arXiv subjects

Aashish Sapkota

Publications and source records attributed to Aashish Sapkota.

16 recordsLinked to original sources

arXiv2026

Pressure-Stabilized MnSb$_2$ with Complex Incommensurate Magnetic Order

Marcasite-type compounds have been proposed as promising hosts of exotic magnetic quantum states, yet experimental realizations in stoichiometric, disorder-free systems remain limited. Here, we report the high-pressure stabilization and magnetic characterization of MnSb$_2$, a marcasite-type compound that is thermodynamically metastable under ambient pressure. Single crystals were synthesized using a cubic multi-anvil press, and powder and single-crystal X-ray diffraction confirm the orthorhombic $Pnnm$ structure. These crystals are stable at ambient pressure for a long time up to between 450-500 K. Heat-capacity measurements reveal phase transitions at approximately 220 K and 118 K. Neutron diffraction uncovers an unconventional magnetic ground state below 220 K. Magnetic powder neutron diffraction refinements reveal possible multiple magnetic configurations that provide comparably acceptable fits to the experimental data. While most solutions are consistent with a spin-density-wave (SDW) description, helical models systematically yield inferior agreement factors. Across a broad range of models, the Mn ordered moment reaches a maximum value of approximately 2 $μ_B$ and remains predominantly collinear, with minimal canting along the $c$-axis. At 200 K, the magnetic propagation vector is $q$ = (0, 0.3975, 0.3783); upon cooling, the $b$ component increases toward 0.5, reflecting a temperature-dependent evolution of the modulation. The need for modification of the magnetic model between high and low temperatures further highlights the complex and strongly temperature-dependent nature of the magnetic order in this system. These results establish MnSb$_2$ as a pressure-stabilized marcasite magnet with a highly tunable, complex magnetic ground state and a compelling stoichiometric platform for exploring unconventional magnetic behavior, including potential altermagnetism.

cond-mat.str-el↗

arXiv2026

Physical properties of R$_2$Co$_6$Al$_{20-δ}$ (R = Gd-Tm, Y) single crystals

Rare-earth (R) based intermetallic compounds can often exhibit diverse physical properties and distinct magnetic anisotropies. A Notable example are the light rare earth members of the mono-clinic, R$_2$Co$_6$Al$_{19}$ series that are known to display a range of physical properties, from non-Fermi liquid behavior to antiferromagnetic (AFM) ordering, with properties that vary depending on R. In this work, we have extended this series to the heavy rare earths and systematically investigate the synthesis, crystal structure, and physical properties of single crystals of R$_2$Co$_6$Al$_{20-δ}$ for R = Gd - Tm and Y. Single crystal X-ray diffraction reveals that these materials adopt an orthorhombic Imma-type structure with delta varying non-monotonically across the heavy rare earths; ranging from 0.73 for Dy to 0.91 for Gd. Temperature-dependent specific heat, resistivity, and magnetization measurements demonstrate AFM ordering in all materials, with the Neel temperature (TN) ranging from 1.8 K for Ho to 11.8 K for Tb. Notably, Gd and Tb-based materials exhibit two distinct AFM transitions, separated by approximately 2 - 3 K. These findings establish the heavy rare-earth members of the R2Co6Al20-delta series as anisotropic antiferromagnets with strong crystal electric field effects and exchange anisotropy. The observed deviation from de Gennes scaling and the anisotropy crossover across the series highlight the important interplay between RKKY exchange and crystal electric field interactions in this orthorhombic system.

cond-mat.mtrl-sci↗

arXiv2026

Suppression of the valence transition in solution-grown single crystals of Eu$_2$Pt$_6$Al$_{15}$

