arXiv subjects

Adwin Boogert

Publications and source records attributed to Adwin Boogert.

At least 19 recordsLinked to original sources

arXiv2026

Dust Absorption towards Supernova Remnant W44

Supernova remnants (SNRs) can strongly affect the chemical composition of the interstellar dust. In this paper we investigate to what degree the dust and ices are modified by observing four stars expected to be absorbed by a giant molecular cloud interacting with SNR W44, using medium-resolution spectroscopy in 2-5 $\mu$m. Absorption from H2O ice around 3.0 $\mu$m and aliphatic hydrocarbon dust around 3.4 $\mu$m were detected towards two stars, while probable CO ice at 4.67 $\mu$m towards one of them. Millimeter gas-phase CO J = 1-0 lines and three-dimensional dust extinction maps show that the dense molecular gas associated with W44 dominates (> 60%) the total interstellar extinction (A_K ~ 2.6) along these two sightlines. The H2O ice column densities are a factor of 1.5-3 lower than nearby MCs at similar extinctions, possibly because of the destruction of ice by shocks and cosmic rays (CRs) from W44, consistent with the low CO ice abundance relative to H2O (< 12%). One of the sightlines shows an unusually strong 3.4 $\mu$m aliphatic hydrocarbon absorption. If the carriers are located in diffuse dust along the sightline, unrelated to W44, its strength is ~ 4 times larger than those typically observed for diffuse dust clouds. Alternatively, the carriers may be enhanced in the W44 environment. We discuss several possible explanations, including shock formation of aliphatic hydrocarbons in diffuse clouds associated with W44, contribution from aliphatic hydrocarbons in shocked and CR-bombarded molecular clouds, and changes in the extinction law due to the SNR interaction.

astro-ph.GA↗

arXiv2026

The Outflow of the B335 Protostar II: After the Outburst

The B335 protostar has recently undergone a major, still ongoing, outburst detected in scattered light from its outflow cavity, offering a rare opportunity to study its impact on a protostellar jet. We use JWST/NIRCam photometry of background stars behind B335 from 2.7 to 4.4 $\mu$m to map extinction and H$_2$O ice absorption, showing that the outflow has carved a cavity in the molecular core. We measure proper motions of shock fronts emerging from the protostar of 131--227 km s$^{-1}$. The kinematic age of the most prominent shock front, 3E, corresponds to the early phase of the current outburst. JWST/NIRSpec IFU data show that the youngest shock, 2E, exhibits ionic lines but no molecular emission. Shock 3E shows strong CO emission together with H$_2$ and [\ion{Fe}{2}], whereas older shocks show weaker CO and are dominated by H$_2$ and [\ion{Fe}{2}]. The feature 0E, closest to the protostar, appears to be a stationary shock. CO-line-removed spectra near the protostar show that the unsaturated absorption features of $^{13}$CO$_2$, OCN$^-$, and OCS increase strongly toward the source. The ice properties are otherwise similar to those along lower-extinction sight lines. In the central bipolar reflection nebula, CO gas is seen in scattered emission from the immediate protostellar surroundings, but a few arcsec farther out, absorption by cooler CO gas in the outflow cavity is detected.

astro-ph.SR↗

arXiv2025

A Comprehensive Analysis of Rovibrational CO in the Era of JWST

We present an analysis of CO rovibrational emission lines in the 183 infrared spectra of nearby Class II objects obtained with the NIRSPEC instrument on the Keck II telescope over the past two decades. The sample includes a broad range of stellar mass (both T Tauri and Herbig Ae/Be) and disk evolutionary states (from full to debris disks). We find that 53% of the sample has CO rovibrational emission lines present in their spectrum with disk/stellar subtype detection rates of 82% for transition disks, 61% for Herbigs, and 77% for CTTSs. Although there is no discernible difference between T Tauri and Herbig Ae/Be star CO detection rates, the detection of accretion and of CO are statistically correlated in T Tauri stars but not in Herbig Ae/Be objects. Within the sample of T Tauri stars, we find that no weak-line T Tauri stars have CO rovibrational emission lines. We use slab modeling to analyze the density, temperature, and emitting area of the sample. The retrieval results imply that Herbig Ae/Be objects tend to have cooler and larger CO emitting regions than T Tauri stars. We find that the CO emitting area is not a thin ring as defined by temperature, but a ring of varying size likely dependent on the structure of the disk. We also present guidelines on how to approach CO rovibrational emission lines in JWST spectra and present methods for linking ground-based observations with JWST spectra. This includes line-to-continuum ratio estimates based on stellar mass and accretion rate.

