arXiv subjects

Alejandro W. Rodriguez

Publications and source records attributed to Alejandro W. Rodriguez.

At least 37 records · Page 2Linked to original sources

arXiv2023

Theoretical Investigation of Charge Transfer Between Two Defects in a Wide-Bandgap Semiconductor

Charge traps in the semiconductor bulk (bulk charge traps) make it difficult to predict the electric field within wide-bandgap semiconductors. The issue is the daunting number of bulk charge-trap candidates which means the treatment of bulk charge traps is generally qualitative or uses generalized models that do not consider the trap's particular electronic structure. The electric field within a wide-bandgap semiconductor is nonetheless a crucial quantity in determining the operation of semiconductor devices and the performance of solid-state single-photon emitters embedded within the semiconductor devices. In this work we accurately compute the average electric field measured at the location of N$V^-$ charged defects for the substitutional N (N$_\text{C}$) concentration of $n_{\text{N}_\text{C}} \approx 1.41\times10^{18}$ cm$^{-3}$ for the commonly used oxygen-terminated diamond (see [D. A. Broadway $et$ $al$., Nature Electronics 1, 502 (2018)]). We achieve this result by evaluating the leading-order contribution to the electric field far away from the surface, which comes from the N$_\text{C}$ defects that induce the ionization of the N$V^-$. Our results use density-functional theory (DFT) and the principle of band bending. Our work has the potential to aid both in the prediction of the functioning of semiconductor devices and in the prediction and correction of the spectral diffusion that often plagues the optical frequencies of solid-state single-photon emitters upon repeated photoexcitation measurements. Our results for the timescales involved in thermally driven charge transfer also have the potential to aid in investigations of charge dynamics.

cond-mat.mtrl-sci↗

arXiv2022

Controlling local thermal states in classical many-body systems

The process of thermalization in many-body systems is driven by complex interactions among sub-systems and with the surrounding environment. Here we lay the theoretical foundations for the active control of local thermal states in arbitrary non-reciprocal systems close to their equilibrium state. In particular we describe how to (i) force some part of the system to evolve according to a prescribed law during the relaxation process (i.e. thermal targeting probem), (ii) insulate some elements from the rest of the system or (iii) synchronize their evolution during the relaxation process. We also derive the general conditions a system must fulfill in order that some parts relax toward a minimal temperature with a minimum energetic cost or relax toward a prescribed temperature with a minimum time. Finally, we consider several representative examples in the context of systems exchanging heat radiatively.

cond-mat.mes-hall↗

arXiv2022

Trace Expressions and Associated Limits for Non-Equilibrium Casimir Torque

We exploit fluctuational electrodynamics to present trace expressions for the torque experienced by arbitrary objects in a passive, non-absorbing, rotationally invariant background environment. Specializing to a single object, this formalism, together with recently developed techniques for calculating bounds via Lagrange duality, is then used to derive limits on the maximum Casimir torque that a single object with an isotropic electric susceptibility can experience when out of equilibrium with its surrounding environment. The maximum torque achievable at any wavelength is shown to scale in proportion to body volumes in both subwavelength (quasistatics) and macroscopic (ray optics) settings, and come within an order of magnitude of achievable torques on topology optimized bodies. Finally, we discuss how to extend the formalism to multiple bodies, deriving expressions for the torque experienced by two subwavelength particles in proximity to one another.

physics.optics↗

arXiv2022

On Sion's Minimax Theorem, Compact QCQPs, and Wave Scattering Optimization

In these notes, we examine certain implications of Sion's minimax theorem for compact quadratically constrained quadratic programs (QCQPs), particularly QCQPs arising in the context of optimizing wave scattering, in relation to Lagrangian duality. The discussion puts forward an alternative "dual" understanding of optimization for wave phenomena that anticipates the realization of algorithmic (inverse design) methods attaining a guaranteed degree of global optimality for common figures of merit appearing in applied photonics, acoustics, and quantum mechanics.

math.OC↗

arXiv2021

Physical limits on electromagnetic response

Photonic devices play an increasingly important role in advancing physics and engineering, and while improvements in nanofabrication and computational methods have driven dramatic progress in expanding the range of achievable optical characteristics, they have also greatly increased design complexity. These developments have led to heightened relevance for the study of fundamental limits on optical response. Here, we review recent progress in our understanding of these limits with special focus on an emerging theoretical framework that combines computational optimization with conservation laws to yield physical limits capturing all relevant wave effects. Results pertaining to canonical electromagnetic problems such as thermal emission, scattering cross sections, Purcell enhancement, and power routing are presented. Finally, we identify areas for additional research, including conceptual extensions and efficient numerical schemes for handling large-scale problems.

