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Abhishek Pradhan

Publications and source records attributed to Abhishek Pradhan.

4 recordsLinked to original sources

GuardianAgentBench: Where Agents Fail and How to Guard Them

As large language model agents increasingly operate autonomously with access to tools and external environments, ensuring their safe and reliable behavior becomes critical. We present GuardianAgentBench (GABench), a benchmark of 580 scenarios across six domains evaluated on three production-ready frameworks: LangChain, LlamaIndex, and Vectara. The benchmark incorporates rigorous multi-stage validation and five adversarial attack modes. Experiments with six state-of-the-art models reveal that even the strongest configuration achieves only 74.8% overall accuracy and expose two distinct failure regimes: stronger models under-call required tools, while weaker models mis-select and over-call tools. Performance degrades monotonically with both tool-set size and sequential turn depth, with long-horizon planning proving the steeper bottleneck. Our guardrail implementation consistently outperforms system-prompt-based defenses across all models, recovering 19.9% of failures at a false positive rate of just 0.5%. These results demonstrate that execution-time structural intervention improves safety without disrupting correct agent behavior.

cs.AI↗

Optimizing Ti substitution for the enhanced densification, ionic conductivity, and microstructure of garnet-type Li$_7$La$_3$Zr$_2$O$_{12}$ solid electrolytes

Garnet-type lithium lanthanum zirconium oxide Li$_7$La$_3$Zr$_2$O$_{12}$ (LLZO) is a favorable solid electrolyte for all-solid-state Li-ion batteries due to its wide electrochemical stability, compatible ionic conductivity, and good safety. However, further improvement in ionic conductivity is required for its practical applications. In this work, titanium (Ti) is doped into LLZO to enhance its Li-ion transport properties and structural stability. The series Li$_7$La$_3$Zr$_{2-x}$Ti$_x$O$_{12}$ has been successfully synthesized using conventional solid-state reaction method. The content of Ti has been varied from 0 to 0.20 atoms per formula unit (a.p.f.u). The conducting cubic phase has been confirmed by the X-ray diffraction technique (XRD). Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) have been used for structural analysis, and elemental distribution. Density measurements have been carried out for all the samples. Electrochemical impedance spectroscopy revealed that the high ionic conductivity of $8.08\times 10^{-5}$ Scm$^{-1}$ is offered by the Li$_7$La$_3$Zr$_{1.9}$Ti$_{0.1}$O$_{12}$ sample, which has the lowest activation energy of 0.37 eV. The DC polarization analysis verified that the main contribution to conductivity in the 0.10 Ti sample comes from ions. A one order of magnitude increase in room temperature ionic conductivity is observed for the 0.10 Ti sample, making it a strong candidate for solid electrolyte applications.

cond-mat.mtrl-sci↗

PowerGenie: Analytically-Guided Evolutionary Discovery of Superior Reconfigurable Power Converters

Discovering superior circuit topologies requires navigating an exponentially large design space-a challenge traditionally reserved for human experts. Existing AI methods either select from predefined templates or generate novel topologies at a limited scale without rigorous verification, leaving large-scale performance-driven discovery underexplored. We present PowerGenie, a framework for automated discovery of higher-performance reconfigurable power converters at scale. PowerGenie introduces: (1) an automated analytical framework that determines converter functionality and theoretical performance limits without component sizing or SPICE simulation, and (2) an evolutionary finetuning method that co-evolves a generative model with its training distribution through fitness selection and uniqueness verification. Unlike existing methods that suffer from mode collapse and overfitting, our approach achieves higher syntax validity, function validity, novelty rate, and figure-of-merit (FoM). PowerGenie discovers a novel 8-mode reconfigurable converter with 23% higher FoM than the best training topology. SPICE simulations confirm average absolute efficiency gains of 10% across 8 modes and up to 17% at a single mode. Code will be released upon publication.

cs.LG↗

Impact of Ce Substitution on Structural and Electrochemical Properties of Ga Doped Garnet Li7La3Zr2O12 Solid Electrolyte

In order to replace conventional liquid electrolytes, solid electrolyte should possess high ionic conductivity. In this study, the effects of Ga-Ce co-doping on the garnet Li7La3Zr2O12 solid electrolyte have been investigated. The series Li6.4Ga0.2La3Zr2-xCexO12 has been prepared with varying content of Ce from 0 to 0.30 atoms per formula unit (a.p.f.u.) by sintering at 1050^0C. Various structural characterizations namely X-diffraction, Scanning Electron Microscopy (SEM), density measurements were carried out. The electrochemical analysis suggested that, the sample with 0.10 a.p.f.u. of Ce offered the highest room temperature ionic conductivity of 4 x 10-4 S/cm with the minimum activation energy of 0.29 eV. Moreover, DC conductivity measurement proved the predominant ionic conduction in the prepared samples making it suitable for the application in all solid state Li-ion batteries (ASSLIBs).

cond-mat.mtrl-sci↗