astro-ph.SR↗

arXiv2024

Ammonium hydrosulfide (NH4SH) as a potentially significant sulfur sink in interstellar ices

Sulfur is depleted with respect to its cosmic standard abundance in dense star-forming regions. It has been suggested that this depletion is caused by the freeze-out of sulfur on interstellar dust grains, but the observed abundances and upper limits of sulfur-bearing ices remain too low to account for all of the missing sulfur. Toward the same environments, a strong absorption feature at 6.85 $μ$m is observed, but its long-standing assignment to the NH4+ cation remains tentative. We investigate the plausibility of NH4SH salt serving as a sulfur reservoir and a carrier of the 6.85 $μ$m band in interstellar ices by characterizing its IR signatures and apparent band strengths in water-rich laboratory ice mixtures and using this laboratory data to constrain NH4SH abundances in observations of 4 protostars and 2 cold dense clouds. The observed 6.85 $μ$m feature is fit well with the laboratory NH4SH:H2O ice spectra. NH4+ column densities obtained from the 6.85 $μ$m band range from 8-23% with respect to H2O toward the sample of protostars and dense clouds. The redshift of the 6.85 $μ$m feature correlates with higher abundances of NH4+ with respect to H2O in both the laboratory data presented here and observational data of dense clouds and protostars. The apparent band strength of the SH- feature is likely too low for the feature to be detectable in the spectrally busy 3.9 $μ$m region, but the 5.3 $μ$m NH4+ $ν_{4}$ + SH- R combination mode may be an alternative means of detection. Its tentative assignment adds to mounting evidence supporting the presence of NH4+ salts in ices and is the first tentative observation of the SH- anion toward interstellar ices. If the majority ($\gtrsim$80-85%) of the NH4+ cations quantified toward the investigated sources in this work are bound to SH- anions, then NH4SH salts could account for up to 17-18% of their sulfur budgets.

astro-ph.GA↗

arXiv2024

On the Interpretation of Mid-Infrared Absorption Lines of Gas-Phase H$_2$O as Observed by JWST/MIRI

Ro-vibrational absorption lines of H$_2$O in the 5-8 $μ$m wavelength range selectively probe gas against the mid-infrared continuum emitting background of the inner regions of YSOs and AGN and deliver important information about these warm, dust-obscured environments. JWST/MIRI detects these lines in many lines of sight at a moderate spectral resolving power of $R\sim3500$ (FWHM of 85 km/s). Based on our analysis of high-resolution SOFIA/EXES observations, we find that the interpretation of JWST/MIRI absorption spectra can be severely hampered by the blending of individual transitions and the lost information on the intrinsic line width or the partial coverage of the background continuum source. In this paper, we point out problems such as degeneracy that arise in deriving physical properties from an insufficiently resolved spectrum. This can lead to differences in the column density by two orders of magnitude. We emphasize the importance of weighting optically thin and weak lines in spectral analyses and provide recipes for breaking down the coupled parameters. We also provide an online tool to generate the H$_2$O absorption line spectra that can be compared to observations.

astro-ph.IM↗

arXiv2023

High-resolution SOFIA/EXES Spectroscopy of Water Absorption Lines in the Massive Young Binary W3 IRS 5