The study of Eu intermetallic compounds has allowed the exploration of valence fluctuations and transitions in 4f electron systems. Recently, a Eu$_2$Pt$_6$Al$_{15}$ phase synthesized by arc-melting followed by a thermal treatment was reported [M. Radzieowski \textit{et al.}, J Am Chem Soc 140(28), 8950-8957 (2018)], which undergoes a transition upon cooling below 45~K that was interpreted as a valence transition from Eu$^{2+}$ to Eu$^{3+}$. In this paper, we present the discovery of another polymorph of Eu$_2$Pt$_6$Al$_{15}$ obtained by high temperature solution growth, which presents different physical properties than the arc-melted polycrystalline sample. Despite the similarities in crystal structure and chemical composition, the Eu valence transition is almost fully suppressed in the solution-grown crystals, allowing the moments associated with the Eu$^{2+}$ state to order antiferromagnetically at around 14~K. A detailed analysis of the crystal structure using single crystal X-ray diffraction reveals that, although the solution grown crystals are built from the same constituent layers as the arc-melted samples, these layers present a different stacking. The effect of different thermal treatments is also studied. Different anneal procedures did not result in significant changes in the intrinsic properties, and only by arc-melting and quenching the crystals we were able to convert them into the previously reported polymorph.

cond-mat.mtrl-sci↗

arXiv2025

Hidden symmetry-breaking in a kagome Ising ferromagnet

Kagome metals can host unconventional electronic phenomena that emerge from their frustrated lattice geometry and associated band topology. Correlated electronic orders, such as charge-density waves and superconductivity, are observed to intertwine with subtle time-reversal symmetry breaking whose microscopic origin is not currently understood. Here, we provide evidence for such time-reversal symmetry breaking in the kagome metal TbV$_6$Sn$_6$ arising from staggered magnetic moments within the kagome layers. TbV$_6$Sn$_6$ consists of metallic V kagome layers separated by Tb triangular layers that host Ising ferromagnetic order. Deep in the ferromagnetic state, the Tb Ising doublet ground state should display a single, dispersionless spin-flip excitation. Instead, inelastic neutron scattering reveals two sharp excitations associated with inequivalent Tb sites, demonstrating that a symmetry-broken phase coexists with Ising ferromagnetism. No additional structural or magnetic phase transitions are detected, and first-principles calculations rule out lattice distortions as the origin of the splitting. We attribute this effect to time-reversal symmetry breaking encoded by small V moments that couple to the Tb sublattice and leave a measurable spectral fingerprint. Our results establish rare-earth local moment spectroscopy as a sensitive probe of subtle broken symmetries and highlight an unexpected interplay between kagome magnetism and rare-earth local moment magnetism.

cond-mat.str-el↗

arXiv2025

Magnetism and Peierls distortion in Dirac semimetal CaMnBi$_2$

Dirac semimetals of the form $A$Mn$X_2$ ($A =$ alkaline-earth or divalent rare earth; $X =$ Bi, Sb) host conducting square-net Dirac-electron layers of $X$ atoms interleaved with antiferromagnetic Mn$X$ layers. In these materials, canted antiferromagnetism can break time-reversal symmetry (TRS) and produce a Weyl semimetallic state. CaMnBi$_2$ was proposed to realize this behavior below $T^{*}\sim 50$ K, where anomalies in resistivity and optical conductivity were reported. We investigate single-crystal CaMnBi$_{2}$ using polarized and unpolarized neutron diffraction, x-ray diffraction, and density functional theory (DFT) calculations to elucidate the underlying crystal and magnetic structures. The results show that the observed anomalies do not originate from spin canting or weak ferromagnetism; no measurable uniform Mn spin canting is detected. Instead, CaMnBi$_2$ undergoes a coupled structural and magnetic symmetry-lowering transition at $T^{*} = 46(2)$ K, from a tetragonal lattice with C-type antiferromagnetism to an orthorhombic phase with unit-cell doubling along the $c$ axis and minimal impact on magnetism. Analysis of superlattice peak intensities and lattice distortion reveals a continuous second-order transition governed by a single order parameter. The refined atomic displacements correspond to a zigzag bond-order-wave (BOW) modulation of Bi-Bi bonds, consistent with an electronically driven Peierls-type instability in the Dirac-electron Bi layer, long anticipated by Hoffmann and co-workers [W.~Tremel and R.~Hoffmann, \textit{J. Am. Chem. Soc.} \textbf{109}, 124 (1987); G.~A.~Papoian and R.~Hoffmann, \textit{Angew. Chem. Int. Ed.} \textbf{39}, 2408 (2000)]. %\textcite{TremelHoffman_JACS1987} [JACS {\bf 109}, 124 (1987)].

