arXiv subjects

Albert Rimola

Publications and source records attributed to Albert Rimola.

At least 37 records · Page 2Linked to original sources

arXiv2023

Oort cloud perturbations as a source of hyperbolic Earth impactors

The observation of interstellar objects 1I/'Oumuamua and 2I/Borisov suggests the existence of a larger population of smaller projectiles that impact our planet with unbound orbits. We analyze an asteroidal grazing meteor (FH1) recorded by the Finnish Fireball Network on October 23, 2022. FH1 displayed a likely hyperbolic orbit lying on the ecliptic plane with an estimated velocity excess of $\sim$0.7 km$\,$s$^{-1}$ at impact. FH1 may either be an interstellar object, indicating a high-strength bias in this population, or an Oort cloud object, which would reinforce migration-based solar system models. Furthermore, under the calculated uncertainties, FH1 could potentially be associated with the passage of Scholz's binary star system. Statistical evaluation of uncertainties in the CNEOS database and study of its hyperbolic fireballs reveals an anisotropic geocentric radiant distribution and low orbital inclinations, challenging the assumption of a randomly incoming interstellar population. Orbital integrations suggest that the event on March 9, 2017 (IM2) from CNEOS may have experienced gravitational perturbation during the Scholz fly-by, contingent upon velocity overestimation within the expected range. These findings suggest that apparent interstellar meteors may, in fact, be the result of accelerated meteoroid impacts caused by close encounters with massive objects within or passing through our solar system.

astro-ph.EP↗

arXiv2023

Deep machine learning for meteor monitoring: advances with transfer learning and gradient-weighted class activation mapping

In recent decades, the use of optical detection systems for meteor studies has increased dramatically, resulting in huge amounts of data being analyzed. Automated meteor detection tools are essential for studying the continuous meteoroid incoming flux, recovering fresh meteorites, and achieving a better understanding of our Solar System. Concerning meteor detection, distinguishing false positives between meteor and non-meteor images has traditionally been performed by hand, which is significantly time-consuming. To address this issue, we developed a fully automated pipeline that uses Convolutional Neural Networks (CNNs) to classify candidate meteor detections. Our new method is able to detect meteors even in images that contain static elements such as clouds, the Moon, and buildings. To accurately locate the meteor within each frame, we employ the Gradient-weighted Class Activation Mapping (Grad-CAM) technique. This method facilitates the identification of the region of interest by multiplying the activations from the last convolutional layer with the average of the gradients across the feature map of that layer. By combining these findings with the activation map derived from the first convolutional layer, we effectively pinpoint the most probable pixel location of the meteor. We trained and evaluated our model on a large dataset collected by the Spanish Meteor Network (SPMN) and achieved a precision of 98\%. Our new methodology presented here has the potential to reduce the workload of meteor scientists and station operators and improve the accuracy of meteor tracking and classification.

astro-ph.EP↗

arXiv2023

Formation of interstellar complex organic molecules on water-rich ices triggered by atomic carbon freezing

The reactivity of interstellar carbon atoms (C) on the water-dominated ices is one of the possible ways to form interstellar complex organic molecules (iCOMs). In this work, we report a quantum chemical study of the coupling reaction of C ($^3$P) with an icy water molecule, alongside possible subsequent reactions with the most abundant closed shell frozen species (NH$_3$, CO, CO$_2$ and H$_2$), atoms (H, N and O), and molecular radicals (OH, NH$_2$ and CH$_3$). We found that C spontaneously reacts with the water molecule, resulting in the formation of $^3$C-OH$_2$, a highly reactive species due to its triplet electronic state. While reactions with the closed-shell species do not show any reactivity, reactions with N and O form CN and CO, respectively, the latter ending up into methanol upon subsequent hydrogenation. The reactions with OH, CH$_3$ and NH$_2$ form methanediol, ethanol and methanimine, respectively, upon subsequent hydrogenation. We also propose an explanation for methane formation, observed in experiments through H additions to C in the presence of ices. The astrochemical implications of this work are: i) atomic C on water ice is locked into $^3$C-OH$_2$, making difficult the reactivity of bare C atoms on the icy surfaces, contrary to what is assumed in astrochemical current models; and ii) the extraordinary reactivity of $^3$C-OH$_2$ provides new routes towards the formation of iCOMs in a non-energetic way, in particular ethanol, mother of other iCOMs once in the gas-phase.

