arXiv subjects

Aditya Mishra

Publications and source records attributed to Aditya Mishra.

21 records · Page 2Linked to original sources

arXiv2020

Using LSTM for the Prediction of Disruption in ADITYA Tokamak

Major disruptions in tokamak pose a serious threat to the vessel and its surrounding pieces of equipment. The ability of the systems to detect any behavior that can lead to disruption can help in alerting the system beforehand and prevent its harmful effects. Many machine learning techniques have already been in use at large tokamaks like JET and ASDEX, but are not suitable for ADITYA, which is comparatively small. Through this work, we discuss a new real-time approach to predict the time of disruption in ADITYA tokamak and validate the results on an experimental dataset. The system uses selected diagnostics from the tokamak and after some pre-processing steps, sends them to a time-sequence Long Short-Term Memory (LSTM) network. The model can make the predictions 12 ms in advance at less computation cost that is quick enough to be deployed in real-time applications.

cs.LG↗

arXiv2020

Enhanced Operational Stability of Perovskite Light-Emitting Electrochemical Cells Leveraging Ionic Additives

Hybrid perovskites are emerging as highly efficient materials for optoelectronic applications, however, the operational lifetime has remained a limiting factor for the continued progress of perovskite light emitting devices such as light emitting diodes (LEDs) and perovskite light emitting electrochemical cells (PeLECs). In this work, PeLECs utilizing an optimized fraction of LiPF6 salt additive exhibit enhanced stability. At 0.5 wt% LiPF6, devices exhibit 100 h operation at high brightness in excess of 800 cd/m2 under constant current driving, achieving a maximum luminance of 3260 cd/m2 and power efficiency of 9.1 Lm/W. This performance extrapolates to a 6700 h luminance half-life from 100 cd/m2, a 5.6-fold improvement over devices with no lithium salt additive. Analysis under constant voltage driving reveals three current regimes, with lithium addition strongly enhancing current in the second and third regimes. The third regime correlates degradation of luminance with decreased current. These losses are mitigated by LiPF6 addition, an effect postulated to arise from preservation of perovskite structure. To further understand lithium salt addition, electrochemical impedance spectroscopy with equivalent circuit modeling is performed. Electrical double layer widths from ionic redistribution are minimized at 0.5wt% LiPF6 and inversely correlate with efficient performance.

cond-mat.mtrl-sci↗

arXiv2019

Bright and Efficient Perovskite Light Emitting Electrochemical Cells Leveraging Ionic Additives

Perovskite light-emitting diodes (PeLEDs) have drawn considerable attention for their favorable optoelectronic properties. Perovskite light-emitting electrochemical cells (PeLECs) _ devices that utilize mobile ions _ have recently been reported but have yet to reach the performance of the best PeLEDs. We leveraged a poly(ethylene oxide) electrolyte and lithium dopant in CsPbBr3 thin films to produce PeLECs of improved brightness and efficiency. In particular, we found that a single layer PeLEC from CsPbBr3:PEO:LiPF6 with 0.5% wt. LiPF6 produced highly efficient (22 cd/A) and bright (~15000 cd/m2) electroluminescence. To understand this improved performance among PeLECs, we characterized these perovskite thin films with photoluminescence (PL) spectroscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD). These studies revealed that this optimal LiPF6 concentration improves electrical double layer formation, reduces the occurrence of voids, charge traps, and pinholes, and increases grain size and packing density.

physics.app-ph↗