arXiv subjects

Ahmed Al-Refaie

Publications and source records attributed to Ahmed Al-Refaie.

At least 19 recordsLinked to original sources

arXiv2025

TIRAMISU: Non-LTE radiative transfer for molecules in exoplanet atmospheres

The TIRAMISU code, a new program for computing on-the-fly non-LTE molecular spectra and opacities for solving self-consistent radiative transfer problems in exoplanet atmospheres, is presented. The ultra-hot Jupiter KELT-20 b is used as a case study to identify the wavelength regions at which non-LTE effects may be detectable. It is shown that upper atmospheric OH in vibrational non-LTE should be observable primarily via hot bands in the mid-infrared and enhanced photodissociation in the visible. Varying the abundance of OH in non-LTE demonstrates a non-linear relationship between the abundance and the strength of non-LTE effects. Using recent calculations of the photodissociation probabilities of OH it is shown that non-LTE effects can increase the total photodissociation rate by two orders of magnitude in the upper atmosphere, which is likely to have a significant impact on atmospheric and chemical modelling. Increases and reductions in the molecular opacities under non-LTE conditions may lead to the mischaracterisation of molecular abundances in retrievals that only consider opacities computed under LTE. Collisional data requirements to support future non-LTE modelling for a variety of exoplanet atmospheres and across a wide range of wavelengths are discussed.

astro-ph.EP↗

arXiv2024

Water is a radiation protection agent for ionised pyrrole

Radiation-induced damage of biological matter is an ubiquitous problem in nature. The influence of the hydration environment is widely discussed, but its exact role remains elusive. Utilising well defined solvated-molecule aggregates, we experimentally observed a hydrogen-bonded water molecule acting as a radiation protection agent for ionised pyrrole, a prototypical aromatic biomolecule. Pure samples of pyrrole and pyrrole(H$_2$O) were outer-valence ionised and the subsequent damage and relaxation processes were studied. Bare pyrrole ions fragmented through the breaking of C-C or N-C covalent bonds. However, for pyrrole(H$_2$O)$^+$, we observed a strong protection of the pyrrole ring through the dissociative release of neutral water or by transferring an electron or proton across the hydrogen bond. Overall, a single water molecule strongly reduces the fragmentation probability and thus the persistent radiation damage of singly-ionised pyrrole.

physics.chem-ph↗

arXiv2023

To Sample or Not To Sample: Retrieving Exoplanetary Spectra with Variational Inference and Normalising Flows

Current endeavours in exoplanet characterisation rely on atmospheric retrieval to quantify crucial physical properties of remote exoplanets from observations. However, the scalability and efficiency of the technique are under strain with increasing spectroscopic resolution and forward model complexity. The situation becomes more acute with the recent launch of the James Webb Space Telescope and other upcoming missions. Recent advances in Machine Learning provide optimisation-based Variational Inference as an alternative approach to perform approximate Bayesian Posterior Inference. In this investigation we combined Normalising Flow-based neural network with our newly developed differentiable forward model, Diff-Tau, to perform Bayesian Inference in the context of atmospheric retrieval. Using examples from real and simulated spectroscopic data, we demonstrated the superiority of our proposed framework: 1) Training Our neural network only requires a single observation; 2) It produces high-fidelity posterior distributions similar to sampling-based retrieval and; 3) It requires 75% less forward model computation to converge. 4.) We performed, for the first time, Bayesian model selection on our trained neural network. Our proposed framework contribute towards the latest development of a neural-powered atmospheric retrieval. Its flexibility and speed hold the potential to complement sampling-based approaches in large and complex data sets in the future.

