arXiv subjects

Alberto Rodriguez-Ardila

Publications and source records attributed to Alberto Rodriguez-Ardila.

18 recordsLinked to original sources

arXiv2025

The Coronal Line Region of Active Galactic Nuclei

Forbidden coronal lines has traditionally called the attention due to the high-energy photons required for their production (IP $>$100~eV, where IP is the ionisation potential of the transitions that originate the line). As such, they are regarded as the most highly ionised component of Active Galactic Nuclei (AGN). For decades, it was thought that they were only formed in the inner portions of the narrow line region (NLR). Nowadays, due to the larger sensitivity of the detectors and the availability of integral field unit (IFU) spectrographs, that emission in addition to the nuclear component is found to be extended up to a few kiloparsecs away from the active centre. In this review, we highlight the most important aspects of the coronal emission and discuss the recent developments in the field. In particular, we emphasize the discovery that they can be used to determine the mass of the central supermassive black hole, to reconstruct the SED, as well as to trace the most energetic feedback component of the ionised gas in AGN.

astro-ph.GA↗

arXiv2024

Observational constraints on the stellar recycled gas in active galactic nuclei feeding

Near-infrared long-slit spectroscopy has been used to study the stellar population (SP) of the low luminosity active galactic nuclei (AGN) and matched analogues (LLAMA) sample. To perform the SP fits we have employed the X-shooter simple stellar population models together with the \st\ code. Our main conclusions are: The star formation history of the AGNs is very complex, presenting many episodes of star formation during their lifetimes. In general, AGN hosts have higher fractions of intermediate-age SP (light-weighted mean ages, $ _L\lesssim$ 4.5 Gyr) when compared with their analogues ($ _L\lesssim$ 8.0 Gyr). AGN are more affected by reddening and require significant fractions of featureless continuum and hot dust components. The ratio between the AGN radiated energy and the gravitational potential energy of the molecular gas ($E_{Rad}$/$E_{PG}$) for the AGN is compared with the \maL\ and a possible anti-correlation is observed. This suggests that the AGN is affecting the star formation in these galaxies, in the sense that more energetic AGN (log$(E_{Rad}$/$E_{PG}) \gtrsim 3$) tend to host nuclear younger SP ($ _L \lesssim$4Gyr). We found that the recent ($t<$2~Gyr) returned (recycled) stellar mass is higher in AGN than in the controls. We also provide evidence that the mass loss of stars would be enough to feed the AGN, thus providing observational constraints for models that predict that AGN feeding is partially due to the recycled gas from dying stars.

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arXiv2024

First detection of outflowing gas in the outskirts of the broad line region in 1H-0707-495

We use near-infrared (NIR) spectroscopy covering simultaneously the $zJHK$ bands to look for outflowing gas from the nuclear environment of 1H0707-495 taking advantage that this region is dominated by low-ionization broad line region (BLR) lines, most of them isolated. We detect broad components in HI, FeII and OI, at rest to the systemic velocity, displaying full width at half maximum (FWHM) values of ~500 km s$^{-1}$, consistent with its classification as a narrow-line Seyfert~1 AGN. Moreover, most lines display a conspicuous blue-asymmetric profile, modeled using a blueshifted component, whose velocity shift reaches up to ~826 km s$^{-1}$. This last feature can be interpreted in terms of outflowing gas already observed in X-ray and UV lines in 1H0707-495 but not detected before in the low-ionization lines. We discuss the relevance of our findings within the framework of the wind scenario already proposed for this source and suggest that the wind extends well into the narrow line region due to the observation of a blueshifted component in the forbidden line of [SIII] $λ$9531.

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arXiv2023

Spectral variability studies in Active Galactic Nuclei: Exploring continuum and emission line regions in the age of LSST and JWST

The investigation of emission line regions within active galaxies (AGNs) has a rich and extensive history, now extending to the use of AGNs and quasars as "standardizable" cosmological indicators, shedding light on the evolution of our universe. As we enter the era of advanced observatories, such as the successful launch of JWST and the forthcoming Vera C. Rubin Observatory's Legacy Survey of Space and Time (LSST), the landscape of AGN exploration across cosmic epochs is poised for exciting advancements. In this work, we delve into recent developments in AGN variability research, anticipating the substantial influx of data facilitated by LSST. The article highlights recent strides made by the AGN Polish Consortium in their contributions to LSST. The piece emphasizes the role of quasars in cosmology, dissecting the intricacies of their calibration as standard candles. The primary focus centers on the relationship between the broad-line region size and luminosity, showcasing recent breakthroughs that enhance our comprehension of this correlation. These breakthroughs encompass a range of perspectives, including spectroscopic analyses, photoionization modeling, and collaborative investigations with other cosmological tools. The study further touches on select studies, underlining how the synergy of theoretical insights and advancements in observational capabilities has yielded deeper insights into these captivating cosmic entities.