astro-ph.GA↗

arXiv2023

Quantum mechanical modeling of the grain-surface formation of acetaldehyde on H$_2$O:CO dirty ice surfaces

Acetaldehyde (CH$_3$CHO) is one of the most detected interstellar Complex Organic Molecule (iCOM) in the interstellar medium (ISM). These species have a potential biological relevance, as they can be precursors of more complex species from which life could have emerged. The formation of iCOMs in the ISM is a challenge and a matter of debate, whether gas-phase, grain-surface chemistry or both are needed for their synthesis. In the gas-phase, CH$_3$CHO can be efficiently synthesized from ethanol and/or ethyl radical. On the grain-surfaces, radical-radical recombinations were traditionally invoked. However, several pitfalls have been recently identified, such as the presence of energy barriers and competitive side reactions (i.e., H abstractions). Here we investigate a new grain-surface reaction pathway for the formation of acetaldehyde, namely the reaction between CH$_3$ and a CO molecule of a dirty water/CO ice followed by hydrogenation of its product, CH$_3$CO. To this end, we carried out \textit{ab initio} computations of the reaction occurring on an ice composed by 75% water and 25% CO molecules. We found that the CH$_3$ + CO$_{(ice)}$ reaction exhibits barriers difficult to overcome in the ISM, either adopting a Langmuir-Hinshelwood or an Eley-Rideal mechanism. The subsequent hydrogenation step is found to be barrierless, provided that the two reacting species have the correct orientation. Therefore, this pathway seems unlikely to occur in the ISM.

astro-ph.GA↗

arXiv2023

Formation of complex organic molecules on interstellar CO ices? Insights from computational chemistry simulations

Carbon ($^3$P) atom is a reactive species that, according to laboratory experiments and theoretical calculations, condensates with interstellar ice components. This fact is of uttermost importance for the chemistry in the interstellar medium (ISM) because the condensation reaction is barrierless and the subsequent species formed are still reactive given their open-shell character. Carbon condensation on CO-rich ices forms the \ch{C=C=O} ($^3$$Σ$$^-$) species, which can be easily hydrogenated twice to form ketene (H$_2$CCO). Ketene is very reactive in terrestrial conditions, usually found as an intermediate hard to be isolated in chemical synthesis laboratories. These characteristics suggest that ketene can be a good candidate to form interstellar complex organic molecules (iCOMs) via a two-step process, i.e., its activation followed by a radical-radical coupling. In this work, reactions between ketene and atomic H, and the OH and NH$_2$ radicals on a CO-rich ice model have been explored by means of quantum chemical calculations complemented by kinetic calculations to evaluate if they are favourable in the ISM. Results indicate that H addition to ketene (helped by tunneling) to form the acetyl radical (CH$_3$CO) is the most preferred path, as the reactions with OH and NH$_2$ possess activation energies ($\geq$ 9kJ/mol) hard to surmount in the ISM conditions, unless external processes provide energy to the system. Thus, acetaldehyde (CH$_3$CHO) and, probably, ethanol (CH$_3$CH$_2$OH) formation via further hydrogenations are the possible unique operating synthetic routes. Moreover, from the computed relatively large binding energies of OH and NH$_2$ on CO ice, slow diffusion is expected, hampering possible radical-radical couplings with CH$_3$CO. The astrophysical implications of these findings are discussed considering the incoming James Webb Space Telescope observations.

astro-ph.GA↗

arXiv2023

Identifying meteorite droppers among the population of bright 'sporadic' bolides imaged by the Spanish Meteor Network during the spring of 2022

The extraordinary weather conditions available between February and March 2022 over Spain have allowed us to analyze the brightest fireballs recorded by the monitoring stations of the Spanish Meteor Network (SPMN). We study the atmospheric flight of 15 large meteoroids to determine if they are meteorite dropper events to prepare campaigns to search for freshly fallen extraterrestrial material. We investigate their origins in the Solar System and their dynamic association with parent bodies and meteoroid streams. Employing our Python pipeline 3D-FireTOC, we reconstruct the atmospheric trajectory utilizing ground-based multi-station observations and compute the heliocentric orbit. In addition, we apply an ablation model to estimate the initial and terminal mass of each event. Using a dissimilarity criterion and propagating backward in time, we check the connection of these meteoroids with known complexes and near-Earth objects. We also calculate if the orbits are compatible with recent meteoroid ejections. We find that ~27% of these fireballs are dynamically associated with minor meteoroid streams and exhibit physical properties of cometary bodies, as well as one associated with a near-Earth asteroid. We identify two meteorite-producing events; however, the on-site search was unsuccessful. By considering that these fireballs are mostly produced by cm-sized rocks that might be the fragmentation product of much larger meteoroids, our findings emphasize the idea that the population of near-Earth objects is a source of near-term impact hazards, existing large Earth-colliding meteoroids in the known complexes.