astro-ph.EP↗

arXiv2023

A re-analysis of equilibrium chemistry in five hot Jupiters

Studying chemistry and chemical composition is fundamental to go back to formation history of planetary systems. We propose here to have another look at five targets to better determine their composition and the chemical mechanisms that take place in their atmospheres. We present a re-analysis of five Hot Jupiters, combining multiple instruments and using Bayesian retrieval methods. We compare different combinations of molecules present in the simulated atmosphere, different chemistry types as well as different clouds parametrization. As a consequence of recent studies questioning the detection of Na and K in the atmosphere of HD 209458b as being potentially contaminated by stellar lines when present, we study the impact on other retrieval parameters of misinterpreting the presence of these alkali species. We use spatially scanned observations from the grisms G102 and G141 of the WFC3 on HST, with a wavelength coverage of $\sim$0.8 to $\sim$1.7 microns. We analyse these data with the publicly available Iraclis pipeline. We added to our datasets STIS observations to increase our wavelength coverage from $\sim$0.4 to $\sim$1.7 microns. We then performed a Bayesian retrieval analysis with the open-source TauREx using a nested sampling algorithm. We explore the influence of including Na and K on the retrieval of the molecules from the atmosphere. Our data re-analysis and Bayesian retrieval are consistent with previous studies but we find small differences in the retrieved parameters. After all, Na and K has no significant impact on the properties of the planet atmospheres. Therefore, we present here our new best-fit models, taking into account molecular abundances varying freely and equilibrium chemistry. This work is a preparation for a future addition of more sophisticated representation of chemistry taking into account disequilibrium effects such as vertical mixing and photochemistry.

astro-ph.EP↗

arXiv2023

Retrieval study of cool, directly imaged exoplanet 51 Eri b

Retrieval methods are a powerful analysis technique for modelling exoplanetary atmospheres by estimating the bulk physical and chemical properties that combine in a forward model to best-fit an observed spectrum, and they are increasingly being applied to observations of directly-imaged exoplanets. We have adapted TauREx3, the Bayesian retrieval suite, for the analysis of near-infrared spectrophotometry from directly-imaged gas giant exoplanets and brown dwarfs. We demonstrate TauREx3's applicability to sub-stellar atmospheres by presenting results for brown dwarf benchmark GJ 570D which are consistent with previous retrieval studies, whilst also exhibiting systematic biases associated with the presence of alkali lines. We also present results for the cool exoplanet 51 Eri b, the first application of a free chemistry retrieval analysis to this object, using spectroscopic observations from GPI and SPHERE. While our retrieval analysis is able to explain spectroscopic and photometric observations without employing cloud extinction, we conclude this may be a result of employing a flexible temperature-pressure profile which is able to mimic the presence of clouds. We present Bayesian evidence for an ammonia detection with a 2.7$σ$ confidence, the first indication of ammonia in an exoplanetary atmosphere. This is consistent with this molecule being present in brown dwarfs of a similar spectral type. We demonstrate the chemical similarities between 51 Eri b and GJ 570D in relation to their retrieved molecular abundances. Finally, we show that overall retrieval conclusions for 51 Eri b can vary when employing different spectral data and modelling components, such as temperature-pressure and cloud structures.

astro-ph.EP↗

arXiv2022

Twinkle -- a small satellite spectroscopy mission for the next phase of exoplanet science

With a focus on off-the-shelf components, Twinkle is the first in a series of cost competitive small satellites managed and financed by Blue Skies Space Ltd. The satellite is based on a high-heritage Airbus platform that will carry a 0.45 m telescope and a spectrometer which will provide simultaneous wavelength coverage from 0.5-4.5 $\rm{μm}$. The spacecraft prime is Airbus Stevenage while the telescope is being developed by Airbus Toulouse and the spectrometer by ABB Canada. Scheduled to begin scientific operations in 2025, Twinkle will sit in a thermally-stable, sun-synchronous, low-Earth orbit. The mission has a designed operation lifetime of at least seven years and, during the first three years of operation, will conduct two large-scale survey programmes: one focused on Solar System objects and the other dedicated to extrasolar targets. Here we present an overview of the architecture of the mission, refinements in the design approach, and some of the key science themes of the extrasolar survey.

astro-ph.IM↗

arXiv2022

Cross-sections for heavy atmospheres: H$_2$O continuum

Most of the exoplanets detected up to now transit in front of their host stars, allowing for the generation of transmission spectra; the study of exoplanet atmospheres relies heavily upon accurate analysis of these spectra. Recent discoveries mean that the study of atmospheric signals from low-mass, temperate worlds are becoming increasingly common. The observed transit depth in these planets is small and more difficult to analyze. Analysis of simulated transmission spectra for two small, temperate planets (GJ 1214 b and K2-18 b) is presented, giving evidence for significant differences in simulated transit depth when the water vapor continuum is accounted for when compared to models omitting it. These models use cross-sections from the CAVIAR lab experiment for the water self-continuum up to 10,000 cm$^{-1}$; these cross-sections exhibit an inverse relationship with temperature, hence lower-temperature atmospheres are the most significantly impacted. Including the water continuum strongly affects transit depths, increasing values by up to 80 ppm, with the differences for both planets being detectable with the future space missions Ariel and JWST. It is imperative that models of exoplanet spectra move toward adaptive cross-sections, increasingly optimized for H$_2$O-rich atmospheres. This necessitates including absorption contribution from the water vapor continuum into atmospheric simulations.