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arXiv2022

Powerful yet lonely: Is 3C 297 a high-redshift fossil group?

The environment of the high-redshift (z=1.408), powerful radio-loud galaxy 3C 297 has several distinctive features of a galaxy cluster. Among them, a characteristic halo of hot gas revealed by Chandra X-ray observations. In addition, a radio map obtained with the Very Large Array (VLA) shows a bright hotspot in the northwestern direction, created by the interaction of the AGN jet arising from 3C 297 with its environment. In the X-ray images, emission cospatial with the northwestern radio lobe is detected, and peaks at the position of the radio hotspot. The extended, complex X-ray emission observed with our new Chandra data is largely unrelated to its radio structure. Despite having attributes of a galaxy cluster, no companion galaxies have been identified from 39 new spectra of neighboring targets of 3C 297 obtained with the Gemini Multi-Object Spectrograph. None of the 19 galaxies for which a redshift was determined lies at the same distance as 3C 297. The optical spectral analysis of the new Gemini spectrum of 3C 297 reveals an isolated Type-II radio-loud AGN. We also detected line broadening in [O II](3728) with a FWHM about 1700 km/s and possible line shifts of up to 500-600 km/s. We postulate that the host galaxy of 3C 297 is a fossil group, in which most of the stellar mass has merged into a single object, leaving behind an X-ray halo.

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arXiv2022

BASS XXVIII: Near-infrared Data Release 2, High-Ionization and Broad Lines in Active Galactic Nuclei

We present the BAT AGN Spectroscopic Survey (BASS) Near-infrared Data Release 2 (DR2), a study of 168 nearby ($\bar z$ = 0.04, $z$ < 0.6) active galactic nuclei (AGN) from the all-sky Swift Burst Array Telescope X-ray survey observed with Very Large Telescope (VLT)/X-shooter in the near-infrared (NIR; 0.8 - 2.4 $μ$m). We find that 49/109 (45%) Seyfert 2 and 35/58 (60%) Seyfert 1 galaxies observed with VLT/X-shooter show at least one NIR high-ionization coronal line (CL, ionization potential $χ$ > 100 eV). Comparing the emission of the [Si vi] $λ$1.9640 CL with the X-ray emission for the DR2 AGN, we find a significantly tighter correlation, with a lower scatter (0.37 dex) than for the optical [O iii] $λ$5007 line (0.71 dex). We do not find any correlation between CL emission and the X-ray photon index $Γ$. We find a clear trend of line blueshifts with increasing ionization potential in several CLs, such as [Si vi] $λ$1.9640, [Si x] $λ$1.4300, [S viii] $λ$0.9915, and [S ix] $λ$1.2520, indicating the radial structure of the CL region. Finally, we find a strong underestimation bias in black hole mass measurements of Sy 1.9 using broad H$α$ due to the presence of significant dust obscuration. In contrast, the broad Pa$α$ and Pa$β$ emission lines are in agreement with the $M$-$σ$ relation. Based on the combined DR1 and DR2 X-shooter sample, the NIR BASS sample now comprises 266 AGN with rest-frame NIR spectroscopic observations, the largest set assembled to date.

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arXiv2020

A 700-pc extended coronal gas emission in the Circinus galaxy

We report the first characterization of an extended outflow of high ionized gas in the Circinus Galaxy by means of the coronal line [FeVII] $λ$6087 Å. This emission is located within the ionization cone already detected in the [OIII] $λ$5007 Å line and is found to extend up to a distance of 700 pc from the AGN. The gas distribution appears clumpy, with several knots of emission. Its kinematics is complex, with split profiles and line centroids shifted from the systemic velocity. The physical conditions of the gas show that the extended coronal emission is likely the remnants of shells inflated by the passage of a radio-jet. This scenario is supported by extended X-ray emission, which is spatially coincident with the morphology and extension of the [FeVII] $λ$6087~Å gas in the NW side of the galaxy. The extension of the coronal gas in the Circinus galaxy is unique among active galaxies and demonstrates the usefulness of coronal lines for tracing the shock ionization component in these objects.

