arXiv subjects

Ai-Min Guo

Publications and source records attributed to Ai-Min Guo.

At least 19 recordsLinked to original sources

arXiv2026

Spin-to-charge conversion driven by inverse chiral-induced spin selectivity

Chiral molecules have attracted significant multidisciplinary interest and extensive research owing to their remarkable ability to achieve charge-to-spin conversion, known as the chiral-induced spin selectivity (CISS). A recent experiment has revealed that chiral molecules also exhibit an unexpected capability for spin-to-charge conversion, referred to as the inverse CISS (ICISS), opening unprecedented avenues for the study and application of chiral molecules. Here, we propose a theoretical model, suggesting that ICISS can be understood in terms of spin-dependent electron deflection induced by the interplay between spin and chiral structure. Our numerical results are consistent with experimental observations, demonstrating that ICISS persists under strong disorder. Our model also reproduces the inverse spin Hall effect (ISHE) in this experiment. Comparative analysis indicates that ICISS exhibits a spin-to-charge conversion behavior that differs from ISHE. Our work develops a microscopic theoretical model that accounts for the experimentally observed phenomena, and may provide a useful perspective for organic spintronics.

physics.chem-ph↗

arXiv2026

Unconventional Spin Valve Based on Normal Metal/Chiral Molecule/Altermagnet Junctions

Chiral molecules have attracted broad interdisciplinary interest for their ability to produce highly spin-polarized current. This phenomenon, known as the chiral-induced spin selectivity effect, holds great potential in the field of spintronics. Here, we propose to combine chiral molecules with altermagnets to construct highly efficient and tunable spin valves. Using the nonequilibrium Green's function method and the Landauer-Büttiker formula, we obtain the conductance and the magnetoresistance of a normal metal/chiral molecule/altermagnet spin valve. Our theoretical results reveal that the conductance of the spin valve can be effectively tuned by reorienting the Néel vector of the altermagnet, and the magnetoresistance of the spin valve increases with molecular length and altermagnetic anisotropy. Moreover, the magnetoresistance vanishes for achiral molecules or in the absence of molecular spin-orbit coupling. Our work paves the way for developing efficient, controllable, and stray-field-free spintronic devices.

physics.chem-ph↗

arXiv2026

Magnetic-flux tunable electronic transport through domain walls in a three-dimensional second-order topological insulator

The three-dimensional (3D) topological insulators (TIs), hosting topologically protected helical surface states, can be promoted into second-order TIs when a diagonal Zeeman term, typical of magnetic doping, is introduced. The latter hosts exotic chiral one-dimensional (1D) topological hinge states (THSs). In this paper, we investigate the electronic transport of THSs through a magnetic domain wall (DW) in a 3D TI nanowire. Due to the sign reversal of the out-of-plane magnetization across the DW, four 1D topological boundary states, residing on the edge of the DW, arise and form an enclosed loop mediating the counterpropagating THSs. By applying a uniform magnetic field parallel to the nanowire, we obtain a perfect sinusoidal Aharonov-Bohm oscillation in the two-terminal conductance $G$, formulated by $G=\frac{e^2}{2h} \left[ 1- \cos(πΦ/Φ_0) \right]$, with $Φ$ the magnetic flux through the DW and $Φ_0 = h/2e$ the flux quantum. Applying a phenomenological scattering matrix approach, we explain this novel Aharonov-Bohm oscillation perfectly, and attribute the constructive (destructive) interference of transmission at $Φ= Φ_0$ (0) to the $π$-spin rotation of the THSs traveling through the DW. Extending our study to a double-DW junction, where the central region has antiparallel magnetization to the leads, we observe Fabry-P{é}rot oscillations, in which the conductance minima are tuned by the magnetic flux. Our findings open a new avenue for finely controlling the quantum transport of THSs in magnetic systems using magnetic flux, and provide a faithful way for detecting THSs in experiments.

cond-mat.mes-hall↗

arXiv2025

Exact mobility edges in quasiperiodic network models with slowly varying potentials