cond-mat.mtrl-sci↗

arXiv2025

Physical properties of $R$Co$_{2}$Al$_{8}$ ($R=$ La, Ce, Pr, Nd and Sm) single crystals: An emerging structure-type for anisotropic Kondo lattice studies

Systematic investigations of rare-earth ($R$) based intermetallic materials are a leading strategy to reveal the underlying mechanisms governing a range of physical phenomena, such as the formation of a Kondo lattice and competing electronic and magnetic anisotropies. In this work, the magnetic, thermal and transport properties of $R$Co$_{2}$Al$_{8}$ ($R=$ La, Ce, Pr, Nd and Sm) single crystals are presented. LaCo$_{2}$Al$_{8}$ is characterized as a Pauli paramagnet and transport measurements, with the current along and perpendicular to the orthorhombic $c$-axis ($ρ_{c}$ and $ρ_{ab}$, respectively), reveal a clear electronic anisotropy, with $ρ_{ab }\approx(4-7)ρ_{c }$ at $300$ K. We show that CeCo$_{2}$Al$_{8}$ is a Kondo-lattice for which the Kondo coherence temperature $T_{\text{K}}^{*}$, deduced from broad maximums in $ρ_{c}$ and $ρ_{ab}$ at $\approx$ 68 and 46 K, respectively, is also anisotropic. This finding is related to a possible underlying anisotropy of the Kondo coupling in CeCo$_{2}$Al$_{8}$. The Pr- and Nd-based materials present strong easy-axis anisotropy ($c$-axis) and antiferromagnetic (AFM) orders below $T=4.84$ K and $T=8.1$ K, respectively. Metamagnetic transitions from this AFM to a spin-polarized paramagnetic phase state are investigated by isothermal magnetization measurements. The Sm-based compound is also an easy-axis AFM with a transition at $T=21.6$ K.

cond-mat.str-el↗

arXiv2025

Tuning the structure and superconductivity of SrNi$_2$P$_2$ by Rh substitution

SrNi$_2$P$_2$ is unique among the ThCr$_2$Si$_2$ class since it exhibits a temperature induced transition upon cooling from an uncollapsed tetragonal (ucT) state to a one-third-collapsed orthorhombic (tcO) state where one out of every three P-rows bond across the Sr layers. This compound is also known for exhibiting bulk superconductivity below 1.4 K at ambient pressure. In this work, we report on the effects of Rh substitution in Sr(Ni$_{1-x}$Rh$_x$)$_2$P$_2$ on the structural and superconducting properties. We studied the variation of the nearest P-P distances as a function of the Rh fraction at room temperature, as well as its temperature dependence for selected compositions. We find that increasing the Rh fraction leads to a decrease in the transition temperature between the ucT and tcO states, until a full suppression of the tcO state for $x\geq 0.166$. The superconducting transition first remains nearly insensitive to the Rh fraction, and then it increases to 2.3 K after the tcO state is fully suppressed. These results are summarized in a phase diagram, built upon the characterization by energy dispersive x-ray spectroscopy, x-ray diffraction, resistance, magnetization and specific heat measurements done on crystalline samples with varying Rh content. The relationship between band structure, crystal structure and superconductivity is discussed based on previously reported band structure calculations on SrRh$_2$P$_2$. Moreover, the effect of Rh fraction on the stress-induced structural transitions is also addressed by means of strain-stress studies done by uniaxial compression of single-crystalline micropillars of Sr(Ni$_{1-x}$Rh$_x$)$_2$P$_2$.