physics.optics↗

arXiv2021

Nonequilibrium Casimir effects of nonreciprocal surface waves

We show that an isotropic dipolar particle in the vicinity of a substrate made of nonreciprocal plasmonic materials can experience a lateral Casimir force and torque when the particle's temperature differs from that of the slab and the environment. We connect the existence of the lateral force to the asymmetric dispersion of nonreciprocal surface polaritons and the existence of the lateral torque to the spin-momentum locking of such surface waves. Using the formalism of fluctuational electrodynamics, we show that the features of lateral force and torque should be experimentally observable using a substrate of doped Indium Antimonide (InSb) placed in an external magnetic field, and for a variety of dielectric particles. Interestingly, we also find that the directions of the lateral force and the torque depend on the constituent materials of the particles, which suggests a sorting mechanism based on lateral nonequilibrium Casimir physics.

quant-ph↗

arXiv2021

$\mathbb{T}$-Operator Limits on Optical Communication: Metaoptics, Computation, and Input-Output Transformations

We present an optimization framework based on Lagrange duality and the scattering $\mathbb{T}$ operator of electromagnetism to construct limits on the possible features that may be imparted to a collection of output fields from a collection of input fields, i.e., constraints on achievable optical transformations and the characteristics of structured materials as communication channels. Implications of these bounds on the performance of representative optical devices having multi-wavelength or multiport functionalities are examined in the context of electromagnetic shielding, focusing, near-field resolution, and linear computing.

physics.optics↗

arXiv2020

Inverse-designed photon extractors for optically addressable defect qubits

Solid-state defect qubit systems with spin-photon interfaces show great promise for quantum information and metrology applications. Photon collection efficiency, however, presents a major challenge for defect qubits in high refractive index host materials. Inverse-design optimization of photonic devices enables unprecedented flexibility in tailoring critical parameters of a spin-photon interface including spectral response, photon polarization and collection mode. Further, the design process can incorporate additional constraints, such as fabrication tolerance and material processing limitations. Here we design and demonstrate a compact hybrid gallium phosphide on diamond inverse-design planar dielectric structure coupled to single near-surface nitrogen-vacancy centers formed by implantation and annealing. We observe device operation near the theoretical limit and measure up to a 14-fold broadband enhancement in photon extraction efficiency. We expect that such inverse-designed devices will enable realization of scalable arrays of single-photon emitters, rapid characterization of new quantum emitters, sensing and efficient heralded entanglement schemes.

physics.app-ph↗

arXiv2020

Hierarchical Mean-Field $\mathbb{T}$ Operator Bounds on Electromagnetic Scattering: Upper Bounds on Near-Field Radiative Purcell Enhancement

We show how the central equality of scattering theory, the definition of the $\mathbb{T}$ operator, can be used to generate hierarchies of mean-field constraints that act as natural complements to the standard electromagnetic design problem of optimizing some objective with respect to structural degrees of freedom. Proof-of-concept application to the problem of maximizing radiative Purcell enhancement for a dipolar current source in the vicinity of a structured medium, an effect central to many sensing and quantum technologies, yields performance bounds that are frequently more than an order of magnitude tighter than all current frameworks, highlighting the irreality of these models in the presence of differing domain and field-localization length scales. Closely related to domain decomposition and multi-grid methods, similar constructions are possible in any branch of wave physics, paving the way for systematic evaluations of fundamental limits beyond electromagnetism.

physics.optics↗

arXiv2020

Global $\mathbb{T}$ operator bounds on electromagnetic scattering: Upper bounds on far-field cross sections

We present a method based on the scattering $\mathbb{T}$ operator, and conservation of net real and reactive power, to provide physical bounds on any electromagnetic design objective that can be framed as a net radiative emission, scattering or absorption process. Application of this approach to planewave scattering from an arbitrarily shaped, compact body of homogeneous electric susceptibility $χ$ is found to predictively quantify and differentiate the relative performance of dielectric and metallic materials across all optical length scales. When the size of a device is restricted to be much smaller than the wavelength (a subwavelength cavity, antenna, nanoparticle, etc.), the maximum cross section enhancement that may be achieved via material structuring is found to be much weaker than prior predictions: the response of strong metals ($\mathrm{Re}[χ] < 0$) exhibits a diluted (homogenized) effective medium scaling $\propto |χ| / \mathrm{Im}[χ]$; below a threshold size inversely proportional to the index of refraction (consistent with the half-wavelength resonance condition), the maximum cross section enhancement possible with dielectrics ($\mathrm{Re}[χ] > 0$) shows the same material dependence as Rayleigh scattering. In the limit of a bounding volume much larger than the wavelength in all dimensions, achievable scattering interactions asymptote to the geometric area, as predicted by ray optics. For representative metal and dielectric materials, geometries capable of scattering power from an incident plane wave within an order of magnitude (typically a factor of two) of the bound are discovered by inverse design. The basis of the method rests entirely on scattering theory, and can thus likely be applied to acoustics, quantum mechanics, and other wave physics.

