arXiv subjects

Agham Posadas

Publications and source records attributed to Agham Posadas.

4 recordsLinked to original sources

arXiv2026

Hybrid BaTiO3/TiO2 Metasurface for Efficient Gigahertz-Speed Free-Space Electro-Optic Modulation

Free-space electro-optic modulators are key to emerging photonic systems, yet their performance remains limited by trade-offs between modulation efficiency, bandwidth, and device aperture. Here we report a hybrid BaTiO3 (BTO)/TiO2 metasurface for large-aperture, efficient, gigahertz-speed free-space electro-optic modulation. Combining scalable BTO film growth by radio-frequency magnetron sputtering with mature TiO2 nanofabrication, we pattern the metasurface in TiO2 on an unetched BTO layer. The resulting devices support guided-mode resonances with quality factors exceeding 1300 and an optical confinement factor of ~0.8, while the continuous BTO layer makes efficient use of the applied voltage, together maximizing the overlap between the optical and driving fields within the BTO. A device with a 0.3 mm x 0.3 mm metasurface achieves a transmittance modulation efficiency of ~0.020 per volt and a -3 dB electro-optic bandwidth of ~0.8 GHz, with an effective Pockels coefficient of ~151 pm/V for the BTO. This establishes a scalable route to high-performance free-space electro-optic modulators for LiDAR, free-space optical communication, and reconfigurable optical computing.

physics.optics↗

arXiv2026

High Coupling Tunable Acoustic Resonators in Monolithic Barium Titanate

The growing number of wireless communication bands has driven demand for compact, low-loss, and frequency adjustable RF filtering. Tunable acoustic resonators are well suited to address these needs, offering a path toward reconfigurable front ends with reduced component count. In this work, we extend upon previous conference results to investigate epitaxial barium titanate (BTO) grown on silicon as a platform for tunable acoustic resonators. We demonstrate lateral excitation of symmetric Lamb (S0) modes in 120 nm X-cut BTO membranes using a multi-cell electrode architecture that simultaneously achieves high electromechanical coupling and practical impedance levels. Devices are fabricated with laterally patterned electrodes on released BTO membranes. Under applied DC bias, ferroelectric domains align, allowing electrical excitation, frequency tuning, and quality-factor enhancement of acoustic modes. The primary resonance near 700 MHz exhibits a Bode quality factor of 175, electromechanical coupling up to 25.1%, and series and parallel resonance tunability of 2.3% and 5.6%, respectively. Voltage-dependent material parameters, including permittivity, stiffness, and piezoelectric coefficients, are extracted through a combination of modified Butterworth-Van Dyke modeling and finite-element simulation to explain the observed trends. These results highlight monolithic BTO on silicon as a promising material system for laterally excited, tunable acoustic resonators for reconfigurable RF applications.

eess.SP↗

arXiv2026

Tunable Ferroelectric Acoustic Resonators in Monolithic Thin-Film Barium Titanate

The increasing development of wireless communication bands has motivated the development of compact, low-loss, and frequency adjustable RF filtering technologies. Acoustic resonators are the ideal solution to these requirements, and tunable implementations offer a path toward reconfigurable front ends. In this work, we investigate epitaxial barium titanate (BTO) grown on silicon as a platform for tunable acoustic resonators operating in the sub-GHz regime. We demonstrate lateral excitation of symmetric lamb (S0) modes in X-cut BTO membranes, in contrast to prior thickness-defined ferroelectric resonators. Devices are designed using finite-element simulations and fabricated with laterally patterned electrodes that enable overtone coupling to multiple resonant modes. Under applied DC bias, ferroelectric domains align, allowing electrical excitation, frequency tuning, and quality-factor enhancement of acoustic modes. Resonances near 300 MHz and 700 MHz exhibit electromechanical coupling up to 8% and bias-dependent frequency tuning, with a distinct transition in behavior near 20 V. These results highlight monolithic BTO on silicon as a promising material system for laterally excited, tunable acoustic resonators for reconfigurable RF applications.

eess.SY↗

arXiv2015

Final-state effect on x-ray photoelectron spectrum of nominally $d^1$ and $n$-doped $d^0$ transition metal oxides

We investigate the x-ray photoelectron spectroscopy (XPS) of nominally $d^1$ and $n$-doped $d^0$ transition metal oxides including NbO$_2$, SrVO$_3$, and LaTiO$_3$ (nominally $d^1$), as well as $n$-doped SrTiO$_3$ (nominally $d^0$). In the case of single phase $d^1$ oxides, we find that the XPS spectra (specifically photoelectrons from Nb $3d$, V $2p$, Ti $2p$ core levels) all display at least two, and sometimes three distinct components, which can be consistently identified as $d^0$, $d^1$, and $d^2$ oxidation states (with decreasing order in binding energy). Electron doping increases the $d^2$ component but decreases the $d^0$ component, whereas hole doping reverses this trend; a single $d^1$ peak is never observed, and the $d^0$ peak is always present even in phase-pure samples. In the case of $n$-doped SrTiO$_3$, the $d^1$ component appears as a weak shoulder with respect to the main $d^0$ peak. We argue that these multiple peaks should be understood as being due to the final-state effect and are intrinsic to the materials. Their presence does not necessarily imply the existence of spatially localized ions of different oxidation states nor of separate phases. A simple model is provided to illustrate this interpretation, and several experiments are discussed accordingly. The key parameter to determine the relative importance between the initial-state and final-state effects is also pointed out.

cond-mat.str-el↗