astro-ph.EP↗

arXiv2022

Where does the energy go during the interstellar NH$_3$ formation on water ice? A computational study

In the coldest (10--20 K) regions of the interstellar medium, the icy surfaces of interstellar grains serve as solid-state supports for chemical reactions. Among their plausible roles, that of third body is advocated, in which the reaction energies of surface reactions dissipate throughout the grain, stabilizing the product. This energy dissipation process is poorly understood at the atomic scale, although it can have a high impact on Astrochemistry. Here, we study, by means of quantum mechanical simulations, the formation of NH3 via successive H-additions to atomic N on water ice surfaces, paying special attention to the third body role. We first characterize the hydrogenation reactions and the possible competitive processes (i.e., H-abstractions), in which the H-additions are more favourable than the H-abstractions. Subsequently, we study the fate of the hydrogenation reaction energies by means of ab initio molecular dynamics simulations. Results show that around 58--90\% of the released energy is quickly absorbed by the ice surface, inducing a temporary increase of the ice temperature. Different energy dissipation mechanisms are distinguished. One mechanism, more general, is based on the coupling of the highly excited vibrational modes of the newly formed species and the libration modes of the icy water molecules. A second mechanism, exclusive during the NH$_3$ formation, is based on the formation of a transient H$_3$O$^+$/NH$_2^-$ ion pair, which significantly accelerates the energy transfer to the surface. Finally, the astrophysical implications of our findings relative to the interstellar synthesis of NH$_3$ and its chemical desorption into the gas are discussed.

astro-ph.GA↗

arXiv2022

Non-Energetic Formation of Ethanol via CCH Reaction with Interstellar H2O Ices. A Computational Chemistry Study

Ethanol (CH$_3$CH$_2$OH) is a relatively common molecule, often found in star forming regions. Recent studies suggest that it could be a parent molecule of several so-called interstellar complex organic molecules (iCOMs). Yet, the formation route of this species remains debated. In the present work, we study the formation of ethanol through the reaction of CCH with one H$_2$O molecule belonging to the ice, as a test case to investigate the viability of chemical reactions based on a "radical + ice component" scheme as an alternative mechanism for the synthesis of iCOMs, beyond the usual radical-radical coupling. This has been done by means of DFT calculations adopting two clusters of 18 and 33 water molecules as ice models. Results indicate that CH$_3$CH$_2$OH can potentially be formed by this proposed reaction mechanism. The reaction of CCH with H$_2$O on the water ice clusters can be barrierless (thanks to the help of boundary icy water molecules acting as proton transfer assistants) leading to the formation of vinyl alcohol precursors (H$_2$CCOH and CHCHOH). Subsequent hydrogenation of vinyl alcohol yielding ethanol is the only step presenting a low activation energy barrier. We finally discuss the astrophysical implications of these findings.

astro-ph.GA↗

arXiv2022

Quantum mechanical simulations of the radical-radical chemistry on icy surfaces

The formation of the interstellar complex organic molecules (iCOMs) is a hot topic in astrochemistry. One of the main paradigms trying to reproduce the observations postulates that iCOMs are formed on the ice mantles covering the interstellar dust grains as a result of radical--radical coupling reactions. We investigate iCOMs formation on the icy surfaces by means of computational quantum mechanical methods. In particular, we study the coupling and direct hydrogen abstraction reactions involving the CH$_3$ + X systems (X = NH$_2$, CH$_3$, HCO, CH$_3$O, CH$_2$OH) and HCO + Y (Y = HCO, CH$_3$O, CH$_2$OH), plus the CH$_2$OH + CH$_2$OH and CH$_3$O + CH$_3$O systems. We computed the activation energy barriers of these reactions as well as the binding energies of all the studied radicals, by means of density functional theory (DFT) calculations on two ice water models, made of 33 and 18 water molecules. Then, we estimated the efficiency of each reaction using the reaction activation, desorption and diffusion energies and derived kinetics with the Eyring equations. We find that radical--radical chemistry on surfaces is not as straightforward as usually assumed. In some cases, direct H abstraction reactions can compete with radical--radical couplings, while in others they may contain large activation energies. Specifically, we found that (i) ethane, methylamine and ethylene glycol are the only possible products of the relevant radical--radical reactions; (ii) glyoxal, methyl formate, glycolaldehyde, formamide, dimethyl ether and ethanol formation is likely in competition with the respective H-abstraction products, and (iii) acetaldehyde and dimethyl peroxide do not seem a likely grain surface products.