cond-mat.supr-con↗

arXiv2023

Vacancy Tuned Magnetism in LaMn$_x$Sb$_2$

The layered ATMPn$_2$ (A = alkali earth or rare earth atom, TM = transition metal, Pn = Sb, Bi) compounds are widely studied for their rich magnetism and electronic structure topology. Here, we characterize the physical properties of LaMn$_x$Sb$_2$, an understudied member of the ATMPn$_2$ family. LaMn$_x$Sb$_2$ forms with intrinsic Mn vacancies, and we demonstrate synthetic control of the Mn occupancy to produce single crystals with x = 0.74-0.97. Magnetization and transport measurements indicate LaMn$_x$Sb$_2$ has a rich temperature-composition (T-x) magnetic phase diagram with physical properties strongly influenced by the Mn occupancy. LaMn$_x$Sb$_2$ orders antiferromagnetically at T$_{1}$ = 130--180 K, where T$_{1}$ increases with x. Below T$_{1}$, the T-x phase diagram is complicated. At high x, there is a second transition T$_2$ that decreases in temperature as x is lowered, vanishing below x $\leq$ 0.85. A third, first-order, transition T$_3$ is detected at x $\approx$ 0.92, and the transition temperature increases as x is lowered, crossing above T$_2$ near x $\approx$ 0.9. On moving below x $<$ 0.79, we find the crystal structure changes from the P4/nmm arrangement to a I$\bar{4}$2m structure with partially ordered Mn vacancies. The change in crystal structure results in the appearance of two new low temperature phases and a crossover between regimes of negative and positive magnetoresistance. Finally, we provide neutron diffraction for x = 0.93, and find that the high x compositions first adopt a G-type AFM structure with the Mn moments aligned within the ab-plane which is followed on cooling by a second transition to a different, non-collinear structure where the moments are rotated within the basal plane. Our results demonstrate that LaMn$_x$Sb$_2$ is a highly tunable material with six unique magnetically ordered phases, depending on T and x.

cond-mat.mtrl-sci↗

arXiv2023

Unconventional nodal superconductivity in miassite Rh$_{17}$S$_{15}$

Unconventional superconductivity has long been believed to arise from a lab-grown correlated electronic system. Here we report compelling evidence of unconventional nodal superconductivity in a mineral superconductor \rhs. We investigated the temperature-dependent London penetration depth $Δλ(T)$ and disorder evolution of the critical temperature $T_c$ and upper critical field $H_{c2}(T)$ in synthetic miassite \rhs. We found a power-law behavior of $Δλ(T)\sim T^n$ with $n\approx 1.1$ at low temperatures below $0.3T_c$ ($T_c$ = 5.4 K), which is consistent with the presence of lines of the node in the superconducting gap of \rhs. The nodal character of the superconducting state in \rhs~was supported by the observed pairbreaking effect in $T_c$ and $H_{c2}(T)$ in samples with the controlled disorder that was introduced by low-temperature electron irradiation. We propose a nodal sign-changing superconducting gap in the $A_{1g}$ irreducible representation, which preserves the cubic symmetry of the crystal and is in excellent agreement with the superfluid density, $λ^2(0)/λ^2(T)$.

cond-mat.supr-con↗

arXiv2023

Coupling of magnetism and Dirac fermions in YbMnSb2

We report inelastic neutron scattering measurements of magnetic excitations in YbMnSb2, a low-carrier-density Dirac semimetal in which the antiferromagnetic Mn layers are interleaved with Sb layers that host Dirac fermions. We observe a considerable broadening of spin waves, which is consistent with substantial spin fermion coupling. The spin wave damping, $γ$, in YbMnSb2 is roughly twice larger compared to that in a sister material, YbMnBi2, where an indication of a small damping consistent with theoretical analysis of the spin-fermion coupling was reported. The inter-plane interaction between the Mn layers in YbMnSb2 is also much stronger, suggesting that the interaction mechanism is rooted in the same spin-fermion coupling. Our results establish the systematics of spin-fermion interactions in layered magnetic Dirac materials.

