arXiv subjects

Aaron T. Bondy

Publications and source records attributed to Aaron T. Bondy.

4 recordsLinked to original sources

arXiv2026

Theory for the Rydberg states of helium: quantum defect extensions and comparison with experiment up to $n = 102$ for the singlet and triplet $P$-states

High precision variational calculations for helium in Hylleraas coordinates are used to obtain a combination of quantum defect expansions for the nonrelativistic energy and $1/n$ expansions for the relativistic and quantum electrodynamic (QED) corrections. The extrapolations based on direct calculations for the singlet and triplet $P$-states up to principal quantum number $n = 35$ provide ionization energies of the $1snp\;^1P_1$ and $^3P_c$ (centroid) states up to $n=102$ with accuracies better than $\pm$1 kHz. The calculated ionization energies are combined with 28 measured transition frequencies to obtain values for the ionization energy of the $1s2s\;^3S_1$ state. The final result of 1152 842 742.705(16) MHz differs from theory by $0.474\pm 0.052$ MHz, and provides a strong confirmation of the 9$σ$ disagreement between theory and experiment obtained previously by quantum defect extrapolation of experimental data to the series limit. An analysis of the quantum defect method is presented, and second-order mass polarization (recoil) terms are identified that vary as $1/n^2$ in lowest order. The nonrelativistic part provides a theoretical justification for the effective reduced-mass Rydberg $R_M^{(+)}$ based on the phenomenological model of a Rydberg electron scattering from a He$^+$ core. The Ritz expansion for the nonrelativistic energy is verified to an unprecedented 20-figure accuracy.

physics.atom-ph↗

arXiv2026

High-order harmonic generation in argon driven by short laser pulses: effects of post-pulse propagation and windowing

We present ab initio calculations using the $R$-matrix with time dependence (RMT) method for high-order harmonic generation (HHG) in argon in a short, intense pulse regime. The calculations employ a $6$-cycle $\sin^2$ pulse at $850$ nm with peak intensity $2.3\times 10^{14}$ W/cm$^2$ and, for comparison with the experiment by Guo et al. [J. Phys. B: At. Mol. Opt. Phys. 51, 034006 (2018)], a Gaussian pulse with the same frequency and peak intensity. Both pulse shapes yield the expected harmonic structure in the region above the ionization threshold (approximately $15.82$ eV in $LS$-coupling). The spectra exhibit strong carrier-envelope-phase (CEP) sensitivity. The energy region leading up to the ionization threshold contains spectral features arising from residual coherent dipole oscillations (free-induction decay) that strongly depend on spectral windowing and the post-pulse propagation time. We show that the HHG spectrum, particularly below the ionization threshold, is a defined quantity that depends on analysis choices rather than being a uniquely determined observable. Comparison between theoretical predictions and experimental observations in this energy regime, therefore, requires explicit specification of these parameters.

physics.atom-ph↗

arXiv2025

Theory for the Rydberg states of helium: Results for $2 \le n \le 35$ and comparison with experiment for the singlet and triplet $P$-states

High precision variational calculations in Hylleraas coordinates are presented for all singlet and triplet $P$-states of helium up to principal quantum number $n = 35$ with a uniform accuracy of 1 part in $10^{22}$ for the nonrelativistic energy. Mass polarization, relativistic and quantum electrodynamic effects are included to achieve a final accuracy of $\pm$1 kHz or better for the ionization energy of the Rydberg states of $^4$He in the range $24\le n \le 35$. The results are combined with 11 transition frequency measurements of Clausen et al. Phys. Rev. A 111, 012817 (2025) to obtain complementary measurements of the ionization energy of the $1s2s\;^3S_1$ state that do not depend on quantum defect extrapolations to the series limit. The result from the triplet spectrum yields an ionization energy of 1152 842 742.728(6) MHz, which agrees with but is larger than the experimental value by 14 $\pm$17 kHz. However, it confirms a much larger 9$σ$ discrepancy of $0.468\pm0.055$ MHz with the theoretical ionization energy of Patkóš et al. Phys. Rev. A 103, 042809 (2021). The results provide a test of the quantum defect extrapolation method at the level of $\pm$17 kHz. This revised version contains an additional table of spin-dependent matrix elements of the Breit interaction in the appendix for $24\le n\le 35$. (12 pages, 1 figure).

physics.atom-ph↗

arXiv2025

Theory for the Rydberg states of helium: Comparison with experiment for the $1s24p\;^1P_1$ state ($n=24$)

Recent measurements of the ionization energies of the Rydberg $^1P$ states of helium for principal quantum number $n = 24$ and higher present a new challenge to theoretical atomic physics. A long-standing obstacle to high precision atomic theory for three-body systems is a rapid loss of accuracy for variational calculations with increasing principal quantum number $n$. We show that this problem can be overcome with the use of a ``triple" basis set in Hylleraas coordinates. Nonrelativistic energies accurate to 23 significant figures are obtained with basis sets of relatively modest size (6744 terms). Relativistic and quantum electrodynamic effects are calculated, including an estimate of terms of order $mα^6$ from a $1/n^3$ extrapolation, resulting in an estimated accuracy of $\pm$1 kHz. The calculated ionization energy of 5704 980.348(1) MHz is in excellent agreement with the experimental value 5704 980.312(95) MHz. These results establish the ionization energy of the $1s24p\;^1P_1$ state as an absolute point of reference for transitions to lower-lying states, and they confirm an $11σ$ disagreement between theory and experiment in the triplet spectrum of helium. Results are also given for the $1s24p\;^3P_J$ states in agreement with a recent experiment on the triplet Rydberg series, thereby confirming a discrepancy of of $0.468 \pm 0.055$ MHz for the ionization energy of the $1s2s\;^3S_1$ state.

physics.atom-ph↗