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Ajay Jayachandran

Publications and source records attributed to Ajay Jayachandran.

3 recordsLinked to original sources

Deterministic Quantum Phase Estimation with Linear Circuit Complexity in a Photonic System

Quantum algorithms solve certain computational problems faster than the best known classical algorithms. Many algorithms, including Shor's for factoring, Grover's for unstructured search, and the HHL for solving linear systems, rely on quantum phase estimation (QPE) as a fundamental subroutine. The QPE protocol proceeds through the initialization of a control register in a uniform superposition, controlled unitary evolution encoding the eigenphase, and a final inverse quantum Fourier transform followed by measurement to extract the phase. Here, we address a special class of unitary operators that frequently appear in quantum Fourier transform-based protocols, cyclic group representations, and periodically evolving quantum systems. We introduce a QPE algorithm that successfully reduces the circuit complexity from $\mathcal{O}(n^2)$ to $\mathcal{O}(n)$ for a special class of unitary operators and implement it on a four-qubit photonic system. The four-qubit system is realised using a photon pair, with two qubits encoded in its polarization degree of freedom and the remaining two in its path modes. In contrast to previous photonic implementations of QPE based on dual-rail encoding and KLM protocol, where controlled operations are inherently probabilistic and thus reduce the overall success probability of phase estimation, our scheme is fully deterministic. Moreover, it is scalable to higher-dimensional unitaries, provided the underlying structure of the unitaries is preserved.

quant-ph

Background-free measurement of exciton-exciton annihilation by two-quantum fluorescence-detected pump-probe spectroscopy

We introduce two-quantum (2Q) fluorescence-detected pump-probe (F-PP) spectroscopy as a tool to probe ultrafast multiparticle interactions in many-body systems. We describe a pulse-shaper-based fully collinear setup utilizing phase cycling to capture the 2Q F-PP signal simultaneously with the one-quantum (1Q) F-PP signal. Thus, we investigate the dynamics of energy transfer and diffusion-limited annihilation. We apply a data post-processing strategy to isolate excited-state dynamics from spurious background. The technique is applied to a squaraine heterodimer and a squaraine copolymer to demonstrate the removal of so-called incoherent mixing that generally plagues action-detected nonlinear spectroscopy on multichromophoric systems. Specifically, we show that this approach is not only applicable to 1Q but also to 2Q F-PP signals, eliminating incoherent mixing contributions as well as other "parasitic" signals that result from pulse-overlap ambiguities. As a result, we retrieve background-free spectral and dynamical information of doubly excited electronic states.

physics.chem-ph

Cogwheel phase cycling in population-detected optical coherent multidimensional spectroscopy

An integral procedure in every coherent multidimensional spectroscopy experiment is to suppress undesired background signals. For that purpose, one can employ a particular phase-matching geometry or phase cycling, a procedure that was adapted from nuclear magnetic resonance (NMR) spectroscopy. In optical multidimensional spectroscopy, phase cycling has been usually carried out in a "nested" fashion, where pulse phases are incremented sequentially with linearly spaced increments. Another phase-cycling approach which was developed for NMR spectroscopy is "cogwheel phase cycling," where all pulse phases are varied simultaneously in increments defined by so-called "winding numbers". Here we explore the concept of cogwheel phase cycling in the context of population-based coherent multidimensional spectroscopy. We derive selection rules for resolving and extracting fourth-order and higher-order nonlinear signals by cogwheel phase cycling and describe how to perform a numerical search for the winding numbers for various population-detected 2D spectroscopy experiments. We also provide an expression for a numerical search for nested phase-cycling schemes and predict the most economical schemes of both approaches for a wide range of nonlinear signals. The signal selectivity of the technique is demonstrated experimentally by acquiring rephasing and nonrephasing fourth-order signals of a laser dye by both phase-cycling approaches. We find that individual nonlinear signal contributions are, in most cases, captured with fewer steps by cogwheel phase cycling compared to nested phase cycling.

physics.optics