We present in this paper mid-infrared (5-8~$μ$m) spectroscopy toward the massive young binary W3~IRS~5, using the EXES spectrometer in high-resolution mode ($R\sim$50,000) from the NASA Stratospheric Observatory for Infrared Astronomy (SOFIA). Many ($\sim$180) $ν_2$=1--0 and ($\sim$90) $ν_2$=2-1 absorption rovibrational transitions are identified. Two hot components over 500 K and one warm component of 190 K are identified through Gaussian fittings and rotation diagram analysis. Each component is linked to a CO component identified in the IRTF/iSHELL observations ($R$=88,100) through their kinematic and temperature characteristics. Revealed by the large scatter in the rotation diagram, opacity effects are important, and we adopt two curve-of-growth analyses, resulting in column densities of $\sim10^{19}$ cm$^{-2}$. In one analysis, the model assumes a foreground slab. The other assumes a circumstellar disk with an outward-decreasing temperature in the vertical direction. The disk model is favored because fewer geometry constraints are needed, although this model faces challenges as the internal heating source is unknown. We discuss the chemical abundances along the line of sight based on the CO-to-H$_2$O connection. In the hot gas, all oxygen not locked in CO resides in water. In the cold gas, we observe a substantial shortfall of oxygen and suggest that the potential carrier could be organics in solid ice.

astro-ph.GA↗

arXiv2022

The kinematics and excitation of infrared water vapor emission from planet-forming disks: results from spectrally-resolved surveys and guidelines for JWST spectra

This work presents ground-based spectrally-resolved water emission at R = 30000-100000 over infrared wavelengths covered by JWST (2.9-12.8 $μ$m). Two new surveys with iSHELL and VISIR are combined with previous spectra from CRIRES and TEXES to cover parts of multiple ro-vibrational and rotational bands observable within telluric transmission bands, for a total of $\approx160$ spectra and 85 disks (30 of which are JWST targets in Cycle 1). The general expectation of a range of regions and excitation conditions traced by infrared water spectra is for the first time supported by the combined kinematics and excitation as spectrally resolved at multiple wavelengths. The main findings from this analysis are: 1) water lines are progressively narrower from the ro-vibrational bands at 2-9 $μ$m to the rotational lines at 12 $μ$m, and partly match a broad (BC) and narrow (NC) emission components, respectively, as extracted from ro-vibrational CO spectra; 2) rotation diagrams of resolved water lines from upper level energies of 4000-9500 K show vertical spread and curvatures indicative of optically thick emission ($\approx 10^{18}$ cm$^{-2}$) from a range of excitation temperatures ($\approx 800$-1100 K); 3) the new 5 $μ$m spectra demonstrate that slab model fits to the rotational lines at $> 10$ $μ$m strongly over-predict the ro-vibrational emission bands at $< 9$ $μ$m, implying non-LTE vibrational excitation. We discuss these findings in the context of emission from a disk surface and a molecular inner disk wind, and provide a list of guidelines to support the analysis of spectrally-unresolved JWST spectra.

astro-ph.EP↗

arXiv2022

Ammonia, carbon dioxide and the non-detection of the 2152 cm$^{-1}$ CO band

CO is one of the most abundant ice components on interstellar dust grains. When it is mixed with amorphous solid water (ASW) or located on its surface, an absorption band of CO at 2152 cm$^{-1}$ is always present in laboratory measurements. This spectral feature is attributed to the interaction of CO with dangling-OH bonds (dOH) in ASW. However, this band is absent in observational spectra of interstellar ices. This raises the question whether CO forms a relatively pure layer on top of ASW or is in close contact with ASW, but not via dangling bonds. We aim to determine whether the incorporation of NH$_3$ or CO$_2$ into ASW blocks the dOH and therefore reduces the 2152 cm$^{-1}$ band. We performed laboratory experiments to simulate the layered structure of the ice mantle, that is, we grew CO ice on top of 1) pure ASW, 2) NH$_3$:H$_2$O=10:100 mixed ice, and 3) CO$_2$:H$_2$O=20:100 mixed ice. Infrared spectra were measured to quantify the strength of the 2152 cm$^{-1}$ band. In addition, a second set of experiments were performed to determine how the incorporation of NH$_3$ into ASW affects the dOH band. We found that annealing the ice reduces the 2152 cm$^{-1}$ band and that NH$_3$ blocks the dOH on ASW surface and therefore reduces the 2152 cm$^{-1}$ band more effectively than CO$_2$. We suggest that this difference between NH$_3$ and CO$_2$ can be ascribed to the polarity of the guest molecule (NH$_3$ is a polar species, whereas CO$_2$ is apolar). The polarity implies that the formation of an H-bond between the N atom of ammonia and the dOH is a barrier-less reaction. We also determined the pore surface area of the ice mixtures as a function of the annealing temperature, and found that the nondetection of 2152 cm$^{-1}$ band does not necessarily exclude the possibility of a porous ice mantle.

