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Aigen Li

Publications and source records attributed to Aigen Li.

At least 73 records · Page 4Linked to original sources
arXiv2019

Probing the Missing Link between the Diffuse Interstellar Bands and the Total-to-Selective Extinction Ratio $R_V$ $-$ I. Extinction versus Reddening

The carriers of the still (mostly) unidentified diffuse interstellar bands (DIBs) have been a long-standing mystery ever since their first discovery exactly 100 years ago. In recent years, the ubiquitous detection of a large number of DIBs in a wide range of Galactic and extragalactic environments has led to renewed interest in connecting the occurrence and properties of DIBs to the physical and chemical conditions of the interstellar clouds, with particular attention paid to whether the DIB strength is related to the shape of the interstellar extinction curve. To shed light on the nature and origin of the DIB carriers, we investigate the relation between the DIB strength and $R_V$, the total-to-selective extinction ratio, which characterizes how the extinction varies with wavelength (i.e., the shape of the extinction curve). We find that the DIB strength and $R_V$ are not related if we represent the strength of a DIB by its reddening-normalized equivalent width (EW), in contrast to the earlier finding of an anticorrelation in which the DIB strength is measured by the extinction-normalized EW. This raises a fundamental question about the appropriate normalization for the DIB EW.

astro-ph.GA↗
arXiv2019

How Much Graphene in Space?

The possible presence of graphene in the interstellar medium (ISM) is examined by comparing the interstellar extinction curve with the ultraviolet absorption of graphene calculated from its dielectric functions experimentally obtained with the electron energy loss spectroscopy (EELS) method. Based on the absence in the interstellar extinction curve of the ~2755 Angstrom $π$--$π^{\ast}$ electronic interband transition of graphene, we place an upper limit of ~20ppm of C/H on the interstellar graphene abundance, exceeding the previous estimate by a factor of ~3 which made use of the dielectric functions measured with the spectroscopic ellipsometry (SE) method. Compared with the SE method which measures graphene in air (and hence its surface is contaminated) in a limited energy range of ~0.7--5 eV, the EELS probes a much wider energy range of ~0--50 eV and is free of contamination. The fact that the EELS dielectric functions are substantially smaller than that of SE naturally explains why a higher upper limit on the graphene abundance is derived with EELS. Inspired by the possible detection of C$_{24}$, a planar graphene sheet, in several Galactic and extragalactic planetary nebulae, we also examine the possible presence of C$_{24}$ in the diffuse ISM by comparing the model IR emission of C$_{24}$ with the observed IR emission of the Galactic cirrus and the diffuse ISM toward $l = 44^{o}20^\prime$ and $b=-0^{o}20^\prime$. An upper limit of ~20 ppm on C$_{24}$ is also derived from the absence of the characteristic vibrational bands of C$_{24}$ at ~6.6, 9.8 and 20 $μ$m in the observed IR emission.

astro-ph.GA↗
arXiv2019

Synthesizing carbon nanotubes in space

Context. As the 4th most abundant element in the universe, carbon (C) is widespread in the interstellar medium (ISM) in various allotropic forms (e.g., fullerenes have been identified unambiguously in many astronomical environments, the presence of polycyclic aromatic hydrocarbon molecules in space has been commonly admitted, and presolar graphite as well as nanodiamonds have been identified in meteorites). As stable allotropes of these species, whether carbon nanotubes (CNTs) and their hydrogenated counterparts are also present in the ISM or not is unknown. Aims. We explore the possible routes for the formation of CNTs in the ISM and calculate their fingerprint vibrational spectral features in the infrared (IR). Methods. We study the hydrogen-abstraction/acetylene-addition (HACA) mechanism and investigate the synthesis of nanotubes using density functional theory (DFT). The IR vibrational spectra of CNTs and hydrogenated nanotubes (HNTs), as well as their cations, have also been obtained with DFT. Results. We find that CNTs could be synthesized in space through a feasible formation pathway. CNTs and cationic CNTs, as well as their hydrogenated counterparts, exhibit intense vibrational transitions in the IR. Their possible presence in the ISM could be investigated by comparing the calculated vibrational spectra with astronomical observations made by the Infrared Space Observatory, Spitzer Space Telescope, and particularly the upcoming James Webb Space Telescope.