astro-ph.EP↗

arXiv2021

Alfnoor: assessing the information content of Ariel's low resolution spectra with planetary population studies

The ARIEL Space Telescope will provide a large and diverse sample of exoplanet spectra, performing spectroscopic observations of about 1000 exoplanets in the wavelength range $0.5 \to 7.8 \; μm$. In this paper, we investigate the information content of ARIEL's Reconnaissance Survey low resolution transmission spectra. Among the goals of the ARIEL Reconnaissance Survey is also to identify planets without molecular features in their atmosphere. In this work, (1) we present a strategy that will allow to select candidate planets to be reobserved in a ARIEL's higher resolution Tier; (2) we propose a metric to preliminary classify exoplanets by their atmospheric composition without performing an atmospheric retrieval; (3) we introduce the possibility to find other methods to better exploit the data scientific content.

astro-ph.EP↗

arXiv2021

ARES V: No Evidence For Molecular Absorption in the HST WFC3 Spectrum of GJ 1132 b

We present a study on the spatially scanned spectroscopic observations of the transit of GJ 1132 b, a warm ($\sim$500 K) Super-Earth (1.13 R$_\oplus$) that was obtained with the G141 grism (1.125 - 1.650 $μ$m) of the Wide Field Camera 3 (WFC3) onboard the Hubble Space Telescope. We used the publicly available Iraclis pipeline to extract the planetary transmission spectra from the five visits and produce a precise transmission spectrum. We analysed the spectrum using the TauREx3 atmospheric retrieval code with which we show that the measurements do not contain molecular signatures in the investigated wavelength range and are best-fit with a flat-line model. Our results suggest that the planet does not have a clear primordial, hydrogen-dominated atmosphere. Instead, GJ 1132 b could have a cloudy hydrogen-dominated envelope, a very enriched secondary atmosphere, be airless, or have a tenuous atmosphere that has not been detected. Due to the narrow wavelength coverage of WFC3, these scenarios cannot be distinguished yet but the James Webb Space Telescope may be capable of detecting atmospheric features, although several observations may be required to provide useful constraints.

astro-ph.EP↗

arXiv2021

Detectability of Rocky-Vapour Atmospheres on Super-Earths with Ariel

Ariel will mark the dawn of a new era as the first large-scale survey characterising exoplanetary atmospheres with science objectives to address fundamental questions about planetary composition, evolution and formation. In this study, we explore the detectability of atmospheres vaporised from magma oceans on dry, rocky Super-Earths orbiting very close to their host stars. The detection of such atmospheres would provide a definitive piece of evidence for rocky planets but are challenging measurements with currently available instruments due to their small spectral signatures. However, some of the hottest planets are believed to have atmospheres composed of vaporised rock, such as Na and SiO, with spectral signatures bright enough to be detected through eclipse observations with planned space-based telescopes. In this study, we find that rocky super-Earths with a irradiation temperature of 3000 K and a distance from Earth of up to 20 pc, as well as planets hotter than 3500 K and closer than 50 pc, have SiO features which are potentially detectable in eclipse spectra observed with Ariel.

astro-ph.EP↗

arXiv2020

Hubble WFC3 Spectroscopy of the Habitable-zone Super-Earth LHS 1140 b

Atmospheric characterisation of temperate, rocky planets is the holy grail of exoplanet studies. These worlds are at the limits of our capabilities with current instrumentation in transmission spectroscopy and challenge our state-of-the-art statistical techniques. Here we present the transmission spectrum of the temperate Super-Earth LHS 1140b using the Hubble Space Telescope (HST). The Wide Field Camera 3 (WFC3) G141 grism data of this habitable zone (T$_{\rm{eq}}$ = 235 K) Super-Earth (R = 1.7 $R_\oplus$), shows tentative evidence of water. However, the signal-to-noise ratio, and thus the significance of the detection, is low and stellar contamination models can cause modulation over the spectral band probed. We attempt to correct for contamination using these models and find that, while many still lead to evidence for water, some could provide reasonable fits to the data without the need for molecular absorption although most of these cause also features in the visible ground-based data which are nonphysical. Future observations with the James Webb Space Telescope (JWST) would be capable of confirming, or refuting, this atmospheric detection.

