arXiv subjects

A. U. B. Wolter

Publications and source records attributed to A. U. B. Wolter.

At least 73 records · Page 4Linked to original sources

arXiv2011

Orthogonal spin arrangement as possible ground state of three - dimensional Shastry - Sutherland network in Ba3Cu3In4O12

The Ba3Cu3In4O12 stands for unique topology of the magnetic subsystem. It consists of rotated by 90\Box$^b$ relative to each other "paper-chain" columns made of vertex-sharing CuIO4 and CuIIO4 planar units. The overall pattern of the copper ions is that of a three-dimensional Shastry-Sutherland network. At high temperatures, the magnetic susceptibility follows the Curie-Weiss law with positive Weiss temperature indicating strong predominance of ferromagnetic coupling. At low temperatures, however, this compound reaches the antiferromagnetically ordered state and experiences non-trivial succession of two spin-flop and two spin-flip transitions reaching full saturation in modest magnetic fields. Here we show that the possible ground state in Ba3Cu3In4O12 can be three-dimensional orthogonal arrangement of the Cu2+ (S = 1/2) magnetic moments forming three virtually independent antiferromagnetic subsystems. In this arrangement, favored by anisotropic exchange interactions, the quantum fluctuations provide the coupling between three mutually orthogonal magnetic subsystems resulting in an impressive "order by disorder" effect.

cond-mat.mtrl-sci↗

arXiv2011

Magnetic properties and revisited exchange integrals of the frustrated chain cuprate PbCuSO$_4$(OH)$_2$ - linarite

We present a detailed study in the paramagnetic regime of the frustrated $s$ = 1/2 spin-compound linarite, PbCuSO$_4$(OH)$_2$, with competing ferromagnetic nearest-neighbor and antiferromagnetic next-nearest-neighbor exchange interactions. Our data reveal highly anisotropic values for the saturation field along the crystallographic main directions, with $\sim$ 7.6, $\sim$ 10.5 and $\sim$ 8.5\,T for the $a$, $b$, and $c$ axes, respectively. In the paramagnetic regime, this behavior is explained mainly by the anisotropy of the \textit{g}-factor but leaving room for an easy-axis exchange anisotropy. Within the isotropic $J_1$-$J_2$ spin model our experimental data are described by various theoretical approaches yielding values for the exchange interactions $J_1$ $\sim$ -100\,K and $J_2$ $\sim$ 36\,K. These main intrachain exchange integrals are significantly larger as compared to the values derived in two previous studies in the literature and shift the frustration ratio $α= J_2/|J_1|$ $\approx$ 0.36 of linarite closer to the 1D critical point at 0.25. Electron spin resonance (ESR) and nuclear magnetic resonance (NMR) measurements further prove that the static susceptibility is dominated by the intrinsic spin susceptibility. The Knight shift as well as the broadening of the linewidth in ESR and NMR at elevated temperatures indicate a highly frustrated system with the onset of magnetic correlations far above the magnetic ordering temperature $T_\mathrm{N}$ = 2.75(5)\,K, in agreement with the calculated exchange constants.

cond-mat.str-el↗

arXiv2011

Calorimetric study of the superconducting and normal state properties of Ca(Fe1-xCox)2As2

We present a calorimetric study on single crystals of Ca(Fe1-xCox)2As2 (x = 0, 0.032, 0.051, 0.056, 0.063, and 0.146). The combined first order spin-density wave/structural transition occurs in the parent CaFe2As2 compound at 168 K and gradually shifts to lower temperature for low doping levels (x = 0.032 and x = 0.051). It is completely suppressed upon higher doping x = 0.056. Simultaneously, superconductivity appears at lower temperature with a transition temperature around Tc = 14.1 K for Ca(Fe0.937Co0.063)2As2. The phase diagram of Ca(Fe0.937Co0.063)2As2 has been derived and the upper critical field is found to be H(c) c2 = 11.5

cond-mat.supr-con↗

arXiv2011

Disorder-induced Spin Gap in the Zigzag Spin-1/2 Chain Cuprate Sr_{0.9}Ca_{0.1}CuO_2

We report a comparative study of 63Cu Nuclear Magnetic Resonance spin lattice relaxation rates, T_1^{-1}, on undoped SrCuO_2 and Ca doped Sr_{0.9}Ca_{0.1}CuO_2 spin chain compounds. A temperature independent T_1^{-1} is observed for SrCuO_2 as expected for an S=1/2 Heisenberg chain. Surprisingly, we observe an exponential decrease of T_1^{-1} for T < 90,K in the Ca-doped sample evidencing the opening of a spin gap. The data analysis within the J_1-J_2 Heisenberg model employing density-matrix renormalization group calculations suggests an impurity driven small alternation of the J_2-exchange coupling as a possible cause of the spin gap.

