arXiv subjects

Ahsan Nazir

Publications and source records attributed to Ahsan Nazir.

At least 37 records · Page 2Linked to original sources

arXiv2024

Capturing non-Markovian polaron dressing with the master equation formalism

Understanding the dynamics of open quantum systems in strong coupling and non-Markovian regimes remains a formidable theoretical challenge. One popular and well-established method of approximation in these circumstances is provided by the polaron master equation (PME). In this work we reevaluate and extend the validity of the PME to capture the impact of non-Markovian polaron dressing, induced by non-equilibrium open system dynamics. By comparing with numerically exact techniques, we confirm that while the standard PME successfully predicts the dynamics of system observables that commute with the polaron transformation (e.g. populations in the Pauli z-basis), it can struggle to fully capture those that do not (e.g. coherences). This limitation stems from the mixing of system and environment degrees of freedom inherent to the polaron transformation, which affects the accuracy of calculated expectation values within the polaron frame. Employing the Nakajima-Zwanzig projection operator formalism, we introduce correction terms that provide an accurate description of observables that do not commute with the transformation. We demonstrate the significance of the correction terms in two cases, the canonical spin-boson model and a dissipative time-dependent Landau-Zener protocol, where they are shown to impact the system dynamics on both short and long timescales.

quant-ph↗

arXiv2024

Vibronic effects on the quantum tunnelling of magnetisation in Kramers single-molecule magnets

Single-molecule magnets are among the most promising platforms for achieving molecular-scale data storage and processing. Their magnetisation dynamics are determined by the interplay between electronic and vibrational degrees of freedom, which can couple coherently, leading to complex vibronic dynamics. Building on an ab initio description of the electronic and vibrational Hamiltonians, we formulate a non-perturbative vibronic model of the low-energy magnetic degrees of freedom in monometallic single-molecule magnets. Describing their low-temperature magnetism in terms of magnetic polarons, we are able to quantify the vibronic contribution to the quantum tunnelling of the magnetisation, a process that is commonly assumed to be independent of spin-phonon coupling. We find that the formation of magnetic polarons lowers the tunnelling probability in both amorphous and crystalline systems by stabilising the low-lying spin states. This work, thus, shows that spin-phonon coupling subtly influences magnetic relaxation in single-molecule magnets even at extremely low temperatures where no vibrational excitations are present.

quant-ph↗

arXiv2023

The gauge-relativity of quantum light, matter, and information

We describe the physical relativity of light and matter quantum subsystems, their correlations, and energy exchanges. We examine the most commonly adopted definitions of atoms and photons, noting the significant difference in their localisation properties when expressed in terms of primitive manifestly gauge-invariant and local fields. As a result, different behaviours for entanglement generation and energy exchange occur for different definitions. We explore such differences in detail using toy models of a single photonic mode interacting with one and two dipoles.

quant-ph↗

arXiv2023

Bypassing thermalization timescales in temperature estimation using prethermal probes

We introduce prethermal temperature probes for sensitive, fast and robust temperature estimation. While equilibrium thermal probes with a manifold of quasidegenerate excited states have been previously recognized for their maximal sensitivity, they suffer from long thermalization timescales. When considering time as a critical resource in thermometry, it becomes evident that these equilibrium probes fall short of ideal performance. Here, we propose a different paradigm for thermometry, where setups originally suggested for optimal equilibrium thermometry should instead be employed as prethermal probes, by making use of their long-lived quasiequilibrium state. This transient state emerges from the buildup of quantum coherences among quasidegenerate levels. For a class of physically-motivated initial conditions, we find that energy measurements of the prethermal state exhibit a similar sensitivity as the equilibrium state. However, they offer the distinct benefit of orders of magnitude reduction in the time required for the estimation protocol. Upon introducing a figure-of-merit that accounts for the estimation protocol time, prethermal probes surpass the corresponding equilibrium probes in terms of effective thermal sensitivity, opening avenues for rapid thermometry by harnessing the long-lived prethermal states.