astro-ph.EP↗

arXiv2020

ARES IV: Probing the atmospheres of the two warm small planets HD 106315 c and HD 3167 c with the HST/WFC3 camera

We present an atmospheric characterization study of two medium sized planets bracketing the radius of Neptune: HD 106315 c (R$_{\rm{P}}$=4.98 $\pm$ 0.23 R$_{\oplus}$) and HD 3167 c (R$_{\rm{P}}$=2.740$_{-0.100}^{+0.106}$ R$_{\oplus}$). We analyse spatially scanned spectroscopic observations obtained with the G141 grism (1.125 - 1.650 $μ$m) of the Wide Field Camera 3 (WFC3) onboard the Hubble Space Telescope. We use the publicly available Iraclis pipeline and TauREx3 atmospheric retrieval code and we detect water vapor in the atmosphere of both planets with an abundance of $\log_{10}[\mathrm{H_2O}]=-2.1^{+0.7}_{-1.3}$ ($\sim$5.68$σ$) and $\log_{10}[\mathrm{H_2O}]=-4.1^{+0.9}_{-0.9}$ ($\sim$3.17$σ$) for HD 106315 c and HD 3167 c, respectively. The transmission spectrum of HD 106315 c shows also a possible evidence of ammonia absorption ($\log_{10}[\mathrm {NH_3}]=-4.3^{+0.7}_{-2.0}$, $\sim$1.97$σ$ -even if it is not significant-), whilst carbon dioxide absorption features may be present in the atmosphere of HD 3167 c in the $\sim$1.1-1.6~$μ$m wavelength range ($\log_{10}[\mathrm{CO_{2}}]= -2.4^{+0.7}_{-1.0}$, $\sim$3.28$σ$). However the CO$_2$ detection appears significant, it must be considered carefully and put into perspective. Indeed, CO$_2$ presence is not explained by 1D equilibrium chemistry models, and it could be due to possible systematics. The additional contribution of clouds, CO and CH$_4$ are discussed. HD 106315 c and HD 3167 c will be interesting targets for upcoming telescopes such as the James Webb Space Telescope (JWST) and the Atmospheric Remote-Sensing Infrared Exoplanet Large-Survey (Ariel).

astro-ph.EP↗

arXiv2020

Alfnoor: A Retrieval Simulation of the Ariel Target List

In this work, we present Alfnoor, a dedicated tool optimised for population studies of exoplanet atmospheres. Alfnoor combines the latest version of the retrieval algorithm TauREx 3, with the instrument noise simulator ArielRad and enables the simultaneous retrieval analysis of a large sample of exo-atmospheres. We applied this tool to the Ariel list of planetary candidates and focus on hydrogen dominated, cloudy atmospheres observed in transit with the Tier-2 mode (medium Ariel resolution). As a first experiment, we randomised the abundances - ranging from 10$^{-7}$ to 10$^{-2}$ - of the trace gases, which include H$_2$O, CH$_4$, CO, CO$_2$ and NH$_3$. This exercise allowed to estimate the detection limits for Ariel Tier-2 and Tier-3 modes when clouds are present. In a second experiment, we imposed an arbitrary trend between a chemical species and the effective temperature of the planet. A last experiment was run requiring molecular abundances being dictated by equilibrium chemistry at a certain temperature. Our results demonstrate the ability of Ariel Tier-2 and Tier-3 surveys to reveal trends between the chemistry and associated planetary parameters. Future work will focus on eclipse data, on atmospheres heavier than hydrogen and will be applied also to other observatories.

astro-ph.EP↗

arXiv2020

ARES I: WASP-76 b, A Tale of Two HST Spectra

We analyse the transmission and emission spectra of the ultra-hot Jupiter WASP-76b, observed with the G141 grism of the Hubble Space Telescope's Wide Field Camera 3 (WFC3). We reduce and fit the raw data for each observation using the open-source software Iraclis before performing a fully Bayesian retrieval using the publicly available analysis suite TauRex 3. Previous studies of the WFC3 transmission spectra of WASP-76 b found hints of titanium oxide (TiO) and vanadium oxide (VO) or non-grey clouds. Accounting for a fainter stellar companion to WASP-76, we reanalyse this data and show that removing the effects of this background star changes the slope of the spectrum, resulting in these visible absorbers no longer being detected, eliminating the need for a non-grey cloud model to adequately fit the data but maintaining the strong water feature previously seen. However, our analysis of the emission spectrum suggests the presence of TiO and an atmospheric thermal inversion, along with a significant amount of water. Given the brightness of the host star and the size of the atmospheric features, WASP-76 b is an excellent target for further characterisation with HST, or with future facilities, to better understand the nature of its atmosphere, to confirm the presence of TiO and to search for other optical absorbers.

