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Ainur Abukaev

Publications and source records attributed to Ainur Abukaev.

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Structural Changes and Transport Properties of $\mathrm{YBa_2Cu_3O_7}$ Locally Modified by a He$^+$ Focused Ion Beam

Irradiation of a material with ions can cause various defects that can lead to structural phase transitions and the modification of the material's properties. Here we study the irradiation of the epitaxyally grown thin films of the high-temperature superconductor $\mathrm{YBa_2Cu_3O_7}$ with $30\,\mathrm{keV}$ He$^{+}$ ions which leads to the expansion of the crystal lattice, decrease of the critical temperature $T_c$ and eventually transition to an insulator. Fabrication of such insulating regions with a focused He-Ion beam with a spot size of $\sim 10\,\mathrm{nm}$ is a powerful technique for fabrication of superconducting nano-devices. Using low-temperature resistivity measurements, diffraction with a nanofocused X-ray beam and atomic force microscopy, we investigated how the structure and the electric transport properties of $\mathrm{YBa_2Cu_3O_7}$ depend on the irradiation dose in a range $10$--$100\,\mathrm{ions/nm^2}$ and on the lateral size of the irradiated area in a range $30$--$5000\,\mathrm{nm}$.

cond-mat.supr-con

Phase behavior and electrical transport in DBTTF-HATCN donor-acceptor mixtures

The formation of donor-acceptor complexes (DACs) between the electron donor Dibenzotetrathiafulvalene (DBTTF) and the acceptor Hexaaza\-triphenylene\-hexacarbo\-nitrile (HATCN) results in a new phase with a distinctly different crystal structure as well as new optical absorption bands below the energy gaps of the two pristine materials. X-ray scattering and atomic force microscopy provide detailed insights into the film structure and morphology by systematic variation of the mixing ratio from pristine DBTTF to pristine HATCN. The measured electrical conductivity of thin films depends in a highly non-monotonic manner on the composition of the mixture and shows significantly improved charge transport compared to the pristine films. The temperature-dependent conductivity, charge carrier concentration, and mobility were investigated across these compositions. Surprisingly, all compositions exhibited n-type behavior, except for pristine DBTTF. This behavior is explained by the electronic structure of the mixtures, as revealed by ultraviolet photoelectron spectroscopy, which indicates that charge injection and transport occur via the lowest unoccupied molecular orbital of the DAC and HATCN. Additionally, the observed electrical conductivity is strongly influenced by morphology and structural ordering of the films. These findings offer valuable insights for the design of advanced materials with enhanced electrical performance.

cond-mat.mtrl-sci