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arXiv2019

A close look at the dwarf AGN of NGC 4395: optical and near-IR integral field spectroscopy

Intermediate mass black holes (10$^3$-10$^5$ M$_\odot$) in the center of dwarf galaxies are believed to be analogous to growing Active Galactic Nuclei (AGN) in the early Universe. Their characterization can provide insight about the early galaxies. We present optical and near-infrared integral field spectroscopy of the inner $\sim$50 pc of the dwarf galaxy NGC4395, known to harbor an AGN. NGC 4395 is an ideal candidate to investigate the nature of dwarf AGN, as it is nearby ($d\approx4.4$ Mpc) enough to allow a close look at its nucleus. The optical data were obtained with the Gemini GMOS-IFU covering the 4500 A to 7300 A spectral range at a spatial resolution of 10 pc. The J and K-band spectra were obtained with the Gemini NIFS at spatial resolutions of $\sim$5 pc. The gas kinematics show a compact, rotation disk component with a projected velocity amplitude of 25 km s$^{-1}$. We estimate a mass of $7.7\times10^5$ M$_\odot$ inside a radius of 10 pc. From the H$α$ broad line component, we estimate the AGN bolometric luminosity as $L_{ bol}=(9.9\pm1.4)\times10^{40}$ erg s$^{-1}$ and a mass $M_{ BH}=(2.5^{+1.0}_{-0.8})\times10^5$ M$_\odot$ for the central black hole. The mean surface mass densities for the ionized and molecular gas are in the ranges (1-2) M$_{\odot} $pc$^{-2}$ and (1-4)$\times10^{-3}$ M${_\odot}$ pc$^{-2}$ and the average ratio between ionized and hot molecular gas masses is $\sim$500. The emission-line flux distributions reveal an elongated structure at 24 pc west of the nucleus, which is blueshifted relative to the systemic velocity of the galaxy by $\approx$30 km s$^{-1}$. We speculate that this structure is originated by the accretion of a gas-rich small satellite or by a low metallicity cosmic cloud.

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arXiv2018

Powerful mechanical-driven outflows in the central parsecs of the Low-Luminosity Active Galactic Nucleus ESO428-G14

Low-Luminosity Active Galactic Nuclei (LLAGN) are characterized for low radiative efficiency, much less than one percent of their Eddington limit. Nevertheless, their main energy release may be mechanical, opposite to powerful AGN classes like Seyfert and Quasars. This work reports on the jet-driven mechanical energy and the corresponding mass outflow deposited by the jet in the central 170~parsecs of the nearby LLAGN ESO428-G14. The jet kinetic output is traced through the coronal line [Si vi] $λ$19641 Å. It is shown that its radial extension, up to hundreds of parsecs, requires a combination of photoionization by the central source and shock excitation as its origin. From the energetics of the ionized gas it is found that the mass outflow rate of the coronal gas is in the range from 3$-8$~M$\odot$~yr$^{-1}$, comparable to those estimated from H I gas at kiloparsec scales in powerful radio galaxies.

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arXiv2018

3C 17: The BCG of a galaxy cluster at z=0.22

Gemini Multi Object Spectrograph medium-resolution spectra and photometric data of 39 objects in the field of the radio galaxy 3C 17 are presented. Based on the new data, a previously uncataloged cluster of galaxies is identified at a mean redshift of z=0.220 +/-0.003, a projected virial radius of 0.37 Mpc, and a velocity dispersion of sigma_v = 821 +/-171 km/s. The brightest member of this cluster is 3C 17 with M_r = -22.45 mag. The surface brightness profile of 3C 17 is best fit with two components (Exponential + Sersic) characteristic of brightest cluster galaxies. The spectrum of 3C 17 is dominated by broad emission lines Halpha + N[II] and Hbeta + [OIII]. Analysis of Chandra data shows extended emission around the cluster core that supports the existence of hot gas cospatial with 3C 17. The discovery of a cluster of galaxies around 3C 17 better explains the sharply bent morphology of the radio jet given that it propagates through a dense intracluster medium.