astro-ph.IM↗

arXiv2022

Ice Age : Chemo-dynamical modeling of Cha-MMS1 to predict new solid-phase species for detection with JWST

Chemical models and experiments indicate that interstellar dust grains and their ice mantles play an important role in the production of complex organic molecules (COMs). To date, the most complex solid-phase molecule detected with certainty in the ISM is methanol, but the James Webb Space Telescope (JWST) may be able to identify still larger organic species. In this study, we use a coupled chemo-dynamical model to predict new candidate species for JWST detection toward the young star-forming core Cha-MMS1, combining the gas-grain chemical kinetic code MAGICKAL with a 1-D radiative hydrodynamics simulation using Athena++. With this model, the relative abundances of the main ice constituents with respect to water toward the core center match well with typical observational values, providing a firm basis to explore the ice chemistry. Six oxygen-bearing COMs (ethanol, dimethyl ether, acetaldehyde, methyl formate, methoxy methanol, and acetic acid), as well as formic acid, show abundances as high as, or exceeding, 0.01% with respect to water ice. Based on the modeled ice composition, the infrared spectrum is synthesized to diagnose the detectability of the new ice species. The contribution of COMs to IR absorption bands is minor compared to the main ice constituents, and the identification of COM ice toward the core center of Cha-MMS1 with the JWST NIRCAM/Wide Field Slitless Spectroscopy (2.4-5.0 micron) may be unlikely. However, MIRI observations (5-28 micron) toward COM-rich environments where solid-phase COM abundances exceed 1% with respect to the water ice column density might reveal the distinctive ice features of COMs.

astro-ph.SR↗

arXiv2022

High-Resolution M-band Spectroscopy of CO towards the Massive Young Stellar Binary W3 IRS5

We present in this paper the results of high spectral resolution ($R$=88,100) spectroscopy at 4.7 $μ$m with iSHELL/IRTF of hot molecular gas close to the massive binary protostar W3 IRS5. The binary was spatially resolved and the spectra of the two sources (MIR1 and MIR2) were obtained simultaneously for the first time. Hundreds of $^{12}$CO $ν$=0-1, $ν$=1-2 lines, and $ν$=0-1 transitions of the isotopes of $^{12}$CO were detected in absorption, and are blue-shifted compared to the cloud velocity $v_{LSR}=-$38 km/s. We decompose and identify kinematic components from the velocity profiles, and apply rotation diagram and curve of growth analyses to determine their physical properties. Temperatures and column densities of the identified components range from 30$-$700 K and 10$^{21}-$10$^{22}$ cm$^{-2}$, respectively. Our curve of growth analyses consider two scenarios. One assumes a foreground slab with a partial covering factor, which well reproduces the absorption of most of the components. The other assumes a circumstellar disk with an outward decreasing temperature in the vertical direction, and reproduces the absorption of all the hot components. We attribute the physical origins of the identified components to the foreground envelope ($<$100 K), post-J-shock regions (200$-$300 K), and clumpy structures on the circumstellar disks ($\sim$600 K). We propose that the components with a J-shock origin are akin to water maser spots in the same region, and are complementing the physical information of water masers along the direction of their movements.

astro-ph.GA↗

arXiv2022

Scanning disk rings and winds in CO at 0.01-10 au: a high-resolution $M$-band spectroscopy survey with IRTF-iSHELL

We present an overview and first results from a $M$-band spectroscopic survey of planet-forming disks performed with iSHELL on IRTF, using two slits that provide resolving power R $\approx$ 60,000-92,000 (5-3.3 km/s). iSHELL provides a nearly complete coverage at 4.52-5.24 $μ$m in one shot, covering $>50$ lines from the R and P branches of $^{12}$CO and $^{13}$CO for each of multiple vibrational levels, and providing unprecedented information on the excitation of multiple emission and absorption components. Some of the most notable new findings of this survey are: 1) the detection of two CO Keplerian rings at $<2$ au (in HD 259431), 2) the detection of H${_2}$O ro-vibrational lines at 5 $μ$m (in AS 205 N), and 3) the common kinematic variability of CO lines over timescales of 1-14 years. By homogeneously analyzing this survey together with a previous VLT-CRIRES survey of cooler stars, we discuss a unified view of CO spectra where emission and absorption components scan the disk surface across radii from a dust-free region within dust sublimation out to $\approx10$ au. We classify two fundamental types of CO line shapes interpreted as emission from Keplerian rings (double-peak lines) and a disk surface plus a low-velocity part of a wind (triangular lines), where CO excitation reflects different emitting regions (and their gas-to-dust ratio) rather than just the irradiation spectrum. A disk+wind interpretation for the triangular lines naturally explains several properties observed in CO spectra, including the line blue-shifts, line shapes that turn into narrow absorption at high inclinations, and the frequency of disk winds as a function of stellar type.