astro-ph.EP↗

arXiv2020

ARES II: Characterising the Hot Jupiters WASP-127 b, WASP-79 b and WASP-62 b with HST

This paper presents the atmospheric characterisation of three large, gaseous planets: WASP-127b, WASP-79b and WASP-62b. We analysed spectroscopic data obtained with the G141 grism (1.088 - 1.68 $μ$m) of the Wide Field Camera 3 (WFC3) onboard the Hubble Space Telescope (HST) using the Iraclis pipeline and the TauREx3 retrieval code, both of which are publicly available. For WASP-127 b, which is the least dense planet discovered so far and is located in the short-period Neptune desert, our retrieval results found strong water absorption corresponding to an abundance of log(H$_2$O) = -2.71$^{+0.78}_{-1.05}$, and absorption compatible with an iron hydride abundance of log(FeH)=$-5.25^{+0.88}_{-1.10}$, with an extended cloudy atmosphere. We also detected water vapour in the atmospheres of WASP-79 b and WASP-62 b, with best-fit models indicating the presence of iron hydride, too. We used the Atmospheric Detectability Index (ADI) as well as Bayesian log evidence to quantify the strength of the detection and compared our results to the hot Jupiter population study by Tsiaras et al. 2018. While all the planets studied here are suitable targets for characterisation with upcoming facilities such as the James Webb Space Telescope (JWST) and Ariel, WASP-127 b is of particular interest due to its low density, and a thorough atmospheric study would develop our understanding of planet formation and migration.

astro-ph.EP↗

arXiv2020

ARES III: Unveiling the Two Faces of KELT-7 b with HST WFC3

We present the analysis of the hot-Jupiter KELT-7b using transmission and emission spectroscopy from the Hubble Space Telescope (HST), both taken with the Wide Field Camera 3 (WFC3). Our study uncovers a rich transmission spectrum which is consistent with a cloud-free atmosphere and suggests the presence of H2O and H-. In contrast, the extracted emission spectrum does not contain strong absorption features and, although it is not consistent with a simple blackbody, it can be explained by a varying temperature-pressure profile, collision induced absorption (CIA) and H-. KELT-7 b had also been studied with other space-based instruments and we explore the effects of introducing these additional datasets. Further observations with Hubble, or the next generation of space-based telescopes, are needed to allow for the optical opacity source in transmission to be confirmed and for molecular features to be disentangled in emission.

astro-ph.EP↗

arXiv2020

Ares: A Mars model retrieval framework for ExoMars Trace Gas Orbiter NOMAD solar occultation measurements

Ares is an extension of the TauREx 3 retrieval framework for the Martian atmosphere. Ares is a collection of new atmospheric parameters and forward models, designed for the European Space Agency's (ESA) Trace Gas Orbiter (TGO) Nadir and Occultation for MArs Discovery (NOMAD) instrument, Solar Occultation (SO) channel. Ares provides unique insights into the chemical composition of the Martian atmosphere by applying methods utilised in exoplanetary atmospheric retrievals, Waldmann et al. (2015), Al-Refaie et al. (2019). This insight may help unravel the true nature of $CH_{4}$ on Mars. The Ares model is here described. Subsequently, the components of Ares are defined, including; the NOMAD SO channel instrument function model, Martian atmospheric molecular absorption cross-sections, geometry models, and a NOMAD noise model. Ares atmospheric priors and forward models are presented, (i.e., simulated NOMAD observations), and are analysed, compared and validated against the Planetary Spectrum Generator, Villanueva et al. (2018).

astro-ph.EP↗

arXiv2020

Spatial separation of 2-propanol monomer and its ionization-fragmentation pathways

The spatial separation of 2-propanol monomer from its clusters in a molecular beam by an electrostatic deflector was demonstrated. Samples of 2-propanol monomer with a purity of 90 % and a beam density of $7\times10^6~\text{cm}^{-3}$ were obtained. These samples were utilized to study the femtosecond-laser-induced strong-field multi-photon ionization and fragmentation of 2-propanol using non-resonant 800 nm light with peak intensities of $3-7\times10^{13}~W/cm^{2}$.

physics.chem-ph↗