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arXiv2015

Understanding the two-dimensional ionization structure in luminous infrared galaxies. A near-IR integral field spectroscopy perspective

We investigate the 2D excitation structure of the ISM in a sample of LIRGs and Seyferts using near-IR IFS. This study extends to the near-IR the well-known optical and mid-IR emission line diagnostics used to classify activity in galaxies. Based on the spatially resolved spectroscopy of prototypes, we identify in the [FeII]1.64/Br$γ$ - H_2 1-0S(1)/Br$γ$ plane regions dominated by the different heating sources, i.e. AGNs, young MS massive stars, and evolved stars i.e. supernovae. The ISM in LIRGs occupy a wide region in the near-IR diagnostic plane from -0.6 to +1.5 and from -1.2 to +0.8 (in log units) for the [FeII]/Br$γ$ and H_2/Br$γ$ line ratios, respectively. The corresponding median(mode) ratios are +0.18(0.16) and +0.02(-0.04). Seyferts show on average larger values by factors ~2.5 and ~1.4 for the [FeII]/Br$γ$ and H_2/Br$γ$ ratios, respectively. New areas and relations in the near-IR diagnostic plane are defined for the compact, high surface brightness regions dominated by AGN, young ionizing stars, and SNe explosions, respectively. In addition, the diffuse regions affected by the AGN radiation field cover an area similar to that of Seyferts, but with high values in [FeII]/Br$γ$ that are not as extreme. The extended, non-AGN diffuse regions cover a wide area in the diagnostic diagram that overlaps that of individual excitation mechanisms (i.e. AGN, young stars, and SNe), but with its mode value to that of the young SF clumps. This indicates that the excitation conditions of the diffuse ISM are likely due to a mixture of the different ionization sources. The integrated line ratios in LIRGs show higher excitation conditions i.e. towards AGNs, than those measured by the spatially resolved spectroscopy. If this behaviour is representative, it would have clear consequences when classifying high-z, SF galaxies based on their near-IR integrated spectra.

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arXiv2015

Differences between CO- and calcium triplet-derived velocity dispersions in spiral galaxies: evidence for central star formation?

We examine the stellar velocity dispersions (sigma) of a sample of 48 galaxies, 35 of which are spirals, from the Palomar nearby galaxy survey. It is known that for ultra-luminous infrared galaxies (ULIRGs) and merger remnants thesigma derived from the near-infrared CO band-heads is smaller than that measured from optical lines, while no discrepancy between these measurements is found for early-type galaxies. No such studies are available for spiral galaxies - the subject of this paper. We used cross-dispersed spectroscopic data obtained with the Gemini Near-Infrared Spectrograph (GNIRS), with spectral coverage from 0.85 to 2.5um, to obtain sigma measurements from the 2.29 $μ$m CO band-heads (sigma_{CO}), and the 0.85 um calcium triplet (sigma_{CaT}). For the spiral galaxies in the sample, we found that sigma_{CO} is smaller than sigma_{CaT}, with a mean fractional difference of 14.3%. The best fit to the data is given by sigma_{opt} = (46.0+/-18.1) + (0.85+/-0.12)sigma_{CO}. This "sigma discrepancy" may be related to the presence of warm dust, as suggested by a slight correlation between the discrepancy and the infrared luminosity. This is consistent with studies that have found no sigma-discrepancy in dust-poor early-type galaxies, and a much larger discrepancy in dusty merger remnants and ULIRGs. That sigma_{CO}$ is lower than sigma_{opt} may also indicate the presence of a dynamically cold stellar population component. This would agree with the spatial correspondence between low sigma_{CO} and young/intermediate-age stellar populations that has been observed in spatially-resolved spectroscopy of a handful of galaxies.

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arXiv2014

Absorption at the dust sublimation radius and the dichotomy between X-ray and optical classification in the Seyfert galaxy H0557-385