cond-mat.str-el↗

arXiv2022

Weak itinerant magnetic phases of La2Ni7

La2Ni7 is an intermetallic compound that is thought to have itinerant magnetism with a small moment ordering below 65 K. A recent study of single crystal samples by Ribeiro et. al. [Phys. Rev. B 105, 014412 (2022)] determined detailed anisotropic H-T phase diagrams and revealed three zero-field magnetic phase transitions at T1 ~ 61.0 K, T2 ~ 56.5K, and T3 ~ 42 K. In that study only the highest temperature phase is shown to have a clear ferromagnetic component. Here we present a single crystal neutron diffraction study determining the propagation vector and magnetic moment direction of the three magnetically ordered phases, two incommensurate and one commensurate, as a function of temperature. The higher temperature phases have similar, incommensurate propagation vectors, but with different ordered moment directions. At lower temperatures the magnetic order becomes commensurate with magnetic moments along the c direction as part of a first-order magnetic phase transition. We find that the low-temperature commensurate magnetic order is consistent with a proposal from earlier DFT calculations.

cond-mat.str-el↗

arXiv2021

Pressure-induced ferromagnetism in the topological semimetal EuCd$_2$As$_2$

The antiferromagnet and semimetal EuCd$_2$As$_2$ has recently attracted a lot of attention due to a wealth of topological phases arising from the interplay of topology and magnetism. In particular, the presence of a single pair of Weyl points is predicted for a ferromagnetic configuration of Eu spins along the $c$-axis in EuCd$_2$As$_2$. In the search for such phases, we investigate here the effects of hydrostatic pressure in EuCd$_2$As$_2$. For that, we present specific heat, transport and $μ$SR measurements under hydrostatic pressure up to $\sim\,2.5\,$GPa, combined with {\it ab initio} density functional theory (DFT) calculations. Experimentally, we establish that the ground state of EuCd$_2$As$_2$ changes from in-plane antiferromagnetic (AFM$_{ab}$) to ferromagnetic at a critical pressure of $\,\approx\,$2\,GPa, which is likely characterized by the moments dominantly lying within the $ab$ plane (FM$_{ab}$). The AFM$_{ab}$-FM$_{ab}$ transition at such a relatively low pressure is supported by our DFT calculations. Furthermore, our experimental and theoretical results indicate that EuCd$_2$As$_2$ moves closer to the sought-for FM$_c$ state (moments $\parallel$ $c$) with increasing pressure further. We predict that a pressure of $\approx$\,23\,GPa will stabilize the FM$_c$ state, if Eu remains in a 2+ valence state. Thus, our work establishes hydrostatic pressure as a key tuning parameter that (i) allows for a continuous tuning between magnetic ground states in a single sample of EuCd$_2$As$_2$ and (ii) enables the exploration of the interplay between magnetism and topology and thereby motivates a series of future experiments on this magnetic Weyl semimetal.

cond-mat.str-el↗

arXiv2018

Distinct pressure evolution of coupled nematic and magnetic order in FeSe

FeSe, despite being the structurally simplest compound in the family of iron-based superconductors, shows an astoundingly rich interplay of physical phenomena including nematicity and pressure-induced magnetism. Here, we present a microscopic study of these two phenomena by high-energy x-ray diffraction and time-domain Mössbauer spectroscopy on FeSe single crystals over a wide temperature and pressure range. The topology of the pressure-temperature phase diagram is a surprisingly close parallel to the well-known doping-temperature phase diagram of BaFe2As2 generated through partial Fe/Co and Ba/Na substitution. In FeSe with pressure p as a control parameter, the magneto-structural ground state can be tuned from "pure" nematic - paramagnetic with an orthorhombic lattice distortion - through a strongly coupled magnetically ordered and orthorhombic state to a magnetically ordered state without an orthorhombic lattice distortion. The magnetic hyperfine field increases monotonically over a wide pressure range. However, the orthorhombic distortion initially decreases under increasing pressure, but is stabilized by cooperative coupling to the pressure-induced magnetic order. Close to the reported maximum of the superconducting critical temperature Tc (occuring at p = 6.8 GPa), the orthorhombic distortion suddenly disappears and FeSe remains tetragonal down to the lowest temperature measured. Analysis of the structural and magnetic order parameters suggests an independent origin of the structural and magnetic ordering phenomena, and their cooperative coupling leads to the similarity with the canonical phase diagram of iron pnictides.