astro-ph.GA↗

arXiv2022

Thermal desorption of interstellar ices. A review on the controlling parameters and their implications fromsnowlines to chemical complexity

The evolution of star-forming regions and their thermal balance are strongly influenced by their chemical composition, that, in turn, is determined by the physico-chemical processes that govern the transition between the gas phase and the solid state, specifically icy dust grains (e.g., particles adsorption and desorption). Gas-grain and grain-gas transitions as well as formation and sublimation of interstellar ices are thus essential elements of understanding astrophysical observations of cold environments (e.g., pre-stellar cores) where unexpected amounts of a large variety of chemical species have been observed in the gas phase. Adsorbed atoms and molecules also undergo chemical reactions which are not efficient in the gas phase. Therefore, the parameterization of the physical properties of atoms and molecules interacting with dust grain particles is clearly a key aspect to interpret astronomical observations and to build realistic and predictive astrochemical models. In this consensus evaluation, we focus on parameters controlling the thermal desorption of ices and how these determine pathways towards molecular complexity and define the location of snowlines, which ultimately influence the planet formation process. We review different crucial aspects of desorption parameters both from a theoretical and experimental point of view. We critically assess the desorption parameters commonly used in the astrochemical community for astrophysical relevant species and provide tables with recommended values. In addition, we show that a non-trivial determination of the pre-exponential factor nu using the Transition State Theory can affect the binding energy value. Finally, we conclude this work by discussing the limitations of theoretical and experimental approaches currently used to determine the desorption properties with suggestions for future improvements.

astro-ph.GA↗

arXiv2022

FAUST III. Misaligned rotations of the envelope, outflow, and disks in the multiple protostellar system of VLA 1623$-$2417

We report a study of the low-mass Class-0 multiple system VLA 1623AB in the Ophiuchus star-forming region, using H$^{13}$CO$^+$ ($J=3-2$), CS ($J=5-4$), and CCH ($N=3-2$) lines as part of the ALMA Large Program FAUST. The analysis of the velocity fields revealed the rotation motion in the envelope and the velocity gradients in the outflows (about 2000 au down to 50 au). We further investigated the rotation of the circum-binary VLA 1623A disk as well as the VLA 1623B disk. We found that the minor axis of the circum-binary disk of VLA 1623A is misaligned by about 12 degrees with respect to the large-scale outflow and the rotation axis of the envelope. In contrast, the minor axis of the circum-binary disk is parallel to the large-scale magnetic field according to previous dust polarization observations, suggesting that the misalignment may be caused by the different directions of the envelope rotation and the magnetic field. If the velocity gradient of the outflow is caused by rotation, the outflow has a constant angular momentum and the launching radius is estimated to be $5-16$ au, although it cannot be ruled out that the velocity gradient is driven by entrainments of the two high-velocity outflows. Furthermore, we detected for the first time a velocity gradient associated with rotation toward the VLA 16293B disk. The velocity gradient is opposite to the one from the large-scale envelope, outflow, and circum-binary disk. The origin of its opposite gradient is also discussed.

astro-ph.GA↗

arXiv2021

Computational investigation on the thermodynamics of H2CO + NH2 NH2CHO + H on interstellar water ice surfaces

Formamide has a key role in prebiotic chemistry as it is the simplest molecule containing the four most important atoms from a biological point of view: hydrogen, carbon, nitrogen and oxygen. Due to its importance, the formation of this molecule has been studied and different pathways have been considered both in gas-phase and on ices of dust grains since it was first detected. In the present work, the thermodynamics of the formation route of formamide starting from NH2 and H2CO, a reaction channel proposed to occur in the gas phase, has been theoretically investigated in the scenario taking place on icy dust grains modelled by both a cluster and a periodic approach. Different DFT functionals have been employed to obtain accurate energy values for the mechanistic steps involved in the reaction.