In this work, the analysis of multi-epoch (1995-2010) X-ray observations of the Seyfert 1 galaxy H0557-385 is presented. The wealth of data presented in this analysis show that the source exhibits dramatic spectral variability, from a typical unabsorbed Seyfert 1 type spectrum to a Compton-thin absorbed state, on time scales of ~5 years. This extreme change in spectral shape can be attributed to variations in the column density and covering fraction of a neutral absorbing medium attenuating the emission from the central continuum source. Evidence for Compton reflection of the intrinsic nuclear emission is present in each of the spectra, though this feature is most prominent in the low-state spectra, where the associated Fe emission line complex is clearly visible. In addition to the variable absorbing medium, a warm absorber component has been detected in each spectral state. Optical spectroscopy concurrent with the 2010 XMM-Newton observation campaign have detected the presence of broad optical emission lines during an X-ray absorption event.From the analysis of both X-ray and optical spectroscopic data, it has been inferred that the X-ray spectral variability is a result of obscuration of the central emission region by a clumpy absorber covering >80 per cent of the source with an average column density of NH ~7x10^{23} cm^{-2}, and which is located outside the broad line region at a distance from the central source consistent with the dust sublimation radius of the AGN.

astro-ph.HE↗

arXiv2012

A correlation between the stellar and [Fe II] velocity dispersions in Active Galaxies

We use near-infrared spectroscopic data from the inner few hundred parsecs of a sample of 47 active galaxies to investigate possible correlations between the stellar velocity dispersion (sigma_star), obtained from the fit of the K-band CO stellar absorption bands, and the gas velocity dispersion (sigma) obtained from the fit of the emission-line profiles of [SIII]0.953um, [Fe II]1.257um, [FeII]1.644um and H_2 2.122um. While no correlations with sigma_star were found for H_2 and [SIII], a good correlation was found for the two [Fe II] emission lines, expressed by the linear fit sigma_star = 95.4\pm16.1 + (0.25\pm0.08)sigma_[Fe II]. Excluding barred objects from the sample a better correlation is found between sigma_star and sigma_[FeII], with a correlation coefficient of R=0.80 and fitted by the following relation: sigma_\star = 57.9\pm23.5 + (0.42\pm0.10)sigma_[FeII]. This correlation can be used to estimate $σ_\star$ in cases it cannot be directly measured and the [FeII] emission lines are present in the spectra, allowing to obtain the mass of the supermassive black hole (SMBH) from the M-σ_\star relation. The scatter from a one-to-one relationship between sigma_star and its value derived from sigma_[FeII] using the equation above for our sample is 0.07dex, which is smaller than that obtained in previous studies which use σ_[OIII] in the optical as a proxy for sigma_star. The use of sigma_[Fe\,II] in the near-IR instead of sigma_[OIII] in the optical is a valuable option for cases in which optical spectra are not available or are obscured, as is the case of many AGN.

astro-ph.CO↗

arXiv2006

Outflows of very ionized gas in the center of Seyfert galaxies: kinematics and physical conditions

Mid-resolution spectra are used to deduce the size and kinematics of the coronal gas in a sample of Seyfert galaxies by means of observations of the [FeXI], [FeX], [FeVII], [SiVI] and [SiVII] lines. These coronal lines (CL) extend from the unresolved nucleus up to a few tens to a few hundreds of parsecs. The region of the highest ionized ions studied, [FeXI] and [FeX], is the least spatially extended, and concentrates at the center; intermediate ionization lines extend from the nucleus up to a few tens to a few hundred parsecs; lower [OIII]-like ions are known to extendin the kpc range. All together indicates a stratification in the ionized gas, usually interpreted in terms of nuclear photoionization as the driving ionization mechanism. However, CL profiles show various peculiarities: they are broader by a factor of two than lower ionization lines, the broadening being in terms of asymmetric blue wings, and their centroid position at the nucleus is blueshifted by a few hundreds of km/s. Moreover, in NGC1386 and NGC1068, a double peak [FeVII] line is detected in the nuclear and extended coronal region, this being the first report in of such type of profile in CL in active galactic nuclei. If interpreted as outflow signatures, the total broadening of the lines at zero intensity levels implies gas velocities up to 2000 km/s. Although the stratification of ions across the coronal region means that photoionization is the main power mechanism, the high velocities deduced from the profiles, the relatively large spatial extension of the emission, and the results from photoionization models indicate that an additional mechanism is at work. We suggest that shocks generated by the outflow could provide the additional required power for line formation.