physics.optics↗

arXiv2020

Near-field Radiative Heat Transfer in Many-Body Systems

Many-body physics aims to understand emergent properties of systems made of many interacting objects. This article reviews recent progress on the topic of radiative heat transfer in many-body systems consisting of thermal emitters interacting in the near-field regime. Near-field radiative heat transfer is a rapidly emerging field of research in which the cooperative behavior of emitters gives rise to peculiar effects which can be exploited to control heat flow at the nanoscale. Using an extension of the standard Polder and van Hove stochastic formalism to deal with thermally generated fields in $N$-body systems, along with their mutual interactions through multiple scattering, a generalized Landauer-like theory is derived to describe heat exchange mediated by thermal photons in arbitrary reciprocal and non-reciprocal multi-terminal systems. In this review, we use this formalism to address both transport and dynamics in these systems from a unified perspective. Our discussion covers: (i) the description of non-additivity of heat flux and its related effects, including fundamental limits as well as the role of nanostructuring and material choice, (ii) the study of equilibrium states and multistable states, (iii) the relaxation dynamics (thermalization) toward local and global equilibria, (iv) the analysis of heat transport regimes in ordered and disordered systems comprised of a large number of objects, density and range of interactions, and (v) the description of thermomagnetic effects in magneto-optical systems and heat transport mechanisms in non-Hermitian many-body systems. We conclude this review by listing outstanding challenges and promising future research directions.

cond-mat.mes-hall↗

arXiv2020

Channel-based algebraic limits to conductive heat transfer

Recent experimental advances probing coherent phonon and electron transport in nanoscale devices at contact have motivated theoretical channel-based analyses of conduction based on the nonequilibrium Green's function formalism. The transmission through each channel has been known to be bounded above by unity, yet actual transmissions in typical systems often fall far below these limits. Building upon recently derived radiative heat transfer limits and a unified formalism characterizing heat transport for arbitrary bosonic systems in the linear regime, we propose new bounds on conductive heat transfer. In particular, we demonstrate that our limits are typically far tighter than the Landauer limits per channel and are close to actual transmission eigenvalues by examining a model of phonon conduction in a 1-dimensional chain. Our limits have ramifications for designing molecular junctions to optimize conduction.

cond-mat.mes-hall↗

arXiv2020

Mechanical relations between conductive and radiative heat transfer

We present a general nonequilibrium Green's function formalism for modeling heat transfer in systems characterized by linear response that establishes the formal algebraic relationships between phonon and radiative conduction, and reveals how upper bounds for the former can also be applied to the latter. We also propose an extension of this formalism to treat systems susceptible to the interplay of conductive and radiative heat transfer, which becomes relevant in atomic systems and at nanometric and smaller separations where theoretical descriptions which treat each phenomenon separately may be insufficient. We illustrate the need for such coupled descriptions by providing predictions for a low-dimensional system of carbyne wires in which the total heat transfer can differ from the sum of its radiative and conductive contributions. Our framework has ramifications for understanding heat transfer between large bodies that may approach direct contact with each other or that may be coupled by atomic, molecular, or interfacial film junctions.

cond-mat.mes-hall↗

arXiv2020

Fluctuational Electrodynamics in Atomic and Macroscopic Systems: van der Waals Interactions and Radiative Heat Transfer

We present an approach to describing fluctuational electrodynamic (FED) interactions, particularly van der Waals (vdW) interactions as well as radiative heat transfer (RHT), between material bodies of vastly different length scales, allowing for going between atomistic and continuum treatments of the response of each of these bodies as desired. Any local continuum description of electromagnetic (EM) response is compatible with our approach, while atomistic descriptions in our approach are based on effective electronic and nuclear oscillator degrees of freedom, encapsulating dissipation, short-range electronic correlations, and collective nuclear vibrations (phonons). While our previous works using this approach have focused on presenting novel results, this work focuses on the derivations underlying these methods. First, we show how the distinction between "atomic" and "macroscopic" bodies is ultimately somewhat arbitrary, as formulas for vdW free energies and RHT look very similar regardless of how the distinction is drawn. Next, we demonstrate that the atomistic description of material response in our approach yields EM interaction matrix elements which are expressed in terms of analytical formulas for compact bodies or semianalytical formulas based on Ewald summation for periodic media; we use this to compute vdW interaction free energies as well as RHT powers among small biological molecules in the presence of a metallic plate as well as between parallel graphene sheets in vacuum, showing strong deviations from conventional macroscopic theories due to the confluence of geometry, phonons, and EM retardation effects. Finally, we propose formulas for efficient computation of FED interactions among material bodies in which those that are treated atomistically as well as those treated through continuum methods may have arbitrary shapes, extending previous surface-integral techniques.