quant-ph↗

arXiv2022

Implications of gauge freedom for nonrelativistic quantum electrodynamics

Gauge freedom in quantum electrodynamics (QED) outside of textbook regimes is reviewed. It is emphasized that QED subsystems are defined relative to a choice of gauge. Each definition uses different gauge-invariant observables. This relativity is eliminated only if a sufficient number of Markovian and weak-coupling approximations are employed. All physical predictions are gauge invariant, including subsystem properties such as photon number and entanglement. However, subsystem properties naturally differ for different physical subsystems. Gauge ambiguities arise not because it is unclear how to obtain gauge-invariant predictions, but because it is not always clear which physical observables are the most operationally relevant. The gauge invariance of a prediction is necessary but not sufficient to ensure its operational relevance. It is shown that, in controlling which gauge invariant observables are used to define a material system, the choice of gauge affects the balance between the material system's localization and its electromagnetic dressing. Various implications of subsystem gauge relativity for deriving effective models, for describing time-dependent interactions, for photodetection theory, and for describing matter within a cavity are reviewed.

quant-ph↗

arXiv2022

Effective Hamiltonian theory of open quantum systems at strong coupling

We present the reaction-coordinate polaron-transform (RCPT) framework for generating effective Hamiltonian models to treat nonequilibrium open quantum systems at strong coupling with their surroundings. Our approach, which is based on two exact transformations of the Hamiltonian followed by its controlled truncation, ends with a new Hamiltonian with a weakened coupling to the environment. This new effective Hamiltonian mirrors the initial one, except that its parameters are dressed by the system-bath couplings. The power and elegance of the RCPT approach lie in its generality and in its mathematical simplicity, allowing for analytic work and thus profound understanding of the impact of strong system-bath coupling effects on open quantum system phenomena. Examples interrogated in this work include canonical models for quantum thermalization, charge and energy transport at the nanoscale, performance bounds of quantum thermodynamical machines such as absorption refrigerators and thermoelectric generators, as well as the equilibrium and nonequilibrium behavior of many-body dissipative spin chains.

quant-ph↗

arXiv2022

Strong coupling in thermoelectric nanojunctions: a reaction coordinate framework

We study a model of a thermoelectric nanojunction driven by vibrationally-assisted tunneling. We apply the reaction coordinate formalism to derive a master equation governing its thermoelectric performance beyond the weak electron-vibrational coupling limit. Employing full counting statistics we calculate the current flow, thermopower, associated noise, and efficiency without resorting to the weak vibrational coupling approximation. We demonstrate intricacies of the power-efficiency-precision trade-off at strong coupling, showing that the three cannot be maximised simultaneously in our model. Finally, we emphasise the importance of capturing non-additivity when considering strong coupling and multiple environments, demonstrating that an additive treatment of the environments can violate the upper bound on thermoelectric efficiency imposed by Carnot.

quant-ph↗

arXiv2022

Theory of photon condensation in an arbitrary gauge condensed matter cavity model

We derive an arbitrary-gauge criterion under which condensed matter within an electromagnetic field may transition to a photon condensed phase. Previous results are recovered by selecting the Coulomb-gauge wherein photon condensation can only occur for a spatially-varying field and can be interpreted as a magnetic instability. We demonstrate the gauge-invariance of our description directly, but since matter and photons are gauge-relative concepts we find more generally that photon condensation can occur within a spatially uniform field, and that the relative extent to which the instability is both magnetic and electric versus purely magnetic depends on the gauge.

quant-ph↗

arXiv2021

Identification of Poincare-gauge and multipolar nonrelativistic theories of QED

For over six decades, quantum electrodynamics (QED) in multipolar form has been an invaluable tool for understanding quantum-scale atomic and molecular interactions. However, its relation to the Poincare-gauge has been a recent topic of controversy and debate. It was claimed by Rousseau and Felbacq in the article Scientific Reports 7, 11115 (2017) that Hamiltonian multipolar QED is not the same as Poincare-gauge QED and that it is not generally equivalent to Coulomb-gauge QED. This claim has subsequently been refuted, but since both sides of the debate appear technically sound, a clear reconciliation remains to be given. This task is of paramount importance due to the widespread use of multipolar QED in quantum optics and atomic physics. Here, unlike in other responses, we adopt the same method as Rousseau and Felbacq of using Dirac's constrained quantisation procedure. However, our treatment shows that Poincare-gauge and multipolar QED are identical. We identify the precise source of the apparent incompatibility of previous results as nothing more than a semantic mismatch. In fact there are no inconsistencies. Our results firmly and rigorously solidify the multipolar theory.