astro-ph.SR↗

arXiv2020

High Resolution Infrared Spectroscopy of Hot Molecular Gas in AFGL 2591 and AFGL 2136: Accretion in the Inner Regions of Disks Around Massive Young Stellar Objects

We have performed a high resolution 4-13 $μm$ spectral survey of the hot molecular gas associated with the massive protostars AFGL 2591 and AFGL 2136, utilising the Echelon-Cross-Echelle-Spectrograph (EXES) on-board the Stratospheric Observatory for Infrared Astronomy (SOFIA), and the iSHELL instrument and Texas Echelon Cross Echelle Spectrograph (TEXES) on the NASA Infrared Telescope Facility (IRTF). Here we present results of this survey with analysis of CO, HCN, C$_2$H$_2$, NH$_3$ and CS, deriving the physical conditions for each species. Also from the IRTF, iSHELL data at 3 $μm$ for AFGL 2591 are presented that show HCN and C$_2$H$_2$ in emission. In the EXES and TEXES data, all species are detected in absorption, and temperatures and abundances are found to be high (600 K and 10$^{-6}$, respectively). Differences of up to an order of magnitude in the abundances of transitions that trace the same ground state level are measured for HCN and C$_2$H$_2$. The mid-infrared continuum is known to originate in a disk, hence we attribute the infrared absorption to arise in the photosphere of the disk. As absorption lines require an outwardly decreasing temperature gradient, we conclude that the disk is heated in the mid-plane by viscous heating due to accretion. We attribute the near-IR emission lines to scattering by molecules in the upper layers of the disk photosphere. The absorption lines trace the disk properties at 50 AU where a high temperature gas-phase chemistry is taking place. Abundances are consistent with chemical models of the inner disk of Herbig disks.

astro-ph.GA↗

arXiv2019

Measuring the magnetic field of young stars using iSHELL observations: BP Tau and V347 Aur

While it has been suggested that there is a connection between the magnetic properties and the internal structure of young stars, there have not been enough magnetic measurements to firmly establish such a correlation at the earliest ages. Here, we contribute to this endeavor by presenting stellar parameters and magnetic field strength measurements of BP Tau and V347 Aur, both stars observed with the near-infrared spectrograph iSHELL. We first test the accuracy of our method by fitting synthetic stellar spectra to a sample of nine main and post-main-sequence stars. We report uncertainties of $σ_{\rm Teff}$ = 91 K in temperature and $σ_{\rm log(g)}$ = 0.14 in gravity. We then apply the modeling technique to BP Tau and measure a surface magnetic field strength of $\langle \rm B \rangle $ = 2.5$^{+0.15}_{-0.16}$ kG, confirming literature results. For this star, however, we obtain a much lower temperature value than previous optical studies ($Δ\rm T \sim 400$ K) and interpret this significant temperature difference as due to the relatively higher impact of starspots at near-infrared wavelengths than at optical wavelengths. We further apply this technique to the class I protostellar source V347 Aur and measure for the first time its magnetic field strength $\langle \rm B \rangle = $ 1.36$^{+0.06}_{-0.05}$ kG and its surface gravity log(g) = 3.25$^{+0.14}_{-0.14}$. Lastly, we combine our measurements with pre-main-sequence stellar evolutionary models and illustrate the effects produced by starspots on the retrieved masses and ages of young stars.

astro-ph.SR↗

arXiv2018

High-Resolution SOFIA/EXES Spectroscopy of $\mathrm{SO}_2$ Gas in the Massive Young Stellar Object MonR2 IRS3: Implications for the Sulfur Budget

