cavitation for the failure time of suction cups in water.

cond-mat.soft↗

arXiv2020

Rubber adhesion and friction: role of surface energy and contamination films

We study the influence of the surface energy and contamination films on rubber adhesion and sliding friction. We find that there is a transfer of molecules from the rubber to the substrate which reduces the work of adhesion and makes the rubber friction insensitive to the substrate surface energy. We show that there is no simple relation between adhesion and friction: adhesion is due to (vertical) detachment processes at the edge of the contact regions (opening crack propagation), while friction in many cases is determined mainly by (tangential) stick-slip instabilities of nanosized regions, within the whole sliding contact. Thus while the pull-off force in fluids may be strongly reduced (due to a reduction of the work of adhesion), the sliding friction may be only slightly affected as the area of real contact may be dry, and the frictional shear stress in the contact area nearly unaffected by the fluid.

cond-mat.soft↗

arXiv2020

Fluid leakage in metallic seals

Metallic seals are crucial machine elements in many important applications, e.g., in ultrahigh vacuum systems. Due to the high elastic modulus of metals, and the surface roughness which exists on all solid surfaces, if no plastic deformation would occur one expects in most cases large fluid flow channels between the contacting metallic bodies, and large fluid leakage. However, in most applications plastic deformation occurs, at least at the asperity level, which allows the surfaces to approach each other to such an extent that fluid leakage often can be neglected. In this study, we present an experimental set-up for studying the fluid leakage in metallic seals. We study the water leakage between a steel sphere and a steel body (seat) with a conical surface. The experimental results are found to be in good quantitative agreement with a (fitting-parameter-free) theoretical model. The theory predicts that the plastic deformations reduce the leak-rate by a factor $\approx 8$

cond-mat.soft↗

arXiv2020

Cylinder-flat contact mechanics with surface roughness

We study the nominal (ensemble averaged) contact pressure $p(x)$ acting on a cylinder squeezed in contact with an elastic half-space with random surface roughness. The contact pressure is Hertzian-like for $α< 0.01$ and Gaussian-like for $α> 10$, where the dimensionless parameter $α= h_{\rm rms}/δ$ is the ratio between the root-mean-square roughness amplitude and the penetration for the smooth surfaces case (Hertz contact).

cond-mat.soft↗

arXiv2020

Two comments on adhesion

The adhesion paradox refers to the observation that for most solid objects no adhesion can be detected when they are separated from a state of molecular contact. The adhesion paradox results from surface roughness, and we present experimental and theoretical results which shows that adhesion in most cases is "killed" by the longest wavelength roughness. Adhesion experiments between a human finger and a clean glass plate were carried out, and for a dry finger, no macroscopic adhesion occurred. We suggest that the observed decrease in the contact area with increasing shear force results from non-adhesive finger-glass contact mechanics, involving large deformations of a complex layered material.

cond-mat.soft↗

arXiv2020

Cylinder-flat contact mechanics during sliding

Using molecular dynamics (MD) we study the dependency of the contact mechanics on the sliding speed when an elastic block (cylinder) with a ${\rm cos} (q_0 x)$ surface height profile is sliding in adhesive contact on a rigid flat substrate.The atoms on the block interact with the substrate atoms by Lennard-Jones (LJ) potentials, and we consider both commensurate and(nearly) incommensurate contacts. For the incommensurate system the friction force fluctuates between positive and negative values, with an amplitude proportional to the sliding speed, but with the average close to zero. For the commensurate system the (time-averaged) friction force is much larger and nearly velocity independent. For both type of systems the width of the contact region is velocity independent even when, for the commensurate case, the frictional shear stress increases from zero (before sliding) to $\approx 0.1 \ {\rm MPa}$ during sliding. This frictional shear stress, and the elastic modulus used, are typical for Polydimethylsiloxan (PDMS) rubber sliding on a glass surface, and we conclude that the reduction in the contact area observed in some experiments when increasing the tangential force must be due to effects not included in our model study, such as viscoelasticity or elastic nonlinearity