cond-mat.str-el↗

arXiv2011

Multi-gap superconductivity in single crystals of Ba$_{0.65}$Na$_{0.35}$Fe$_2$As$_2$: A calorimetric investigation

We investigate the electronic properties and the superconducting gap characteristics of a single crystal of hole-doped 122 Fe-pnictide Ba$_{0.65}$Na$_{0.35}$Fe$_2$As$_2$ by means of specific heat measurements. The specific heat exhibits a pronounced anomaly around the superconducting transition temperature $T_c$ = 29.4 K, and a small residual part at low temperature. In a magnetic field of 90 kOe, the transition is broadened and $T_c$ is lowered insignificantly by an amount $\sim$ 1.5 K. We estimate a high electronic coefficient in the normal state with a value 57.5 mJ mol$^{-1}$ K$^2$, being consistent with hole-doped 122 compounds. The temperature-dependent superconducting electronic specific heat cannot be described with single-gap BCS theory under weak coupling approach. Instead, our analysis implies a presence of two s-wave like gaps with magnitudes $Δ_1(0)/k_BT_c$ = 1.06 and $Δ_2(0)/k_BT_c$ = 2.08 with their respective weights of 48% and 52%. While our results have qualitative similarities with other hole-doped 122 materials, the gap's magnitude and their ratio are quite different.

cond-mat.supr-con↗

arXiv2010

The superconducting gaps in LiFeAs: Joint study of specific heat and ARPES

We present specific heat, c_P, and ARPES data on single crystals of the stoichiometric superconductor LiFeAs. A pronounced anomaly is found in c_P at the superconducting transition. The electronic contribution can be described by two s-type energy gaps with magnitudes of approximately Delta1 = 1.2 meV and Delta2 = 2.6 meV and a normal-state gamma coefficient of 10 mJ/mol K^2. All these values are in remarkable agreement with ARPES results.

cond-mat.supr-con↗

arXiv2010

Magnetoelastic and structural properties of azurite Cu3(CO3)2(OH)2 from neutron scattering and muon spin rotation

Azurite, Cu3(CO3)2(OH)2, has been considered an ideal example of a one-dimensional (1D) diamond chain antiferromagnet. Early studies of this material imply the presence of an ordered antiferromagnetic phase below $T_N \sim 1.9$ K while magnetization measurements have revealed a 1/3 magnetization plateau. Until now, no corroborating neutron scattering results have been published to confirm the ordered magnetic moment structure. We present recent neutron diffraction results which reveal the presence of commensurate magnetic order in azurite which coexists with significant magnetoelastic strain. The latter of these effects may indicate the presence of spin frustration in zero applied magnetic field. Muon spin rotation, $μ$SR, reveals an onset of short-range order below 3K and confirms long-range order below $T_N$.

cond-mat.stat-mech↗

arXiv2010

Fishtail effect and vortex dynamics in LiFeAs single crystals

We investigate the fishtail effect, critical current density ($J_c$) and vortex dynamics in LiFeAs single crystals. The sample exhibits a second peak (SP) in the magnetization loop only with the field $||$ c-axis. We calculate a reasonably high $J_c$, however, values are lower than in 'Ba-122' and '1111'-type FeAs-compounds. Magnetic relaxation data imply a strong pinning which appears not to be due to conventional defects. Instead, its behavior is similar to that of the triplet superconductor Sr$_2$RuO$_4$. Our data suggest that the origin of the SP may be related to a vortex lattice phase transition. We have constructed the vortex phase diagram for LiFeAs on the field-temperature plane.

cond-mat.supr-con↗

arXiv2010

Transition from a phase-segregated state to single-phase incommensurate sodium ordering in Na_xCoO_2 with x \approx 0.53

Synchrotron X-ray diffraction investigations of two single crystals of Na_xCoO_2 from different batches with composition x = 0.525-0.530 reveal homogeneous incommensurate sodium ordering with propagation vector (0.53 0.53 0) at room-temperature. The incommensurate (qq0) superstructure exists between 220 K and 430 K. The value of q varies between q = 0.514 and 0.529, showing a broad plateau at the latter value between 260 K and 360 K. On cooling, unusual reversible phase segregation into two volume fractions is observed. Below 220 K, one volume fraction shows the well-known commensurate orthorhombic x = 0.50 superstructure, while a second volume fraction with x = 0.55 exhibits another commensurate superstructure, presumably with a 6a x 6a x c hexagonal supercell. We argue that the commensurate-to-incommensurate transition is an intrinsic feature of samples with Na concentrations x = 0.5 + d with d ~ 0.03.

cond-mat.str-el↗

arXiv2009

Ga substitution as an effective variation of Mn-Tb coupling in multiferroic TbMnO3