astro-ph.IM↗
arXiv2019

Unusual Infrared Emission toward Sgr B2: Possible Planar C$_{24}$

Interstellar graphene could be present in the interstellar medium (ISM), resulting from the photochemical processing of polycyclic aromatic hydrocarbon (PAH) molecules and/or collisional fragmentation of graphitic particles. Indeed, by comparing the observed ultraviolet (UV) extinction and infrared (IR) emission of the diffuse ISM with that predicted for graphene, as much as $\sim$ 2% of the total interstellar carbon could have been locked up in graphene without violating the observational constraints. While the possible detection of planar C$_{24}$, a small piece of a graphene sheet, has been reported towards several Galactic and extragalactic planetary nebulae, graphene has not yet been detected in interstellar environments. In this work, we search for the characteristic IR features of C$_{24}$ at $\sim$ 6.6, 9.8, 20 $μm$ toward Sgr B2, a high-mass star formation region, and find a candidate target toward R.A. (J2000) = $267^{\circ}.05855$ and Decl. (J2000) = $-28^{\circ}.01479$ in Sgr B2 whose Spitzer/IRS spectra exhibit three bands peaking at $\sim$ 6.637, 9.853 and 20.050 $μm$ which appear to be coincident with that of C$_{24}$. Possible features of C$_{60}$ are also seen in this region. The candidate region is a warm dust environment heated by massive stars or star clusters, associated with a WISE spot (a tracer of star-formation activity), close to the HII region candidate IRAS 17450-2759, and is surrounded by seven young stellar object candidates within $\sim$ 5$^{\prime}$, suggesting that the creation and/or excitation of C$_{24}$ could be related to star formation activities.

astro-ph.GA↗
arXiv2018

Nano Dust in Space and Astrophysics

We summarize the Focus Meeting (FM10) "Nano Dust in Space and Astrophysics" held in Vienna, Austria on 28-29 August 2018 during the 30th General Assembly of the International Astronomical Union (IAU). The theme of this focus meeting is related to the detection, characterization and modeling of nano particles --- cosmic dust of sizes of roughly 1 to 100 nm --- in space environments like the interstellar medium, planetary debris disks, the heliosphere, the vicinity of the Sun and planetary atmospheres, and the space near Earth. Discussions focus on nano dust that forms from condensations and collisions and from planetary objects, as well as its interactions with space plasmas like the solar and stellar winds, atmospheres and magnetospheres. A particular goal is to bring together space scientists, astronomers, astrophysicists, and laboratory experimentalists and combine their knowledge to reach cross fertilization of different disciplines.

astro-ph.GA↗
arXiv2018

Graphene and Carbon Nanotubes in Space

As the fourth most abundant element in the universe, carbon plays an important role in the physical and chemical evolution of the interstellar medium. Due to its unique property to form three different types of chemical bonds through sp^1, sp^2, and sp^3 hybridizations, carbon can be stabilized in various allotropes, including amorphous carbon, graphite, diamond, polycyclic aromatic hydrocarbon, fullerenes, graphene, and carbon nanotubes.

astro-ph.GA↗
arXiv2018

The Widespread Presence of Nanometer-size Dust Grains in the Interstellar Medium of Galaxies

Interstellar dust spans a wide range in size distribution, ranging from ultrasmall grains of a few Angstroms to micrometer-size grains. While the presence of nanometer-size dust grains in the Galactic interstellar medium was speculated six decades ago and was previously suggested based on early infrared observations, systematic and direct analysis of their properties over a wide range of environments has been lacking. Here we report the detection of nanometer-size dust grains that appear to be universally present in a wide variety of astronomical environments, from Galactic high-latitude clouds to nearby star-forming galaxies and galaxies with low levels of nuclear activity. The prevalence of such a grain population is revealed conclusively as prominent mid-infrared continuum emission at wavelength short than 10μm seen in the Spitzer/IRS data, characterized by temperatures of ~300-400K that are significantly higher than the equilibrium temperatures of common, submicron-size grains in typical galactic environments. We propose that the optimal carriers of this pervasive, featureless hot dust component are very small carbonaceous (e.g., graphite) grains of nanometer size that are transiently heated by single-photon absorption. This grain population accounts for ~1.4% of the total infrared emission at ~5-3000μm and ~0.4% of the total interstellar dust mass.

astro-ph.GA↗
arXiv2018

A New Technique for Measuring Polycyclic Aromatic Hydrocarbon Emission in Different Environments