Quasiperiodic models are important physical platforms to explore Anderson transitions in low dimensional systems, yet the exact mobility edges (MEs) are generally hard to be determined analytically. To date, the MEs in only a few models can be determined exactly. In this manuscript, we propose a new class of network models characterized by quasiperiodic slowly varying potentials and the absence of hidden self-duality, and exactly determine their MEs. We take the mosaic models with slowly varying potentials as examples to illustrate this result and derive its MEs from the effective Hamiltonian. In this method, we can integrate out the periodic sites to obtain an effective Hamiltonian with energy-dependent potentials $g(E)V$ and effective eigenenergy $f(E)$, which directly yields the MEs at $f(E) = \pm(2t^κ\pm g(E)V)$, where $κ\in \mathbb{Z}^+$. With this idea in hand, we then generalize our method to more quasiperiodic network models, including those with much more complicated geometries and non-Hermitian features. Finally, we propose the realization of these models using optical waveguides and show that the Anderson transition can be observed even in small physical systems (with lattice sites about $L = 50 - 100$). Our results provide some key insights into the understanding and realization of exact MEs in experiments.

cond-mat.dis-nn↗

arXiv2025

Hidden self-duality and exact mobility edges in quasiperiodic network models

In one-dimensional quasiperiodic systems, only a few models with exact mobility edges (MEs) have been constructed using generalized self-duality theory, Avila's global theory, or the renormalization group method. This raises an intriguing question that whether we can realize more physical models with exact solvable MEs. In this work, we uncover the hidden self-duality within a class of quasiperiodic network models constituted by periodic and quasiperiodic sites. Although the original Hamiltonians appear to lack self-duality, their effective Hamiltonians obtained by integrating out the periodic sites exhibit self-duality, which yield MEs. The well-studied mosaic model, which is the simplest case of quasiperiodic network models, was previously thought to exhibit MEs due to the absence of self-duality, but we show that they actually arise from the hidden self-duality. Using the effective Hamiltonian, we further introduce the concept of resonant states to understand the shape of MEs. Finally, we present in detail how to determine the MEs in various network models, including some non-Hermitian models, based on the hidden self-duality. These predictions can be experimentally realized using optical and acoustic waveguide arrays. Our work can greatly advance our understanding of MEs in Anderson transition.

cond-mat.dis-nn↗

arXiv2025

Anomalous Magnetoresistance beyond the Jullière Model for Spin Selectivity in Chiral Molecules

The issue of anomalous high magnetoresistance, beyond the Jullière model, observed in nonmagnetic electrode-chiral molecular-ferromagnetic electrode devices has puzzled the community for a long time. Here, by considering the magnetic proximity effect which shifts the nonmagnetic-ferromagnetic interface toward chiral molecules, we show the anomalous high magnetoresistance beyond the spin polarization in ferromagnetic electrodes even in the very weak spin-orbit coupling. Our results are in excellent agreement with the experiments, demonstrating that the spin-orbit coupling plays a fundamental role in chiral-induced spin selectivity and the magnetic proximity effect can dramatically enhance the magnetoresistance. These results elucidate the interaction between chiral molecules and ferromagnetic electrodes and facilitate the design of chiral-based spintronic devices.

physics.chem-ph↗

arXiv2025

Spin-to-charge conversion modulated by chiral molecules

Molecular chirality and electron spin are intricately intertwined via the fascinating phenomenon of chiral-induced spin selectivity (CISS), which has garnered considerable attention due to its extensive potential applications. A recent experiment has revealed that chiral molecules self-assembled on the gold surface can modulate the inverse spin Hall effect, providing an alternative platform for studying the interplay between chirality and spin transport. Our study uncovers that this modulation stems from the CISS effect, which enhances spin currents of one spin orientation while suppressing those of the opposite spin orientation. We provide numerical results that are highly consistent with the experimental phenomena and further investigate the influence of various factors on this modulation. This work offers a theoretical explanation of previously unexplained experimental findings, and the underlying physical mechanism broadens current perspectives on understanding and applying CISS.

physics.chem-ph↗

arXiv2025

Strongly correlated electrons in superconducting islands with fluctuating Cooper pairs