physics.chem-ph↗

arXiv2021

Ab initio Calculation of Binding Energies of Interstellar Sulphur-Containing Species on Crystalline Water Ice Models

There are different environments in the interstellar medium (ISM), depending on the density, temperature and chemical composition. Among them, molecular clouds, often referred to as the cradle of stars, are paradigmatic environments relative to the chemical diversity and complexity in space. Indeed, there, radio to far-infrared observations revealed the presence of several molecules in the gas phase, while near-infrared spectroscopy detected the existence of submicron sized dust grains covered by H2O -dominated ice mantles. The interaction between gas-phase species and the surfaces of water ices is measured by the binding energy (BE), a crucial parameter in astrochemical modelling. In this work, the BEs of a set of sulphur-containing species on water ice mantles have been computed by adopting a periodic ab initio approach using a crystalline surface model. The Density Functional Theory (DFT)-based B3LYP-D3(BJ) functional was used for the prediction of the structures and energetics. DFT BEs were refined by adopting an ONIOM-like procedure to estimate them at CCSD(T) level toward complete basis set extrapolation, in which a very good correlation between values has been found. Moreover, we show that geometry optimization with the computationally cheaper HF-3c method followed by single point energy calculations at DFT to compute the BEs is a suitable cost-effective recipe to arrive at BE values of the same quality as those computed at full DFT level. Finally, computed data were compared with the available literature data.

astro-ph.GA↗

arXiv2021

Using fireball networks to track more frequent reentries: Falcon 9 upper stage orbit determination from video recordings

On February 16, 2021, an artificial object was recorded by the Spanish Meteor Network (SPMN) moving slowly over the Mediterranean. From the astrometric measurements, we identify this event as the reentry engine burn of a SpaceX Falcon 9 launch vehicle's upper stage. To study this event in detail, we adapted the plane intersection method for near-straight meteoroid trajectories to analyze slow and curved orbits associated with artificial objects. To corroborate our results, we approximated the orbital elements for the upper stage using four pieces of "debris" cataloged by the U.S. Government Combined Space Operations Center (CSpOC). Based on these calculations, we also estimated the possible deorbit hazard zone using the MSISE90 model atmosphere. We warn of the interference that these artificial bolides might have in fireball studies. In addition, given that artificial bolides will be probably more frequent in the future, we point out the new role that ground-based detection networks can play in the monitoring of potentially hazardous artificial objects in near-Earth space and determining the strewn field of artificial space debris.

astro-ph.EP↗

arXiv2021

Theoretical computations on the efficiency of acetaldehyde formation on interstellar icy grains

Interstellar grains are known to be important actors in the formation of interstellar molecules such as H$_2$, water, ammonia, and methanol. It has been suggested that the so-called interstellar complex organic molecules (iCOMs) are also formed on the interstellar grain icy surfaces by the combination of radicals via reactions assumed to have an efficiency equal to unity. In this work, we aim to investigate the robustness or weakness of this assumption by considering the case of acetaldehyde (CH$_3$CHO) as a starting study case. In the literature, it has been postulated that acetaldehyde is formed on the icy surfaces via the combination of HCO and CH$_3$. Here we report new theoretical computations on the efficiency of its formation. To this end, we coupled quantum chemical calculations of the energetics and kinetics of the reaction CH$_3$ + HCO, which can lead to the formation of CH$_3$CHO or CO + CH$_4$. Specifically, we combined reaction kinetics computed with the Rice-Ramsperger-Kassel-Marcus (RRKM) theory (tunneling included) method with diffusion and desorption competitive channels. We provide the results of our computations in the format used by astrochemical models to facilitate their exploitation. Our new computations indicate that the efficiency of acetaldehyde formation on the icy surfaces is a complex function of the temperature and, more importantly, of the assumed diffusion over binding energy ratio $f$ of the CH$_3$ radical. If the ratio $f$ is $\geq$0.4, the efficiency is equal to unity in the range where the reaction can occur, namely between 12 and 30 K. However, if $f$ is smaller, the efficiency dramatically crashes: with $f$=0.3, it is at most 0.01. In addition, the formation of acetaldehyde is always in competition with that of CO + CH$_4$.

astro-ph.GA↗

arXiv2021

Accurate 3D fireball trajectory and orbit calculation using the 3D-FireTOC automatic Python code