quant-ph↗

arXiv2021

Exact dynamics of non-additive environments in non-Markovian open quantum systems

When a quantum system couples strongly to multiple baths then it is generally no longer possible to describe the resulting system dynamics by simply adding the individual effects of each bath. However, capturing such multi-bath system dynamics has up to now required approximations that can obscure some of the non-additive effects. Here we present a numerically-exact and efficient technique for tackling this problem that builds on the time-evolving matrix product operator (TEMPO) representation. We test the method by applying it to a simple model system that exhibits non-additive behaviour: a two-level dipole coupled to both a vibrational and an optical bath. Although not directly coupled, there is an effective interaction between the baths mediated by the system that can lead to population inversion in the matter system when the vibrational coupling is strong. We benchmark and validate multi-bath TEMPO against two approximate methods - one based on a polaron transformation, the other on an identification of a reaction coordinate - before exploring the regime of simultaneously strong vibrational and optical coupling where the approximate techniques break down. Here we uncover a new regime where the quantum Zeno effect leads to a fully mixed state of the electronic system.

quant-ph↗

arXiv2021

Ultrastrong time-dependent light-matter interactions are gauge-relative

Time-dependent light-matter interactions are a widespread means by which to describe controllable experimental operations. They can be viewed as an approximation in which a third system - the control system - is treated as external within the Hamiltonian. We demonstrate that this results in non-equivalence between gauges. We provide a physical example in which each different non-equivalent model coincides with a gauge-invariant description applied in a different experimental situation. The qualitative final-time predictions obtained from these models, including entanglement and photon number, depend on the gauge within which the time-dependent coupling assumption is made. This occurs whenever the interaction switching is sufficiently strong and non-adiabatic even if the coupling vanishes at the preparation and measurement stages of the protocol, at which times the subsystems are unique and experimentally addressable.

quant-ph↗

arXiv2020

Uniqueness of the Phase Transition in Many-Dipole Cavity Quantum Electrodynamical Systems

The possibility of a superradiant phase transition in light-matter systems is the subject of much debate, due to numerous apparently conflicting no-go and counter no-go theorems. Using an arbitrary gauge approach we show that a unique phase transition does occur in archetypal many-dipole cavity QED systems, and that it manifests unambiguously via a macroscopic gauge-invariant polarisation. We find that the gauge choice controls the extent to which this polarisation is included as part of the radiative quantum subsystem and thereby determines the degree to which the abnormal phase is classed as superradiant. This resolves the long-standing paradox of no-go and counter no-go theorems for superradiance, which are shown to refer to different definitions of radiation.

quant-ph↗

arXiv2020

Photon Statistics of Filtered Resonance Fluorescence

Spectral filtering of resonance fluorescence is widely employed to improve single photon purity and indistinguishability by removing unwanted backgrounds. For filter bandwidths approaching the emitter linewidth, complex behaviour is predicted due to preferential transmission of components with differing photon statistics. We probe this regime using a Purcell-enhanced quantum dot in both weak and strong excitation limits, finding excellent agreement with an extended sensor theory model. By changing only the filter width, the photon statistics can be transformed between antibunched, bunched, or Poissonian. Our results verify that strong antibunching and a sub-natural linewidth cannot simultaneously be observed, providing new insight into the nature of coherent scattering.