We present a particle-number conserving theory for many-body effects in mesoscopic superconducting islands connected to normal electrodes, which explicitly includes quantum fluctuations of Cooper pairs in the condensate. Beyond previous BCS mean-field descriptions, our theory can precisely treat the pairing and Coulomb interactions over an unprecedentedly broad range of parameters by using the numerical renormalization group method. On increasing the ratio of pairing to Coulomb interactions, the low-energy physics of the system evolves from the spin Kondo to mixed valence regimes and eventually reaches an anisotropic charge Kondo phase, while a crossover from $1e$- to $2e$-periodic Coulomb blockade of transport is revealed at high temperatures. For weak pairing, the superconducting condensate is frozen in the local spin-flip processes but fluctuates in the virtual excitations, yielding an enhanced spin Kondo temperature. For strong pairing, massive fluctuations of Cooper pairs are crucial for establishing charge Kondo correlations whose Kondo temperature rapidly decreases with the pairing interaction. Surprisingly, a charge-exchange induced local field may occur even at the charge degenerate point, thereby destroying the charge Kondo effect. These are demonstrated in the spectral and transport properties of the island.

cond-mat.str-el↗

arXiv2025

Dynamical theory of chiral-induced spin selectivity in electron donor-chiral molecule-acceptor systems

The chiral-induced spin selectivity (CISS) effect, a phenomenon where the chirality of molecules imparts significant spin selectivity to electron transfer processes, has garnered increasing interest among the chemistry, biology, and physics communities. Although this effect was discovered more than a decade ago, the dynamical process of how electron spin polarization is caused by chiral molecules is still unclear. Here, we propose a dynamical theory of electron transfer in donor-chiral molecule bridge-acceptor systems without electrodes or substrates based on the Lindblad-type master equation. We demonstrate that the molecular spin-orbit coupling generates unequal spin velocities and achieves steady spin polarization with the help of dephasing. Our work elucidates the dynamical process of CISS and may promote the applications of chiral-based spintronic devices.

physics.chem-ph↗

arXiv2025

Frustration-enhanced persistent currents in correlated trimer nanorings

We investigate the persistent current in a correlated trimer nanoring comprising of three magnetic atoms, which sits on a metallic host and encloses a magnetic flux. In the molecular-orbital regime, charge fluctuations can reverse the aromaticity of the trimer molecule by driving quantum phase transitions between many-body states. It is shown that in frustrated trimers the superexchange-induced current as a function of interatom hopping is enhanced by the competition of conflicting magnetic orders, with an asymmetric peak at the quantum criticality separating the ferromagnetic and antiferromagnetic Kondo regimes. Interestingly, the critical current undergoes an anomalous rise with temperature before decaying, signaling the suppression of Kondo bound state at finite temperature. Our results demonstrate that the coherent current response to external flux indeed conveys important information on the states of strongly correlated systems.

cond-mat.str-el↗

arXiv2024

Thermal dissipation of the quantum spin Hall edge states in HgTe/CdTe quantum well

Quantum spin Hall effect is characterized by topologically protected helical edge states. Here we study the thermal dissipation of helical edge states by considering two types of dissipation sources. The results show that the helical edge states are dissipationless for normal dissipation sources with or without Rashba spin-orbit coupling in the system, but they are dissipative for spin dissipation sources. Further studies on the energy distribution show that electrons with spin-up and spin-down are both in their own equilibrium without dissipation sources. Spin dissipation sources can couple the two subsystems together to induce voltage drop and nonequilibrium distribution, leading to thermal dissipation, while normal dissipation sources cannot. With the increase of thermal dissipation, the subsystems of electrons with spin-up and spin-down evolve from non-equilibrium finally to mutual equilibrium. In addition, the effects of disorder on thermal dissipation are also discussed. Our work provides clues to reduce thermal dissipation in the quantum spin Hall systems

cond-mat.mes-hall↗

arXiv2024

Quantized perfect transmission in graphene nanoribbons with random hollow adsorbates

Impurities exist inevitably in two-dimensional materials as they spontaneously adsorb onto the surface during fabrication, usually exerting detrimental effects on electronic transport. Here, we focus on a special type of impurities that preferentially adsorb onto the hollow regions of graphene nanoribbons (GNRs), and study how they affect the quantum transport in GNRs. Contrary to previous knowledge that random adatoms should localize electrons, the so-called Anderson localization, noteworthy quantized conductance peaks (QCPs) are observed at specific electron energies. These QCPs are remarkably robust against variations in system size, GNR edge, and adatom properties, and they can reappear at identical energies following an arithmetic sequence of device width. Further investigation of wavefunction reveals a unique transport mode at each QCP energy which transmits through disordered GNRs reflectionlessly, while all the others become fully Anderson localized, indicating the survival of quantum ballistic transport in the localized regime. Our findings highlight the potential utility of hollow adatoms as a powerful tool to manipulate the conductivity of GNRs, and deepen the understanding of the interplay between impurities and graphene.