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arXiv2004

Molecular Hydrogen and [FeII] in Active Galactic Nuclei

(Abridge) Near-infrared spectroscopy is used to study the kinematics and excitation mechanisms of the H2 and [FeII] gas in a sample of AGN. The H2 lines are unresolved in all objects in which they were detected while the [FeII] lines have widths implying gas velocities of up to 650 km/s. This suggests that, very likely, the H2 and [FeII] emission does not originate from the same parcel of gas. Molecular H2 were detected in 90% of the sample, including PG objects, indicating detectavel amounts of molecular material even in objects with low levels of circumnuclear starburst activity. The data favors thermal excitation for the H2 lines. Indeed, in NGC3227, Mrk766, NGC4051 and NGC4151, the molecular emission is found to be purely thermal. This result is also confirmed by the rather similar vibrational and rotational temperatures in the objects for which they were derived. [FeII] lines are detected in all of the AGN. The [FeII] 1.254mu/Pa-beta ratio is compatible with excitation of the [FeII] by the active nucleus, but in Mrk 766 it implies a stellar origin. A correlation between H2/Br-gamma and [FeII]/Pa-beta is found. We confirm that it is a useful diagnostic tool in the NIR to separate emitting line objects by their level of nuclear activity. X-ray excitation models are able to explain the observed H2 and part of the [FeII] emission. Most likely, a combination of X-ray heating, shocks driven by the radio jet, and circumnuclear star formation contributes, in different proportions, to the H2 and [FeII] emission. In most of our spectra, the [FeII] 1.257mu/1.644mu ratio is found to be 30% lower than the intrinsic value based on current atomic data. This implies either than the extinction towards the [FeII] emitting clouds is very similar in most objects or there are possible inaccuracies in the A-values in the [FeII] transitions.

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arXiv2003

The Narrow Line Region of Ark 564

The continuum and emission-line spectrum of the narrow-line Seyfert 1 galaxy Ark 564 is used to investigate, for the first time, the physical conditions and structure of its narrow line region (NLR). For this purpose, composite models, accounting for the coupled effect of photoionization and shocks, are employed. The emission-line spectrum of Ark 564, which ranges from the ultraviolet to the near-infrared, shows a rich forbidden line spectrum. Strong emphasis is given to the study of the coronal line region. The diversity of physical conditions deduced from the observations requires multi-cloud models to reproduce the observed lines and continuum. We find that a combination of high velocity (Vs = 1500 km/s) shock-dominated clouds as well as low velocity (Vs = 150 km/s) radiation-dominated clouds explains the coronal lines, while the optical low-ionization lines are mainly explained by shock-dominated clouds. The results for Ark 564 are compared with those obtained for other Seyfert galaxies previously analyzed such as NGC 5252, Circinus, NGC 4051 and NGC 4151. The model results for the ultraviolet and optical permitted lines suggest that the broad line region may contribute up to 80%, depending on the emission-line, being of about 30% for Hbeta. The consistency of the multi-cloud model is checked by comparing the predicted and observed continuum, from radio to X-ray, and indicate that the dust-to-gas ratio in the clouds varies from 10^{-15} to 10^{-12}.

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arXiv2002

Near-Infrared Coronal Lines in Narrow-Line Seyfert 1 Galaxies

We report spectroscopic observations in the wavelength region 0.8-2.4 microns aimed at detecting near-infrared coronal lines in a sample of 5 narrow-line and 1 broad-line Seyfert 1 galaxies. Our measurements show that [SiVI] 1.963mu, [SIX] 1.252mu and [SVIII] 0.991mu are present in most of the objects and are useful tracers of nuclear activity. Line ratios between coronal and low ionization forbidden lines are larger in narrow-line Seyfert 1 galaxies. A positive correlation between FHWM and ionization potential of the forbidden lines is observed. Some coronal lines have widths similar to that of lines emitted in the broad line region (BLR), indicating that part of their flux originates in gas close to the outer portions of the BLR. Most coronal lines are blueshifted relative to the systemic velocity of the galaxy and this shift increases with the increase in line width. Assymetries towards the blue are observed in the profiles of high-ionization Fe lines, suggesting that the emitting gas is related to winds or outflows, most probably originating in material that is being evaporated from the torus. This scenario is supported by models that combine the effects of shock ionization and photoionization by a central continuum source in the gas clouds. The agreement between the coronal line emission predicted by the models and the observations is satisfactory; the models reproduced the whole range of coronal line intensities observed. We also report the detection of [FeXIII] 1.074,1.079mu in three of our objects and the first detection of [PII] 1.188mu and [NiII] 1.191mu in a Seyfert 1 galaxy, ARK 564. Using the ratio [PII]/[FeII] we deduced that most Fe present in the outer NLR of ARK 564 is locked up in grains, and the influence of shocks is negligible.

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