cond-mat.supr-con↗

arXiv2017

Collapsed Tetragonal Phase Transition in LaRu$_2$P$_2$

The structural properties of LaRu$_2$P$_2$ under external pressure have been studied up to 14 GPa, employing high-energy x-ray diffraction in a diamond-anvil pressure cell. At ambient conditions, LaRu$_2$P$_2$ (I4/mmm) has a tetragonal structure with a bulk modulus of $B=105(2)$ GPa and exhibits superconductivity at $T_c= 4.1$ K. With the application of pressure, LaRu$_2$P$_2$ undergoes a phase transition to a collapsed tetragonal (cT) state with a bulk modulus of $B=175(5)$ GPa. At the transition, the c-lattice parameter exhibits a sharp decrease with a concurrent increase of the a-lattice parameter. The cT phase transition in LaRu$_2$P$_2$ is consistent with a second order transition, and was found to be temperature dependent, increasing from $P=3.9(3)$ GPa at 160 K to $P=4.6(3)$ GPa at 300 K. In total, our data are consistent with the cT transition being near, but slightly above 2 GPa at 5 K. Finally, we compare the effect of physical and chemical pressure in the RRu$_2$P$_2$ (R = Y, La-Er, Yb) isostructural series of compounds and find them to be analogous.

cond-mat.supr-con↗

arXiv2017

Pressure induced half-collapsed-tetragonal phase in CaKFe$_4$As$_4$

We report the temperature-pressure phase diagram of CaKFe$_4$As$_4$ established using high pressure electrical resistivity, magnetization and high energy x-ray diffraction measurements up to 6 GPa. With increasing pressure, both resistivity and magnetization data show that the bulk superconducting transition of CaKFe$_4$As$_4$ is suppressed and then disappears at $p$ $\gtrsim$ 4 GPa. High pressure x-ray data clearly indicate a phase transition to a collapsed tetragonal phase in CaKFe$_4$As$_4$ under pressure that coincides with the abrupt loss of bulk superconductivity near 4 GPa. The x-ray data, combined with resistivity data, indicate that the collapsed tetragonal transition line is essentially vertical, occuring at 4.0(5) GPa for temperatures below 150 K. Band structure calculations also find a sudden transition to a collapsed tetragonal state near 4 GPa, as As-As bonding takes place across the Ca-layer. Bonding across the K-layer only occurs for $p$ $\geq$ 12 GPa. These findings demonstrate a new type of collapsed tetragonal phase in CaKFe$_4$As$_4$: a half-collapsed-tetragonal phase.

cond-mat.supr-con↗

arXiv2016

Discovery of unconventional charge density wave at the surface of K0.9Mo6O17

We use Angle Resolved Photoemission Spectroscopy (ARPES), Raman spectroscopy, Low Energy Electron Diffraction (LEED) and x-ray scattering to reveal an unusual electronically mediated charge density wave (CDW) in K0.9Mo6O17. Not only does K0.9Mo6O17 lack signatures of electron-phonon coupling, but it also hosts an extraordinary surface CDW, with TS CDW =220 K nearly twice that of the bulk CDW, TB CDW =115 K. While the bulk CDW has a BCS-like gap of 12 meV, the surface gap is ten times larger and well in the strong coupling regime. Strong coupling behavior combined with the absence of signatures of strong electron-phonon coupling indicates that the CDW is likely mediated by electronic interactions enhanced by low dimensionality.

cond-mat.str-el↗