arXiv subjects

Ajeet Rohatgi

Publications and source records attributed to Ajeet Rohatgi.

4 recordsLinked to original sources

arXiv2026

Mitigating the contact resistance limitation of cavitated fine line Ag paste by Laser-Enhanced Contact Optimization

Cavitation-assisted Ag paste is a promising route for fine-line, low-silver metallization in silicon solar cells because it improves paste dispersion, extends shelf life, and reduces Ag consumption, but matching the contact performance of commercial pastes remains a challenge. Here, cavitated paste was evaluated on PERC solar cells at peak firing temperatures of 720, 740, 750, and 762 C, with and without laser-enhanced contact optimization (LECO). The results show a clear firing window: 720 and 740 °C produced high series resistance and reduced fill factor, 750 C gave the best pre-LECO performance, and 762 C showed additional electrical limitations with only limited LECO benefit. LECO selectively recovered the under-activated states, increasing fill factor from 76.8 to 80.2% at 720 C and from 76.7 to 79.8% at 740 C. Electroluminescence and conductive AFM further indicated improved current collection and stronger localized conduction after LECO. These results show that cavitated paste performance is governed primarily by a shifted contact-formation window, and that firing optimization combined with LECO provides a practical route to retain the fine-line advantage while improving electrical performance.

physics.app-ph↗

arXiv2026

Neutralization of the impact of belt speed on screen printed copper metallization by LECO on PERC homogeneous emitter

Copper fire-through metallization is a cost-effective alternative to Ag counterpart for industrial high efficiency solar cells. The fire through dielectric metallization relies on belt speed, which dictates the ramp up and ramp down rates for effective contact formation. In this paper three belt speeds (325oC, 360oC, 390oC) at constant peak firing temperature, were used to process PERC (homogeneous emitter) cells. After the contact firing the electrical parameters were dependent on belt speed, but after LECO treatment, they were identical. The SEM/EDS cross sectional analyses showed increased elemental Cu with belt speed, and the series resistance was lowest for the middle belt speed before LECO. However, after the LECO treatment, the series resistance dropped, respectively, to 0.503 ohm-cm-2, 0.428 ohm-cm-2 and 0.500 ohm-cm-2 leading to efficiency of 20.8% on homogeneous PERC emitter.

physics.app-ph↗

arXiv2026

Critical look at the atmospheric Cu fire-through dielectric metallization for cost-effective and high efficiency silicon solar cells

The formation of stable copper-silicide (Cu3Si) interfaces is crucial for cost-effective, high-efficiency solar cells. However, copper's diffusivity and electromigration issues pose challenges for contact stability. This study employs Laser-Enhanced Contact Optimization (LECO) to induce localized nano-scale Joule heating at the Cu-Si interface in phosphorus-doped p-PERC solar cells. High-resolution STEM and bright field analyses confirm stable Cu3Si formation in LECO-treated samples, with significantly reduced material segregation compared to nonLECO samples. SEM and post-etch EDS mapping demonstrate improved chemical resistance and interface cleanliness. Electrically, LECO treatmenet reduces series resistance by a factor 3, enhancing fill factor and efficiency while preserving diode quality. These results highlight LECO as a scalable method for reliable, silver-free solar cell metallization.

physics.app-ph↗

arXiv2021

Spatial profiles of photon chemical potential in near-field thermophotovoltaic cells

Emitted photons stemming from the radiative recombination of electron-hole pairs carry chemical potential in radiative energy converters. This luminescent effect can substantially alter the local net photogeneration in near-field thermophotovoltaic cells. Several assumptions involving the luminescent effect are commonly made in modeling photovoltaic devices; in particular, the photon chemical potential is assumed to be zero or a constant prescribed by the bias voltage. The significance of photon chemical potential depends upon the emitter temperature, the semiconductor properties, and the injection level. Hence, these assumptions are questionable in thermophotovoltaic devices operating in the near-field regime. In the present work, an iterative solver that combines fluctuational electrodynamics with the drift-diffusion model is developed to tackle the coupled photon and charge transport problem, enabling the determination of the spatial profile of photon chemical potential beyond the detailed balance approach. The difference between the results obtained by allowing the photon chemical potential to vary spatially and by assuming a constant value demonstrates the limitations of the conventional approaches. This study is critically important for performance evaluation of near-field thermophotovoltaic systems.

physics.app-ph↗