Sulfur has been observed to be severely depleted in dense clouds leading to uncertainty in the molecules that contain it and the chemistry behind their evolution. Here, we aim to shed light on the sulfur chemistry in young stellar objects (YSOs) by using high-resolution infrared spectroscopy of absorption by the $ν_3$ rovibrational band of SO$_2$ obtained with the Echelon-Cross-Echelle Spectrograph on the Stratospheric Observatory for Infrared Astronomy. Using local thermodynamic equilibrium models we derive physical parameters for the SO$_2$ gas in the massive YSO MonR2 IRS3. This yields a SO$_2$/$\mathrm{H}$ abundance lower limit of $5.6\pm0.5\times10^{-7}$, or $>\!4\%$ of the cosmic sulfur budget, and an intrinsic line width (Doppler parameter) of $b<3.20\;\mathrm{km\;s}^{-1}$. The small line widths and high temperature ($T_\mathrm{ex}=234\pm15\;\mathrm{K}$) locate the gas in a relatively quiescent region near the YSO, presumably in the hot core where ices have evaporated. This sublimation unlocks a volatile sulfur reservoir (e.g., sulfur allotropes as detected abundantly in comet 67P/Churyumov--Gerasimenko), which is followed by SO$_2$ formation by warm, dense gas-phase chemistry. The narrowness of the lines makes formation of SO$_2$ from sulfur sputtered off grains in shocks less likely toward MonR2 IRS3.

astro-ph.SR↗

arXiv2018

Infrared Detection of Abundant CS in the Hot Core AFGL 2591 at High Spectral Resolution with SOFIA/EXES

We have performed a 5-8 $μ$m spectral line survey of the hot molecular core associated with the massive protostar AFGL 2591, using the Echelon-Cross-Echelle Spectrograph (EXES) on the Stratospheric Observatory for Infrared Astronomy (SOFIA). We have supplemented these data with a ground based study in the atmospheric M band around 4.5 $μ$m using the iSHELL instrument on the Infrared Telescope Facility (IRTF), and the full N band window from 8-13 $μ$m using the Texas Echelon Cross Echelle Spectrograph (TEXES) on the IRTF. Here we present the first detection of ro-vibrational transitions of CS in this source. The absorption lines are centred on average around -10 kms$^{-1}$ and the line widths of CS compare well with the hot component of $^{13}$CO (around 10 kms$^{-1}$). Temperatures for CS, hot $^{13}$CO and $^{12}$CO v=1-2 agree well and are around 700 K. We derive a CS abundance of 8$\times$10$^{-3}$ and 2$\times$10$^{-6}$ with respect to CO and H$_2$ respectively. This enhanced CS abundance with respect to the surrounding cloud (1$\times$10$^{-8}$) may reflect sublimation of H$_2$S ice followed by gas-phase reactions to form CS. Transitions are in LTE and we derive a density of $>$10$^7$ cm$^{-3}$, which corresponds to an absorbing region of $<$0.04$''$. EXES observations of CS are likely to probe deeply into the hot core, to the base of the outflow. Submillimeter and infrared observations trace different components of the hot core as revealed by the difference in systemic velocities, line widths and temperatures, as well as the CS abundance.

astro-ph.GA↗

arXiv2018

The $^{12}$CO$_2$ and $^{13}$CO$_2$ Absorption Bands as Tracers of the Thermal History of Interstellar Icy Grain Mantles

Analyses of infrared signatures of CO$_2$ in water dominated ices in the ISM can give information on the physical state of CO$_2$ in icy grains and on the thermal history of the ices themselves. In many sources, CO$_2$ was found in the `pure' crystalline form, as signatured by the splitting in the bending mode absorption profile. To a large extent, pure CO$_2$ is likely to have formed from segregation of CO$_2$ from a CO$_2$:H$_2$O mixture during thermal processing. Previous laboratory studies quantified the temperature dependence of segregation, but no systematic measurement of the concentration dependence of segregation is available. In this study, we measured both the temperature dependence and concentration dependence of CO$_2$ segregation in CO$_2$:H$_2$O mixtures, and found that no pure crystalline CO$_2$ forms if the CO$_2$:H$_2$O ratio is less than 23%. Therefore the segregation of CO$_2$ is not always a good thermal tracer of the ice mantle. We found that the position and width of the broad component of the asymmetric stretching vibrational mode of $^{13}$CO$_2$ change linearly with the temperature of CO$_2$:H$_2$O mixtures, but are insensitive to the concentration of CO$_2$. We recommend using this mode, which will be observable towards low mass protostellar envelopes and dense clouds with the James Webb Space Telescope, to trace the thermal history of the ice mantle, especially when segregated CO$_2$ is unavailable. We used the laboratory measured $^{13}$CO$_2$ profile to analyze the ISO-SWS observations of ice mantles towards Young Stellar Objects, and the astrophysical implications are discussed.

