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A. Watt

Publications and source records attributed to A. Watt.

3 recordsLinked to original sources

Active metamaterials with negative static electric susceptibility

Well-established textbook arguments suggest that static electric susceptibility must be positive in "all bodies" [1]. However, it has been pointed out that media that are not in thermodynamic equilibrium are not necessarily subject to this restriction; negative static electric susceptibility has been predicted theoretically in systems with inverted populations of atomic and molecular energy levels [2,3], though this has never been confirmed experimentally. Here we exploit the design freedom afforded by metamaterials to fabricate active structures that exhibit the first experimental evidence of negative static electric susceptibility. Unlike the systems envisioned previously---which were expected to require reduced temperature and pressure---negative values are readily achieved at room temperature and pressure. Further, values are readily tuneable throughout the negative range of stability -1<χ^{(0)}<0, resulting in magnitudes that are over one thousand times greater than predicted previously [4]. This opens the door to new technological capabilities such as stable electrostatic levitation.

physics.app-ph

Polarised Photoluminescence from Surface-Passivated PbS Nanocrystals

Effective surface-passivation of PbS nanocrystals in aqueous colloidal solution has been achieved following treatment with CdS precursors. The resultant photoluminescent emission displays two distinct components, one originating from the absorption band-edge and the other from above the absorption band-edge. We show that both of these components are strongly polarised but display distinctly different behaviours. The polarisation arising from the band-edge shows little dependence on the excitation energy while the polarisation of the above-band-edge component is strongly dependent on the excitation energy. In addition, time resolved polarisation spectroscopy reveals that the above-band-edge polarisation is restricted to the first couple of nanoseconds, while the band-edge polarisation is nearly constant over hundreds of nanoseconds. We recognise an incompatibility between the two different polarisation behaviours, which enables us to identify two distinct types of surface-passivated PbS nanocrystal.

cond-mat.mtrl-sci

Inorganic Surface Passivation of PbS Nanocrystals resulting in Strong Photoluminescent Emission

Strong photoluminescent emission has been obtained from 3 nm PbS nanocrystals in aqueous colloidal solution, following treatment with CdS precursors. The observed emission can extend across the entire visible spectrum and usually includes a peak near 1.95 eV. We show that much of the visible emission results from absorption by higher-lying excited states above 3.0 eV with subsequent relaxation to and emission from states lying above the observed band-edge of the PbS nanocrystals. The fluorescent lifetimes for this emission are in the nanosecond regime, characteristic of exciton recombination.

cond-mat.mtrl-sci