Ga for Mn substitution in multiferroic TbMnO$_{3}$ has been performed in order to study the influence of Mn-magnetic ordering on the Tb-magnetic sublattice. Complete characterization of TbMn$_{1-x}$Ga$_x$O$_{3}$ ($x$ = 0, 0.04, 0.1) samples, including magnetization, impedance spectroscopy, and x-ray resonant scattering and neutron diffraction on powder and single crystals has been carried out. We found that keeping the same crystal structure for all compositions, Ga for Mn substitution leads to the linear decrease of $T_{\rm N}^{\rm Mn}$ and $τ^{\rm Mn}$, reflecting the reduction of the exchange interactions strength $J_{\rm Mn-Mn}$ and the change of the Mn-O-Mn bond angles. At the same time, a strong suppression of both the induced and the separate Tb-magnetic ordering has been observed. This behavior unambiguously prove that the exchange fields $J_{\rm Mn-Tb}$ have a strong influence on the Tb-magnetic ordering in the full temperature range below $T_{\rm N}^{\rm Mn}$ and actually stabilize the Tb-magnetic ground state.

cond-mat.str-el↗

arXiv2009

Magnetic-field induced effects on the electric polarization in RMnO3 (R = Dy, Gd)

X-ray resonant magnetic scattering studies of rare earth magnetic ordering were performed on perovskite manganites RMnO3 (R = Dy, Gd) in an applied magnetic field. The data reveal that the field-induced three-fold polarization enhancement for H || a (H approx. 20 kOe) observed in DyMnO3 below 6.5 K is due to a re-emergence of the Mn-induced Dy spin order with propagation vector k(Dy) = k(Mn) = 0.385 b*, which accompanies the suppression of the independent Dy magnetic ordering, k(Dy) = 1/2 b*. For GdMnO3, the Mn-induced ordering of Gd spins is used to track the Mn-ordering propagation vector. The data confirm the incommensurate ordering reported previously, with k(Mn) varying from 0.245 to 0.16 b* on cooling from T_N(Mn) down to a transition temperature T'. New superstructure reflections which appear below T' suggest a propagation vector k(Mn) = 1/4 b* in zero magnetic field, which may coexist with the previously reported A-type ordering of Mn. The Gd spins order with the same propagation vector below 7 K. Within the ordered state of Gd at T = 1.8 K we find a phase boundary for an applied magnetic field H || b, H = 10 kOe, which coincides with the previously reported transition between the ground state paraelectric and the ferroelectric phase of GdMnO3. Our results suggest that the magnetic ordering of Gd in magnetic field may stabilize a cycloidal ordering of Mn that, in turn, produces ferroelectricity.

cond-mat.str-el↗

arXiv2007

Nature of the spin dynamics and 1/3 magnetization plateau in azurite

We present a specific heat and inelastic neutron scattering study in magnetic fields up into the 1/3 magnetization plateau phase of the diamond chain compound azurite Cu$_3$(CO$_3$)$_2$(OH)$_2$. We establish that the magnetization plateau is a dimer-monomer state, {\it i.e.}, consisting of a chain of $S = 1/2$ monomers, which are separated by $S = 0$ dimers on the diamond chain backbone. The effective spin couplings $J_{mono}/k_B = 10.1(2)$ K and $J_{dimer}/k_B = 1.8(1)$ K are derived from the monomer and dimer dispersions. They are associated to microscopic couplings $J_1/k_B = 1(2)$ K, $J_2/k_B = 55(5)$ K and a ferromagnetic $J_3/k_B = -20(5)$ K, possibly as result of $d_{z^2}$ orbitals in the Cu-O bonds providing the superexchange pathways.

cond-mat.stat-mech↗

arXiv2007

Coupling of frustrated Ising spins to magnetic cycloid in multiferroic TbMnO3

We report on diffraction measurements on multiferroic TbMnO3 which demonstrate that the Tb- and Mn-magnetic orders are coupled below the ferroelectric transition TFE = 28 K. For T < TFE the magnetic propagation vectors (tau) for Tb and Mn are locked so that tauTb = tauMn, while below TNTb = 7 K we find that tauTb and tauMn lock-in to rational values of 3/7 b* and 2/7 b*, respectively, and obey the relation 3tauTb - tauMn = 1. We explain this novel matching of wave vectors within the frustrated ANNNI model coupled to a periodic external field produced by the Mn-spin order. The tauTb = tauMn behavior is recovered when Tb magnetization is small, while the tauTb = 3/7 regime is stabilized at low temperatures by a peculiar arrangement of domain walls in the ordered state of Ising-like Tb spins.