cond-mat.mes-hall↗

arXiv2023

Transverse spin selectivity in helical nanofibers prepared without any chiral molecule

In the last decade, chirality-induced spin selectivity (CISS) has been attracting extensive interest. However, there still exists a large gap between experiments and quantitative theoretical results, and the microscopic mechanism of CISS, especially transverse CISS where electrons are injected perpendicular to the helix axis of chiral molecules, remains elusive. Here, we address these issues by performing a combined experimental and theoretical study on conducting polyaniline helical nanofibers which are synthesized in the absence of any chiral species. Large spin polarization is measured in both left- and right-handed nanofibers for electrons injected perpendicular to their helix axis, which is comparable to the value of parallel electron injection in other chiral molecules, and it will be reversed by switching the handedness between two enantiomers. We develop a theoretical model with extremely weak spin-orbit coupling arising exclusively from electron propagation between neighboring polyanilines and the numerical results are quantitatively consistent with the experimental data. Our results demonstrate that the supramolecular handedness is sufficient for spin-selective electron transmission in chiral molecules assembled from achiral monomers and the mechanism of transverse CISS is revealed.

cond-mat.mes-hall↗

arXiv2022

Topologically nontrivial and trivial zero modes in chiral molecules

Recently, electron transport along chiral molecules has been attracting extensive interest and several intriguing phenomena have been reported in recent experiments, such as the emergence of zero-bias conductance peaks upon the adsorption of single-helical protein on superconducting films. Here, we study theoretically the electron transport through a two-terminal single-helical protein sandwiched between a superconducting electrode and a normal-metal one in the presence of a perpendicular magnetic field. As the proximity-induced superconductivity attenuates with the distance from superconducting media, the pairing potential along the helix axis of the single-helical protein is expected to decrease exponentially, which is characterized by the decay exponent $λ$ and closely related to the experiments. Our results indicate that (i) a zero-bias conductance peak of $2e^2/h$ appears at zero temperature and the peak height (width) decreases (broadens) with increasing temperature, and (ii) this zero-bias peak can split into two peaks, which are in agreement with the experiments [see, e.g., Nano Lett. 19, 5167 (2019)]. Remarkably, Majorana zero modes are observed in this protein-superconductor setup in a wide range of model parameters, as manifested by the $Z_2$ topological invariant and the Majoroana oscillation. Interestingly, a specific region is demonstrated for decaying superconductivity, where topologically nontrivial and trivial zero modes coexist and the bandgap remains constant. With increasing the pairing potential, the topologically nontrivial zero modes will transform to the trivial ones without any bandgap closing-reopening, and the critical pairing potential of the phase transition attenuates exponentially with $λ$. Additionally, one of the two zero modes can be continuously shifted from one end of the protein toward the other end contacted by the normal-metal electrode.

cond-mat.mes-hall↗

arXiv2022

Quantized charge-pumping in higher-order topological insulators

We study the quantized charge pumping of higher-order topological insulators (HOTIs) with edge-corner correspondences based on the combination of the rotation of in-plane magnetic field and the quantum spin Hall effect. A picture of a specific charge pumping process is uncovered with the help of the non-equilibrium Green's function method. Significantly, we demonstrate that the quantized charge pumping current is achieved without the participation of bulk states, and the charges move along the boundary of the sample. Furthermore, the effects of external parameters on the pumping current is also studied. We find that the magnitude and direction of the pumping current can be manipulated by adjusting the coupling strength between the leads and sample. Our work deepens the understanding of the charge pumping in HOTIs and extends the study of their transport properties.