quant-ph↗

arXiv2020

Gauge non-invariance due to material truncation in ultrastrong-coupling QED

Gauge non-invariance due to material truncation has recently been explored in a number of contexts in strong-coupling QED. We show that the approach proposed recently in Nature Physics 15, 803 (2019) rests on an incorrect mathematical assertion and so does not resolve gauge non-invariance. It produces new two-level models that are not equivalent in different gauges. The new Coulomb-gauge model is inaccurate for the regimes considered in Nature Physics 15, 803 (2019), for which the multipolar-gauge quantum Rabi model is accurate. The models analysed in Nature Physics 15, 803 (2019) do not result from the argument provided in the main text, but instead from truncation within the multipolar-gauge followed by the application of a truncated phase-invariance principle. More generally, this principle can be applied following truncation in any gauge and it yields an equivalence class of truncated models within the gauge chosen. Equivalence classes belonging to different gauges are not equivalent and the truncated phase-invariance principle does not provide an argument to prefer a particular class. In general, the optimal class depends on the physical situation, including the observables, the parameter regime, and the number of field modes being considered. We also emphasise that gauge-ambiguities are not synonymous with gauge non-invariance due to approximations. Independent of material truncation subsystem predictions can be vastly different depending on the theoretical definitions of the subsystems, which are controlled by the gauge choice. This constitutes an example of vector-space relativity that in no way contradicts gauge-invariance. However, within ultrastrong-coupling regimes this relativity can no longer be ignored.

quant-ph↗

arXiv2020

Quantum limit to nonequilibrium heat-engine performance imposed by strong system-reservoir coupling

We show that finite system-reservoir coupling imposes a distinct quantum limit on the performance of a non-equilibrium quantum heat engine. Even in the absence of quantum friction along the isentropic strokes, finite system-reservoir coupling induces correlations that result in the generation of coherence between the energy eigenstates of the working system. This coherence acts to hamper the engine's power output, as well as the efficiency with which it can convert heat into useful work, and cannot be captured by a standard Born-Markov analysis of the system-reservoir interactions.

quant-ph↗

arXiv2019

Electron Counting Statistics for Non-Additive Environments

Molecular electronics is a rapidly developing field focused on using molecules as the structural basis for electronic components. It is common in such devices for the system of interest to couple simultaneously to multiple environments. Here we consider a model comprised of a double quantum dot (or molecule) coupled strongly to vibrations and weakly to two electronic leads held at arbitrary bias voltage. The strong vibrational coupling invalidates treating the bosonic and electronic environments simply as acting additively, as would be the case in the weak coupling regime or for flat leads at infinite bias. Instead, making use of the reaction coordinate framework we incorporate the dominant vibrational coupling effects within an enlarged system Hamiltonian. This allows us to derive a non-additive form for the lead couplings that accounts properly for the influence of strong and non-Markovian coupling between the double dot system and the vibrations. Applying counting statistics techniques we track electron flow between the double dot and the electronic leads, revealing both strong-coupling and non-additive effects in the electron current, noise and Fano factor.

cond-mat.mes-hall↗

arXiv2019

Vibrational enhancement of quadrature squeezing and phase sensitivity in resonance fluorescence

Vibrational environments are commonly considered to be detrimental to the optical emission properties of solid-state and molecular systems, limiting their performance within quantum information protocols. Given that such environments arise naturally it is important to ask whether they can instead be turned to our advantage. Here we show that vibrational interactions can be harnessed within resonance fluorescence to generate optical states with a higher degree of quadrature squeezing than in isolated atomic systems. Considering the example of a driven quantum dot coupled to phonons, we demonstrate that it is feasible to surpass the maximum level of squeezing theoretically obtainable in an isolated atomic system and indeed come close to saturating the fundamental upper bound on squeezing from a two-level emitter. We analyse the performance of these vibrationally-enhanced squeezed states in a phase estimation protocol, finding that for the same photon flux, they can outperform the single mode squeezed vacuum state.

quant-ph↗

arXiv2019

Phonon limit to simultaneous near-unity efficiency and indistinguishability in semiconductor single photon sources

Semiconductor quantum dots have recently emerged as a leading platform to efficiently generate highly indistinguishable photons, and this work addresses the timely question of how good these solid-state sources can ultimately be. We establish the crucial role of lattice relaxation in these systems in giving rise to trade-offs between indistinguishability and efficiency. We analyse the two source architectures most commonly employed: a quantum dot embedded in a waveguide and a quantum dot coupled to an optical cavity. For waveguides, we demonstrate that the broadband Purcell effect results in a simple inverse relationship, where indistinguishability and efficiency cannot be simultaneously increased. For cavities, the frequency selectivity of the Purcell enhancement results in a more subtle trade-off, where indistinguishability and efficiency can be simultaneously increased, though by the same mechanism not arbitrarily, limiting a source with near-unity indistinguishability ($>99$\%) to an efficiency of approximately 96\% for realistic parameters.

quant-ph↗