astro-ph.IM↗

arXiv2018

High Spectral Resolution SOFIA/EXES Observations of C2H2 towards Orion-IRc2

We present high-spectral resolution observations from 12.96 - 13.33 microns towards Orion IRc2 using the mid-infrared spectrograph, EXES, on SOFIA. These observations probe the physical and chemical conditions of the Orion hot core, which is sampled by a bright, compact, mid-infrared background continuum source in the region, IRc2. All ten of the rovibrational C2H2 transitions expected in our spectral coverage, are detected with high S/N, yielding continuous coverage of the R-branch lines from J=9-8 to J=18-17, including both ortho and para species. Eight of these rovibrational transitions are newly reported detections. The isotopologue, 13CCH2, is clearly detected with high signal-to-noise. This enabled a direct measurement of the 12C/13C isotopic ratio for the Orion hot core of 14 +/- 1 and an estimated maximum value of 21. We also detected several HCN rovibrational lines. The ortho and para C2H2 ladders are clearly separate and tracing two different temperatures, 226 K and 164 K, respectively, with a non-equilibrium ortho to para ratio (OPR) of 1.7 +\- 0.1. Additionally, the ortho and para V_LSR values differ by about 1.8 +/- 0.2 km/s, while, the mean line widths differ by 0.7 +/- 0.2 km/s, suggesting that these species are not uniformly mixed along the line of sight to IRc2. We propose that the abnormally low C2H2 OPR could be a remnant from an earlier, colder phase, before the density enhancement (now the hot core) was impacted by shocks generated from an explosive event 500 yrs ago.

astro-ph.GA↗

arXiv2016

Science Impacts of the SPHEREx All-Sky Optical to Near-Infrared Spectral Survey: Report of a Community Workshop Examining Extragalactic, Galactic, Stellar and Planetary Science

SPHEREx is a proposed SMEX mission selected for Phase A. SPHEREx will carry out the first all-sky spectral survey and provide for every 6.2" pixel a spectra between 0.75 and 4.18 $μ$m [with R$\sim$41.4] and 4.18 and 5.00 $μ$m [with R$\sim$135]. The SPHEREx team has proposed three specific science investigations to be carried out with this unique data set: cosmic inflation, interstellar and circumstellar ices, and the extra-galactic background light. It is readily apparent, however, that many other questions in astrophysics and planetary sciences could be addressed with the SPHEREx data. The SPHEREx team convened a community workshop in February 2016, with the intent of enlisting the aid of a larger group of scientists in defining these questions. This paper summarizes the rich and varied menu of investigations that was laid out. It includes studies of the composition of main belt and Trojan/Greek asteroids; mapping the zodiacal light with unprecedented spatial and spectral resolution; identifying and studying very low-metallicity stars; improving stellar parameters in order to better characterize transiting exoplanets; studying aliphatic and aromatic carbon-bearing molecules in the interstellar medium; mapping star formation rates in nearby galaxies; determining the redshift of clusters of galaxies; identifying high redshift quasars over the full sky; and providing a NIR spectrum for most eROSITA X-ray sources. All of these investigations, and others not listed here, can be carried out with the nominal all-sky spectra to be produced by SPHEREx. In addition, the workshop defined enhanced data products and user tools which would facilitate some of these scientific studies. Finally, the workshop noted the high degrees of synergy between SPHEREx and a number of other current or forthcoming programs, including JWST, WFIRST, Euclid, GAIA, K2/Kepler, TESS, eROSITA and LSST.

astro-ph.CO↗