cond-mat.mes-hall↗

arXiv2020

$\mathbb{T}$-operator bounds on angle-integrated absorption and thermal radiation for arbitrary objects

We derive fundamental per-channel bounds on angle-integrated absorption and thermal radiation for arbitrary bodies---for any given material susceptibility and bounding region---that simultaneously encode both the per-volume limit on polarization set by passivity and geometric constraints on radiative efficiencies set by finite object sizes through the scattering $\mathbb{T}$-operator. We then analyze these bounds in two practical settings, comparing against prior limits as well as near optimal structures discovered through topology optimization. Principally, we show that the bounds properly capture the physically observed transition from the volume scaling of absorptivity seen in deeply subwavelength objects (nanoparticle radius or thin film thickness) to the area scaling of absorptivity seen in ray optics (blackbody limits).

physics.optics↗

arXiv2019

Quantum nonlinear mixing of thermal photons to surpass the blackbody limit

Nearly all thermal radiation phenomena involving materials with linear response can be accurately described via semi-classical theories of light. Here, we go beyond these traditional paradigms to study a nonlinear system which, as we show, necessarily requires quantum theory of damping. Specifically, we analyze thermal radiation from a resonant system containing a $χ^{(2)}$ nonlinear medium and supporting resonances at frequencies $ω_1$ and $ω_2\approx 2ω_1$, where both resonators are driven only by intrinsic thermal fluctuations. Within our quantum formalism, we reveal new possibilities for shaping the thermal radiation. We show that the resonantly enhanced nonlinear interaction allows frequency-selective enhancement of thermal emission through upconversion, surpassing the well-known blackbody limits associated with linear media. Surprisingly, we also find that the emitted thermal light exhibits non-trivial statistics ($g^{(2)}(0) \neq 2$) and biphoton intensity correlations (at two distinct frequencies). We highlight that these features can be observed in the near future by heating a properly designed nonlinear system, without the need for any external signal. Our work motivates new interdisciplinary inquiries combining the fields of nonlinear photonics, quantum optics and thermal science.

physics.optics↗

arXiv2019

Fundamental limits to attractive and repulsive Casimir--Polder forces

We derive upper and lower bounds on the Casimir--Polder force between an anisotropic dipolar body and a macroscopic body separated by vacuum via algebraic properties of Maxwell's equations. These bounds require only a coarse characterization of the system---the material composition of the macroscopic object, the polarizability of the dipole, and any convenient partition between the two objects---to encompass all structuring possibilities. We find that the attractive Casimir--Polder force between a polarizable dipole and a uniform planar semi-infinite bulk medium always comes within 10% of the lower bound, implying that nanostructuring is of limited use for increasing attraction. In contrast, the possibility of repulsion is observed even for isotropic dipoles, and is routinely found to be several orders of magnitude larger than any known design, including recently predicted geometries involving conductors with sharp edges. Our results have ramifications for the design of surfaces to trap, suspend, or adsorb ultracold gases.

quant-ph↗

arXiv2019

Fundamental limits to radiative heat transfer: the limited role of nanostructuring in the near field

In a complementary article, we exploited algebraic properties of Maxwell's equations and fundamental principles such as electromagnetic reciprocity and passivity, to derive fundamental limits to radiative heat transfer applicable in near- through far-field regimes. The limits depend on the choice of material susceptibilities and bounding surfaces enclosing arbitrarily shaped objects. In this article, we apply these bounds to two different geometric configurations of interest, namely dipolar particles or extended structures of infinite area in the near field of one another, and compare these predictions to prior limits. We find that while near-field radiative heat transfer between dipolar particles can saturate purely geometric "Landauer" limits, bounds on extended structures cannot, instead growing much more slowly with respect to a material response figure of merit, an "inverse resistivity" for metals, due to the deleterious effects of multiple scattering; nanostructuring is unable to overcome these limits, which can be practically reached by planar media at the surface polariton condition.

physics.class-ph↗