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Alberto Garilli

Publications and source records attributed to Alberto Garilli.

7 recordsLinked to original sources

Exact asymptotic equivalence between precisions of record-times and integrated currents

We establish an exact equivalence between the fluctuations of integrated currents and the temporal statistics of current record events in continuous-time Markov jump processes. Specifically, we show that, under minimal assumptions, the Fano factor of an integrated current coincides exactly with the squared coefficient of variation of the inter-record waiting times. This result is obtained by showing that inter-record times induce a renewal structure, since each record event resets the system to a fixed state, and that their generating function can be expressed exactly in terms of a combinatorial organization governed by Narayana numbers. The equivalence extends previous results obtained for unicyclic networks to arbitrary finite-state graphs and provides a unified representation of current fluctuations in terms of record-time observables. The results are derived within a purely probabilistic framework and clarify the structural origin of current precision in terms of first-passage-like event statistics.

cond-mat.stat-mech

Using precision coefficients on recurrence times and integrated currents to lower bound the average dissipation rate

For continuous-time Markov jump processes on irreducible networks with time-independent rate constants, we employ a transition-based formalism to express the long-time precision of a single integrated current over an observable channel in terms of precisions of the recurrence times of the forward and backward jumps, and of an effective affinity that captures the thermodynamic driving on that channel. This leads to a general inequality that, similarly to the well-known Thermodynamic Uncertainty Relation (TUR), links the stationary entropy production rate with the fluctuations of an integrated current, but also incorporates the statistics of the forward and backward recurrence times. Such inequality can be saturated in less restrictive conditions than the TUR, and potentially offers new opportunities for the optimization and design of biological and chemical out-of-equilibrium systems at the nanoscale.

cond-mat.stat-mech

Interrelation between precisions on integrated currents and on recurrence times in Markov jump processes

For Markov jump processes on irreducible networks with finite number of sites, we derive a general and explicit expression of the squared coefficient of variation for the net number of transitions from one site to a connected site in a given time window of observation (i.e., an `integrated current' as dynamical output). Such expression, which in itself is particularly useful for numerical calculations, is then elaborated to obtain the interrelation with the precision on the intrinsic timing of the recurrences of the forward and backward transitions. In biochemical ambits, such as enzyme catalysis and molecular motors, the precision on the timing is quantified by the so-called randomness parameter and the above connection is established in the long time limit of monitoring and for an irreversible site-site transition; the present extension to finite time and reversibility adds a new dimension. Some kinetic and thermodynamic inequalities are also derived.

cond-mat.stat-mech

Fluctuation relations for a few observable currents at their own beat

Coarse-grained models are widely used to explain the effective behavior of partially observable physical systems with hidden degrees of freedom. Reduction procedures in state space typically disrupt Markovianity and a fluctuation relation cannot be formulated. A recently developed framework of transition-based coarse-graining gave rise to a fluctuation relation for a single current, while all others are hidden. Here, we extend the treatment to an arbitrary number of observable currents. Crucial for the derivation are the concepts of mixed currents and their conjugated effective affinities, that can be inferred from the time series of observable transitions. We also discuss the connection to generating functions, transient behavior, and how our result recovers the fluctuation relation for a complete set of currents.

cond-mat.stat-mech

Methods and Conversations in (Post)Modern Thermodynamics

Lecture notes after the doctoral school (Post)Modern Thermodynamics held at the University of Luxembourg, December 2022, 5-7, covering and advancing continuous-time Markov chains, network theory, stochastic thermodynamics, large deviations, deterministic and stochastic chemical reaction networks, metastability, martingales, quantum thermodynamics, and foundational issues.

cond-mat.stat-mech

Beat of a current

The fluctuation relation, a milestone of modern thermodynamics, is only established when a set of fundamental currents can be measured. Here we prove that it also holds for systems with hidden transitions if observations are carried ``at their own beat,'' that is, by stopping the experiment after a fixed number of visible transitions, rather than the elapse of an external clock time. This suggests that thermodynamic symmetries are more resistant to the loss of information when described in the space of transitions.

cond-mat.stat-mech

Sustaining a temperature difference

We derive an expression for the minimal rate of entropy that sustains two reservoirs at different temperatures $T_0$ and $T_\ell$. The law displays an intuitive $\ell^{-1}$ dependency on the relative distance and a characterisic $\log^2 (T_\ell/T_0)$ dependency on the boundary temperatures. First we give a back-of-envelope argument based on the Fourier Law (FL) of conduction, showing that the least-dissipation profile is exponential. Then we revisit a model of a chain of oscillators, each coupled to a heat reservoir. In the limit of large damping we reobtain the exponential and squared-log behaviors, providing a self-consistent derivation of the FL. For small damping "equipartition frustration" leads to a well-known balistic behaviour, whose incompatibility with the FL posed a long-time challenge.

cond-mat.stat-mech