cond-mat.str-el↗

arXiv2007

Electronic structure of the molecule based magnet Cu PM(NO3)2 (H2O)2

We present density functional calculations on the molecule based S=1/2 antiferromagnetic chain compound Cu PM(NO3)2 (H2O)2; PM = pyrimidine. The properties of the ferro- and antiferromagnetic state are investigated at the level of the local density approximation and with the hybrid functional B3LYP. Spin density maps illustrate the exchange path via the pyrimidine molecule which mediates the magnetism in the one-dimensional chain. The computed exchange coupling is antiferromagnetic and in reasonable agreement with the experiment. It is suggested that the antiferromagnetic coupling is due to the possibility of stronger delocalization of the charges on the nitrogen atoms, compared to the ferromagnetic case. In addition, computed isotropic and anisotropic hyperfine interaction parameters are compared with recent NMR experiments.

cond-mat.mtrl-sci↗

arXiv2007

High field level crossing studies on spin dimers in the low dimensional quantum spin system Na$_2$T$_2$(C$_2$O$_4$)$_3$(H$_2$O)$_2$ with T=Ni,Co,Fe,Mn

In this paper we demonstrate the application of high magnetic fields to study the magnetic properties of low dimensional spin systems. We present a case study on the series of 2-leg spin-ladder compounds Na$_2$T$_2$(C$_2$O$_4$)$_3$(H$_2$O)$_2$ with T = Ni, Co, Fe and Mn. In all compounds the transition metal is in the $T^{2+}$ high spin configuation. The localized spin varies from S=1 to 3/2, 2 and 5/2 within this series. The magnetic properties were examined experimentally by magnetic susceptibility, pulsed high field magnetization and specific heat measurements. The data are analysed using a spin hamiltonian description. Although the transition metal ions form structurally a 2-leg ladder, an isolated dimer model consistently describes the observations very well. This behaviour can be understood in terms of the different coordination and superexchange angles of the oxalate ligands along the rungs and legs of the 2-leg spin ladder. All compounds exhibit magnetic field driven ground state changes which at very low temperatures lead to a multistep behaviour in the magnetization curves. In the Co and Fe compounds a strong axial anisotropy induced by the orbital magnetism leads to a nearly degenerate ground state and a strongly reduced critical field. We find a monotonous decrease of the intradimer magnetic exchange if the spin quantum number is increased.

cond-mat.mtrl-sci↗

arXiv2006

Determining ethylene group disorder levels in $κ$-(BEDT-TTF)$_2$Cu[N(CN)$_2$]Br

We present a detailed structural investigation of the organic superconductor $κ$-(BEDT-TTF)$_2$Cu[N(CN)$_2$]Br at temperatures $T$ from 9 to 300 K. Anomalies in the $T$ dependence of the lattice parameters are associated with a glass-like transition previously reported at $T_g$ = 77 K. From structure refinements at 9, 100 and 300 K, the orthorhombic crystalline symmetry, space group {\it Pnma}, is established at all temperatures. Further, we extract the $T$ dependence of the occupation factor of the eclipsed conformation of the terminal ethylene groups of the BEDT-TTF molecule. At 300 K, we find 67(2) %, with an increase to 97(3) % at 9 K. We conclude that the glass-like transition is not primarily caused by configurational freezing-out of the ethylene groups.

cond-mat.mtrl-sci↗

arXiv2006

S=1/2 antiferromagnetic Heisenberg chain with staggered fields: Copper pyrimidine and copper benzoate using the density matrix renormalization group for transfer matrices

We consider the spin-1/2 antiferromagnetic Heisenberg chain in a staggered magnetic field describing materials such as copper benzoate and copper pyrimidine dinitrate. Using the density-matrix renormalization group for transfer matrices (TMRG) we calculate the magnetization of these materials at finite temperature and arbitrary magnetic field. These results are in excellent agreement with experimental data, allowing for a determination of the inhomogeneity parameter c of copper benzoate (c = 0.043) and copper pyrimidine dinitrate (c= 0.11). The TMRG approach can be applied to rather low temperatures yielding singular field and temperature dependences of susceptibilities.

cond-mat.str-el↗

arXiv2005

Giant spin canting in the S = 1/2 antiferromagnetic chain [CuPM(NO3)2(H2O)2]n observed by 13C-NMR

We present a combined experimental and theoretical study on copper pyrimidine dinitrate [CuPM(NO3)2(H2O)2]n, a one-dimensional S = 1/2 antiferromagnet with alternating local symmetry. From the local susceptibility measured by NMR at the three inequivalent carbon sites in the pyrimidine molecule we deduce a giant spin canting, i.e., an additional staggered magnetization perpendicular to the applied external field at low temperatures. The magnitude of the transverse magnetization, the spin canting of 52 degrees at 10 K and 9.3 T and its temperature dependence are in excellent agreement with exact diagonalization calculations.

cond-mat.mtrl-sci↗