We present a new method to decompose the emission features of polycyclic aromatic hydrocarbons (PAHs) from mid-infrared spectra using theoretical PAH templates in conjunction with modified blackbody components for the dust continuum and an extinction term. The primary goal is to obtain robust measurements of the PAH features, which are sensitive to the star formation rate, in a variety of extragalactic environments. We demonstrate the effectiveness of our technique, starting with the simplest Galactic high-latitude clouds to extragalactic systems of ever-increasing complexity, from normal star-forming galaxies to low-luminosity active galaxies, quasars, and heavily obscured infrared-luminous galaxies. In addition to providing accurate measurements of the PAH emission, including the upper limits thereof, our fits can reproduce reasonably well the overall continuum shape and constrain the line-of-sight extinction. Our new PAH line flux measurements differ systematically and significantly from those of previous methods by ~15% to as much as a factor of ~6. The decomposed PAH spectra show remarkable similarity among different systems, suggesting a uniform set of conditions responsible for their excitation.

astro-ph.GA↗
arXiv2018

Probing the 9.7μm Interstellar Silicate Extinction Profile through the Spitzer/IRS Spectroscopy of OB Stars

The 9.7$μ$m interstellar spectral feature, arising from the Si--O stretch of amorphous silicate dust, is the strongest extinction feature in the infrared (IR). In principle, the spectral profile of this feature could allow one to diagnose the mineralogical composition of interstellar silicate material. However, observationally, the 9.7$μ$m interstellar silicate extinction profile is not well determined. Here we utilize the Spitzer/IRS spectra of five early-type (one O- and four B-type) stars and compare them with that of unreddened stars of the same spectral type to probe the interstellar extinction of silicate dust around 9.7$μ$m. We find that, while the silicate extinction profiles all peak at ~9.7$μ$m, two stars exhibit a narrow feature of FWHM ~2.0$μ$m and three stars display a broad feature of FWHM ~3.0$μ$m. We also find that the width of the 9.7$μ$m extinction feature does not show any environmental dependence. With a FWHM of ~2.2$μ$m, the mean 9.7μm extinction profile, obtained by averaging over our five stars, closely resembles that of the prototypical diffuse interstellar medium along the lines of sight toward Cyg OB2 No.12 and WR 98a. Finally, an analytical formula is presented to parameterize the interstellar extinction in the IR at $0.9μ{\rm m} < λ< 15μ{\rm m}$.

astro-ph.SR↗
arXiv2017

Cosmic Dust IX

This is an editorial to the special issue on Cosmic Dust IX.

astro-ph.GA↗
arXiv2017

On Graphene in the Interstellar Medium

The possible detection of C_{24}, a planar graphene, recently reported in several planetary nebulae by Garciaa-Hernandez et al. (2011, 2012) inspires us to explore whether and how much graphene could exist in the interstellar medium (ISM) and how it would reveal its presence through its ultraviolet (UV) extinction and infrared (IR) emission. In principle, interstellar graphene could arise from the photochemical processing of polycyclic aromatic hydrocarbon (PAH) molecules which are abundant in the ISM through a complete loss of their hydrogen atoms and/or from graphite which is thought to be a major dust species in the ISM through fragmentation caused by grain-grain collisional shattering. Both quantum-chemical computations and laboratory experiments have shown that the exciton-dominated electronic transitions in graphene cause a strong absorption band near 2755 Angstrom. We calculate the UV absorption of graphene and place an upper limit of ~5 ppm of C/H (i.e., ~1.9\% of the total interstellar C) on the interstellar graphene abundance. We also model the stochastic heating of graphene C_{24} excited by single starlight photons of the interstellar radiation field in the ISM and calculate its IR emission spectra. We also derive the abundance of graphene in the ISM to be <5 ppm of C/H by comparing the model emission spectra with that observed in the ISM.

astro-ph.GA↗
arXiv2017

Interstellar Silicon Depletion and the Ultraviolet Extinction

Spinning small silicate grains were recently invoked to account for the Galactic foreground anomalous microwave emission. These grains, if present, will absorb starlight in the far ultraviolet (UV). There is also renewed interest in attributing the enigmatic 2175 Angstrom interstellar extinction bump to small silicates. To probe the role of silicon in the UV extinction, we explore the relations between the amount of silicon required to be locked up in silicates [Si/H]_{dust} and the 2175 Angstrom bump or the far-UV extinction rise, based on an analysis of the extinction curves along 46 Galactic sightlines for which the gas-phase silicon abundance [Si/H]_{gas} is known. We derive [Si/H]_{dust} either from {[Si/H]_{ISM} - [Si/H]_{gas}} or from the Kramers-Kronig relation which relates the wavelength-integrated extinction to the total dust volume, where [Si/H]_{ISM} is the interstellar silicon reference abundance and taken to be that of proto-Sun or B stars. We also derive [Si/H]_{dust} from fitting the observed extinction curves with a mixture of amorphous silicates and graphitic grains. We find that in all three cases [Si/H]_{dust} shows no correlation with the 2175 Angstrom bump, while the carbon depletion [C/H]_{dust} tends to correlate with the 2175 Angstrom bump. This supports carbon grains instead of silicates as the possible carrier of the 2175 Angstrom bump. We also find that neither [Si/H]_{dust} nor [C/H]_{dust} alone correlates with the far-UV extinction, suggesting that the far-UV extinction is a combined effect of small carbon grains and silicates.