cond-mat.mes-hall↗

arXiv2022

Resonant tunneling in disordered borophene nanoribbons with line defects

Very recently, borophene has been attracting extensive and ongoing interest as the new wonder material with structural polymorphism and superior attributes, showing that the structural imperfection of line defects (LDs) occurs widely at the interface between $ν_{1/5}$ ($χ_3$) and $ν_{1/6}$ ($β_{12}$) boron sheets. Motivated by these experiments, here we present a theoretical study of electron transport through two-terminal disordered borophene nanoribbons (BNRs) with random distribution of LDs. Our results indicate that LDs could strongly affect the electron transport properties of BNRs. In the absence of LDs, both $ν_{1/5}$ and $ν_{1/6}$ BNRs exhibit metallic behavior, in agreement with experiments. While in the presence of LDs, the overall electron transport ability is dramatically decreased, but some resonant peaks of conductance quantum can be found in the transmission spectrum of any disordered BNR with arbitrary arrangement of LDs. These disordered BNRs exhibit metal-insulator transition by varying nanoribbon width with tunable transmission gap in the insulating regime. Furthermore, the bond currents present fringe patterns and two evolution phenomena of resonant peaks are revealed for disordered BNRs with different widths. These results may help for understanding structure-property relationships and designing LD-based nanodevices.

cond-mat.mes-hall↗

arXiv2021

Charge transport in a multi-terminal DNA tetrahedron: Interplay among contact position, disorder, and base-pair mismatch

As a secondary structure of DNA, DNA tetrahedra exhibit intriguing charge transport phenomena and provide a promising platform for wide applications like biosensors, as shown in recent electrochemical experiments. Here, we study charge transport in a multi-terminal DNA tetrahedron, finding that its charge transport properties strongly depend upon the interplay among contact position, on-site energy disorder, and base-pair mismatch. Our results indicate that the charge transport efficiency is nearly independent of contact position in the weak disorder regime, and is dramatically declined by the occurrence of a single base-pair mismatch between the source and the drain, in accordance with experimental results [J. Am. Chem. Soc. {\bf 134}, 13148 (2012); Chem. Sci. {\bf 9}, 979 (2018)]. By contrast, the charge transport efficiency could be enhanced monotonically by shifting the source toward the drain in the strong disorder regime, and be increased when the base-pair mismatch takes place exactly at the contact position. In particular, when the source moves successively from the top vertex to the drain, the charge transport through the tetrahedral DNA device can be separated into three regimes, ranging from disorder-induced linear decrement of charge transport to disorder-insensitive charge transport, and to disorder-enhanced charge transport. Finally, we predict that the DNA tetrahedron functions as a more efficient spin filter compared to double-stranded DNA and opposite spin polarization could be observed at different drains, which may be used to separate spin-unpolarized electrons into spin-up ones and spin-down ones. These results could be readily checked by electrochemical measurements and may help for designing novel DNA tetrahedron-based molecular nanodevices.

cond-mat.mes-hall↗

arXiv2020

Spin-dependent electron transport along hairpin-like DNA molecules

The chirality-induced spin selectivity (CISS), demonstrated in diverse chiral molecules by numerous experimental and theoretical groups, has been attracting extensive and ongoing interest in recent years. As the secondary structure of DNA, the charge transfer along DNA hairpins has been widely studied for more than two decades, finding that DNA hairpins exhibit spin-related effects as reported in recent experiments. Here, we propose a setup to demonstrate directly the CISS effect in DNA hairpins contacted by two nonmagnetic leads at both ends of the stem. Our results indicate that DNA hairpins present pronounced CISS effect and the spin polarization could be enhanced by using conducting molecules as the loop. In particular, DNA hairpins show several intriguing features, which are different from other chiral molecules. First, the local spin currents can flow circularly and assemble into a number of vortex clusters when the electron energy locates in the left/right electronic band of the stem. The chirality of vortex clusters in each band is the same and will be reversed by switching the electron energy from the left band to the right one, inducing the sign reversal of the spin polarization. Interestingly, the local spin currents can be greater than the corresponding spin component of the source-drain current. Second, both the conductance and the spin polarization can increase with molecular length as well as dephasing strength, contrary to the physical intuition that the transmission ability of molecular wires should be poorer when suffering from stronger scattering. Third, we unveil the optimal contact configuration of efficient electron transport and that of the CISS effect, which are distinct from each other and can be controlled by dephasing strength. The underlying physical mechanism is illustrated.

cond-mat.mes-hall↗