SearcharxivSearch

arXiv subjects

Alessio Bruno

Publications and source records attributed to Alessio Bruno.

2 recordsLinked to original sources

Moxia: A Trust-First Neuro-Symbolic Execution Architecture for Self-Explaining Mathematical Reasoning

We present Moxia (formerly AXIOM), a trust-first neuro-symbolic architecture for self-explaining mathematical reasoning over natural-language input. Its language model is strictly a canonicalizer: it rewrites informal problem text into a narrow schema consumed by a deterministic Computer-Algebra-System (CAS) pipeline, which derives and verifies the answer or abstains as a first-class output. Routing follows a 1:1:1 alignment of problem-shape regex, schema-specific prompt, and closed-form CAS handler, with 4,783 routes shipped, 71% of which answer without invoking the language model, and zero LOST_CORRECT regressions as a standing release gate. Because the answer is derived rather than generated, so is its explanation: every handler emits a step trace of the computation it performed, rendered as prose by a layer covering all 4,785 task files that cannot narrate a step the handler did not take. Derivations export to Lean 4 as well: 479 task files (10%) emit a theorem from the problem's declared data, 445 accepted by the Lean kernel with Mathlib; that gate covers a fixture corpus, so live output is generated, not machine-checked. We report two numbers and never fuse them. On the full 7-category MATH test split, designed against, Moxia answers 90.2% (4,510/5,000) with one confident-wrong answer (99.98% trust on parseable). On held-out MATH-500, never designed against, it answers 89.2% (446/500) with zero confident-wrong answers. The 1.0 pp gap is the substantive result: a registry that had merely memorized problem shapes would collapse on held-out data, and this one does not. The rule-only path answers the 20,000-record lm-eval arithmetic benchmark at 100%, 1 ms per record. What we emphasize is not an accuracy figure but the forward dynamic: every logged abstain is a candidate correct after one ship cycle, since new tasks compose without regressing the registry.

cs.AI

The X-ray absorption spectrum of the propargyl radical, C$_3$H$_3^{\cdot}$

We report a combined experimental and computational study of the near-edge X-ray absorption fine structure (NEXAFS) spectrum of the propargyl radical, C$_3$H$_3^{\cdot}$. As a central intermediate in the formation of polycyclic aromatic hydrocarbons, the propargyl radical is a species of considerable relevance in combustion and astrochemistry and was here generated by pyrolysis from propargyl bromide. The NEXAFS spectrum shows a pronounced band at 282.2 eV corresponding to transitions from carbon 1s orbitals to singly occupied molecular orbitals. Ab initio calculations show that two transitions to the lowest lying states 1 $^2$A$_1$ and 2 $^2$A$_1$, which take place from the C1s orbital of the two terminal carbon atoms, contribute to this band. In addition, a 420 meV spacing of the first band is visible and is assigned to a vibrational progression in the symmetric CH$_2$ stretch. Transitions at higher energies are also described reasonably well by theory. The fragmentation pattern was investigated at the different resonant transitions and shows the cleavage of one as well as both C--C bonds.

physics.chem-ph