astro-ph.GA↗
arXiv2017

The gas-to-extinction ratio and the gas distribution in the Galaxy

We investigate the relation between the optical extinction ($A_V$) and the hydrogen column density ($N_H$) determined from X-ray observations of a large sample of Galactic sightlines toward 35 supernova remnants, 6 planetary nebulae, and 70 X-ray binaries for which $N_H$ was determined in the literature with solar abundances. We derive an average ratio of ${N_H}/{A_V}=(2.08\pm0.02)\times10^{21}{\rm H\, cm^{-2}\, mag^{-1}}$ for the whole Galaxy. We find no correlation between ${N_H}/{A_V}$ and the number density of hydrogen, the distance away from the Galactic centre, and the distance above or below the Galactic plane. The ${N_H}/{A_V}$ ratio is generally invariant across the Galaxy, with ${N_H}/{A_V}=(2.04\pm0.05)\times10^{21}{\rm H\, cm^{-2}\, mag^{-1}}$ for the 1st and 4th Galactic quadrants and ${N_H}/{A_V}=(2.09\pm0.03)\times10^{21}{\rm H\, cm^{-2}\, mag^{-1}}$ for the 2nd and 3rd Galactic quadrants. We also explore the distribution of hydrogen in the Galaxy by enlarging our sample with additional 74 supernova remnants for which both $N_H$ and distances are known. We find that, between the Galactic radius of 2 kpc to 10 kpc, the vertical distribution of hydrogen can be roughly described by a Gaussian function with a scale height of $h=75.5\pm12.4\,{\rm pc}$ and a mid-plane density of $n_{H}(0)=1.11\pm0.15\,{\rm cm^{-3}}$, corresponding to a total gas surface density of ${\sum}_{gas}{\sim}7.0\,{M_{\bigodot}}\,{\rm pc^{-2}}$. We also compile $N_H$ from 19 supernova remnants and 29 X-ray binaries for which $N_H$ was determined with subsolar abundances. We obtain ${N_H}/{A_V}=(2.47\pm0.04)\times10^{21}{\rm H\, cm^{-2}\, mag^{-1}}$ which exceeds that derived with solar abundances by $\sim$20%. We suggest that in future studies one may simply scale $N_H$ derived from subsolar abundances by a factor of $\sim$1.2 when converting to $N_H$ of solar abundances.

astro-ph.GA↗
arXiv2017

Detection of Polarized Infrared Emission by Polycyclic Aromatic Hydrocarbons in the MWC 1080 Nebula

Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous in astrophysical environments, as revealed by their pronounced emission features at 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 $μ$m commonly ascribed to the C--H and C--C vibrational modes. Although these features have long been predicted to be polarized, previous searches for PAH polarization led to null or, at best, tentative detections. Here we report the definite detection of polarized PAH emission at 11.3 $μ$m in the nebula associated with the Herbig Be star MWC 1080. We measure a polarization degree of 1.9$\pm$0.2\%, which is unexpectedly high compared to models. This poses a challenge in the current understanding of the alignment of PAHs, which is required to polarize the PAH emission but thought to be substantially suppressed. PAH alignment with a magnetic field via a resonance paramagnetic relaxation process may account for such a high level of polarization.

astro-ph.GA↗
arXiv2017

On the Optical-to-Silicate Extinction Ratio as a Probe of the Dust Size in Active Galactic Nuclei

Dust plays a central role in the unification theory of active galactic nuclei (AGNs). Whether the dust that forms the torus around an AGN is tenth-$μ$m-sized like interstellar grains or much larger has a profound impact on correcting for the obscuration of the dust torus to recover the intrinsic spectrum and luminosity of the AGN. Here we show that the ratio of the optical extinction in the visual band ($A_V$) to the optical depth of the 9.7 $μ$m silicate absorption feature ($Δτ_{9.7}$) could potentially be an effective probe of the dust size. The anomalously lower ratio of $A_V/Δτ_{9.7} \approx 5.5$ of AGNs compared to that of the Galactic diffuse interstellar medium of $A_V/Δτ_{9.7} \approx 18$ reveals that the dust in AGN torus could be substantially larger than the interstellar grains of the Milky Way and of the Small Magellanic Cloud, and therefore, one might expect a flat extinction curve for AGNs.