cond-mat.soft↗

arXiv2020

Plastic deformation of rough metallic surfaces

We present experimental and theoretical results for the surface topography of a plastically deformed metallic (aluminum) block. When a hard spherical body (here a steel-, silica glass- or silicon nitride ball) with a smooth surface is indented in a metal block with a nominally flat, but still rough, surface, a spherical-cup-like indentation result due to plastic flow. The surface roughness in the indented region is, however, not entirely flattened. The long wavelength (macroasperity) content of the roughness result from the roughness on the original (aluminum) surface, but now plastically deformed. The roughness at short length scale, in the plastically deformed macroasperity contact regions, result from the roughness on the hard ball, and from inhomogeneous plastic flow. We model the contact mechanics using the boundary element method, combined with a simple numerical procedure to take into account the plastic flow. The theory can semi-quantitatively describe the modification of the roughness by the plastic flow. Since the fluid leakage of metallic seals in most cases is determined by the long wavelength roughness, we predict that the leakage can be estimated based on the elastoplastic contact mechanics model employed here. The plastic deformations of surfaces of some glassy polymers is very different from what we observed for aluminum, which we attribute to strong work-hardening and to inhomogeneous plastic flow for the polymers. Thus the numerical procedure to account for the plastic flow proposed here cannot be applied to glassy polymers in general.

cond-mat.soft↗

arXiv2020

On the origin of sliding friction: Role of lattice trapping

Using molecular dynamics we study the dependence of the friction force on the sliding speed when an elastic slab (block) is sliding on a rigid substrate with a ${\rm sin} (q_0 x)$ surface height profile. The friction force is nearly velocity independent due to phonon emission at the closing and opening crack tips, where rapid atomic snap-in and -out events occur during sliding. The rapid events result from lattice trapping and are closely related to the velocity gap and hysteresis effects observed in model studies of crack propagation in solids. This indicates that the friction force is dominated by processes occurring at the edges of the contact area, which is confirmed by calculations showing that the friction force is independent of the normal force. The friction force increases drastically when the sliding velocity approaches the solid transverse sound velocity, as expected from the theory of cracks.

cond-mat.soft↗

arXiv2020

Sphere and cylinder contact mechanics during slip

Using molecular dynamics (MD) we study the dependency of the contact mechanics on the sliding speed when an elastically soft slab (block) is sliding on a rigid substrate with a ${\rm sin} (q_0 x)$ surface height profile. The atoms on the block interact with the substrate atoms by Lennard-Jones potentials. We consider contacts with and without adhesion. We found that the contact area and the friction force are nearly velocity independent for small velocities ($v < 0.25 \ {\rm m/s}$) in spite of the fact that the shear stress in the contact area is rather non-uniform. For the case of no adhesion the friction coefficient is very small. For the case of adhesion the friction coefficient is higher, and is mainly due to energy dissipation at the opening crack tip, where rapid atomic snap-off events occur during sliding. Adhesion experiments between a human finger and a clean glass plate were carried out, and for a dry finger no macroscopic adhesion occurred. We suggest that the observed decrease in the contact area with increasing shear force results from non-adhesive finger-glass contact mechanics, involving large deformations of a complex layered material.

cond-mat.soft↗

arXiv2019

Theory for diffusive and ballistic air leakage and its application to suction cups

We have developed a theory of air leakage at interfaces between two elastic solids with application to suction cups in contact with randomly rough surfaces. We present an equation for the airflow in narrow constrictions which interpolate between the diffusive and ballistic (Knudsen) air-flow limits. To test the theory we performed experiments using two different suction cups, made from soft polyvinylchloride (PVC), in contact with sandblasted polymethylmethacrylate (PMMA) plates. We found that the measured time to detatch (lifetime) of suction cups were in good agreement with theory, except for surfaces with the root-mean-square (rms) roughness below $\approx 1 \ {\rm μm}$, where diffusion of plasticizer from the PVC to the PMMA surface caused blockage of critical constrictions. Suction cup volume, stiffness and elastic modulus have a huge influence on the air leakage and hence the failure time of the cups. Based on our research we propose an improved biomimetic design of suction cups, that could show improved failure times in varying degree of roughness under dry and wet environments.

cond-mat.soft↗

arXiv2019

Creeping flow of micropolar fluid through a swarm of cylindrical cells with porous layer (membrane)

The flow of micropolar fluid through a membrane modeled as a swarm of solid cylindrical particles with porous layer using the cell model technique is considered. The flow is directed perpendicular to the axis of the cylinders. Boundary value problem involves traditional conditions of velocities and stresses continuity, no-stress and no-couple stress / no-spin condition on hypothetical cell surface. The problem was solved analytically. The influence of micropolar and porous medium parameters on hydrodynamic permeability of a membrane has been studied.

physics.flu-dyn↗