The disruption of asteroids and comets produces cm-sized meteoroids that end up impacting the Earth's atmosphere and producing bright fireballs that might have associated shock waves or, in geometrically-favorable occasions excavate craters that put them into unexpected hazardous scenarios. The astrometric reduction of meteors and fireballs to infer their atmospheric trajectories and heliocentric orbits involves a complex and tedious process that generally requires many manual tasks. To streamline the process, we present a software package called SPMN 3D Fireball Trajectory and Orbit Calculator (3D-FireTOC), an automatic Python code for detection, trajectory reconstruction of meteors, and heliocentric orbit computation from video recordings. The automatic 3D-FireTOC package comprises of a user interface and a graphic engine that generates a realistic 3D representation model, which allows users to easily check the geometric consistency of the results and facilitates scientific content production for dissemination. The software automatically detects meteors from digital systems, completes the astrometric measurements, performs photometry, computes the meteor atmospheric trajectory, calculates the velocity curve, and obtains the radiant and the heliocentric orbit, all in all quantifying the error measurements in each step. The software applies corrections such as light aberration, refraction, zenith attraction, diurnal aberration and atmospheric extinction. It also characterizes the atmospheric flight and consequently determines fireball fates by using the $α- β$ criterion that analyses the ability of a fireball to penetrate deep into the atmosphere and produce meteorites. We demonstrate the performance of the software by analyzing two bright fireballs recorded by the Spanish Fireball and Meteorite Network (SPMN).

astro-ph.EP↗

arXiv2021

Study of Fischer-Tropsch Type reactions on chondritic meteorites

How simple organic matter appeared on Earth and the processes by which it transformed into more evolved organic compounds, which ultimately led to the emergence of life, is still an open topic. Different scenarios have been proposed, the main one assumes that simple organic compounds were synthesized, either in the gas phase or on the surfaces of dust grains, during the process of star formation, and were incorporated into larger bodies in the protoplanetary disk. Transformation of these simple organic compounds in more complex forms is still a matter of debate. Recent discoveries point out to catalytic properties of dust grains present in the early stellar envelope, which can nowadays be found in the form of chondrites. The huge infall of chondritic meteorites during the early periods of Earth suggests that the same reactions could have taken place in certain environments of the Earth surface, with conditions more favorable for organic synthesis. This work attempts the synthesis of simple organic molecules, such as hydrocarbons and alcohols, via Fischer-Tropsch Type reactions supported by different chondritic materials under early-Earth conditions, to investigate if organic synthesis can likely occur in this environment and which are the differences in selectivity when using different types of chondrites. Fischer-Tropsch-type reactions are investigated from mixtures of CO and H2 at 1 atm of pressure on the surfaces of different chondritic samples. The different products obtained are analyzed in situ by gas chromatography. Different Fischer-Tropsch reaction products are obtained in quantitative amounts. The formation of alkanes and alkenes being the main processes. Formation of alcohols also takes place in a smaller amount. Other secondary products were obtained in a qualitative way.

astro-ph.EP↗

arXiv2021

H2 formation on interstellar grains and the fate of reaction energy

Molecular hydrogen is the most abundant molecular species in the Universe. While no doubts exist that it is mainly formed on the interstellar dust grain surfaces, many details of this process remain poorly known. In this work, we focus on the fate of the energy released by the H$_2$ formation on the dust icy mantles, how it is partitioned between the substrate and the newly formed H$_2$, a process that has a profound impact on the interstellar medium. We carried out state-of-art \textit{ab-initio} molecular dynamics simulations of H$_2$ formation on periodic crystalline and amorphous ice surface models. Our calculations show that up to two thirds of the energy liberated in the reaction ($\sim$300 kJ/mol $\sim$3.1 eV) is absorbed by the ice in less than 1 ps. The remaining energy ($\sim$140 kJ/mol $\sim$1.5 eV) is kept by the newly born H$_2$. Since it is ten times larger than the H$_2$ binding energy on the ice, the new H$_2$ molecule will eventually be released into the gas-phase. The ice water molecules within $\sim$4 Å~from the reaction site acquire enough energy, between 3 and 14 kJ/mol (360--1560 K), to potentially liberate other frozen H$_2$ and, perhaps, frozen CO molecules. If confirmed, the latter process would solve the long standing conundrum of the presence of gaseous CO in molecular clouds. Finally, the vibrational state of the newly formed H$_2$ drops from highly excited states ($ν= 6$) to low ($ν\leq 2$) vibrational levels in a timescale of the order of ps.

astro-ph.GA↗