astro-ph.GA↗
arXiv2017

The Carriers of the "Unidentified" Infrared Emission Features: Clues from Polycyclic Aromatic Hydrocarbons with Aliphatic Sidegroups

The "unidentified" infrared emission (UIE) features at 3.3, 6.2, 7.7, 8.6, and 11.3 $μ$m are ubiquitously seen in various astrophysical regions. The UIE features are characteristic of the stretching and bending vibrations of aromatic hydrocarbons. The 3.3 $μ$m feature resulting from aromatic C--H stretches is often accompanied by a weaker feature at 3.4 $μ$m often attributed to aliphatic C--H stretches. The ratio of the observed intensity of the 3.3 $μ$m aromatic C--H feature ($I_{3.3}$) to that of the 3.4 $μ$m aliphatic C--H feature ($I_{3.4}$) allows one to estimate the aliphatic fraction (i.e. $N_{\rm C,aliph}/N_{\rm C,arom}$, the number of C atoms in aliphatic units to that in aromatic rings) of the UIE carriers, provided the intrinsic oscillator strengths of the 3.3 $μ$m aromatic C--H stretch ($A_{3.3}$) and the 3.4 $μ$m aliphatic C--H stretch ($A_{3.4}$) are known. In this article we summarize the computational results on $A_{3.3}$ and $A_{3.4}$ and their implications for the aromaticity and aliphaticity of the UIE carriers. We use density functional theory and second-order perturbation theory to derive $A_{3.3}$ and $A_{3.4}$ from the infrared vibrational spectra of seven PAHs with various aliphatic substituents (e.g., methyl-, dimethyl-, ethyl-, propyl-, butyl-PAHs, and PAHs with unsaturated alkyl-chains). The mean band strengths of the aromatic ($A_{3.3}$) and aliphatic ($A_{3.4}$) C--H stretches are derived and then employed to estimate the aliphatic fraction of the UIE carriers by comparing $A_{3.4}$/$A_{3.3}$ with $I_{3.4}$/$I_{3.3}$. We conclude that the UIE emitters are predominantly aromatic, as revealed by the observationally-derived ratio <$I_{3.4}$/$I_{3.3}$> ~ 0.12 and the computationally-derived ratio <$A_{3.4}$/$A_{3.3}$> ~ 1.76 which suggest an upper limit of $N_{\rm C,aliph}/N_{\rm C,arom}$ ~ 0.02 for the aliphatic fraction of the UIE carriers.

astro-ph.GA↗
arXiv2017

Polycyclic Aromatic Hydrocarbons with Aliphatic Sidegroups: Intensity Scaling for the C-H Stretching Modes and Astrophysical Implications

The so-called unidentified infrared emission (UIE) features at 3.3, 6.2, 7.7, 8.6, and 11.3 $μ$m ubiquitously seen in a wide variety of astrophysical regions are generally attributed to polycyclic aromatic hydrocarbon (PAH) molecules. Astronomical PAHs may have an aliphatic component as revealed by the detection in many UIE sources of the aliphatic C-H stretching feature at 3.4 $μ$m. The ratio of the observed intensity of the 3.4 $μ$m feature to that of the 3.3 $μ$m aromatic C-H feature allows one to estimate the aliphatic fraction of the UIE carriers. This requires the knowledge of the intrinsic oscillator strengths of the 3.3 $μ$m aromatic C-H stretch ($A_{3.3}$) and the 3.4 $μ$m aliphatic C-H stretch ($A_{3.4}$). Lacking experimental data on $A_{3.3}$ and $A_{3.4}$ for the UIE candidate materials, one often has to rely on quantum-chemical computations. Although the second-order Moller-Plesset (MP2) perturbation theory with a large basis set is more accurate than the B3LYP density functional theory, MP2 is computationally very demanding and impractical for large molecules. Based on methylated PAHs, we show here that, by scaling the band strengths computed at an inexpensive level (e.g., B3LYP/6-31G*) we are able to obtain band strengths as accurate as that computed at far more expensive levels (e.g., MP2/6-311+G(3df,3pd)).

astro-ph.GA↗