arXiv subjects

Alex Kleiner

Publications and source records attributed to Alex Kleiner.

5 recordsLinked to original sources

arXiv2023

Nanopore and tunneling resonance in an open kink in carbon nanotubes

In weakly buckled carbon nanotubes, the kink is an open, ovalized constriction where molecular-sized analytes and ions can pass. Moreover, in semiconducting tubes, the kink has an electronic bound state within the bandgap. This state is localized, hence highly susceptible to electrostatic perturbation by a proximate, itinerant ion. The degree to which this perturbation will modulate the electronic current, which is our signal, can be maximized in a tunnel-junction set-up, near resonance. We thus propose such a device, analyze its performance and, since the bound state depends on the post-buckling bending, suggest a scalable fabrication method to achieve bending and buckling of carbon nanotubes to an adjustable degree.

cond-mat.mes-hall↗

arXiv2023

Bandgaps of bent and buckled carbon nanotubes

Carbon nanotube's large electro-mechanical coupling and robustness makes them attractive for applications where bending and buckling is present. But the nature of this coupling is not well understood. Existing theory treats only weak and homogeneous deformations. We generalize it and derive close-form expressions for bandgaps under non-homogeneous deformation. The theory is first compared with a number of published DFT simulations, and then applied to the specific case of bending and buckling -- where a kink is present. In the pre-buckling regime, bandgaps change $\propto\pm \kappa^4$ where $\kappa$ is the bending curvature; inside the kink at post-buckling, while near criticality, the kink is shallow and the gap is $\propto \pm\kappa^{1/2}$, where the sign depends on the chiral integers. For a deeper kink but still with an open cross-section, both the bandgap and local Fermi energy strongly downshift.

cond-mat.mes-hall↗

arXiv2002

Spin stripes in nanotubes

It is shown here that electrons on the surface of a nanotube in a perpendicular magnetic field undergo spin-chirality separation along the circumference. Stripes of spin-polarization propagate along the tube, with a spatial pattern that can be modulated by the electron filling.

cond-mat.mes-hall↗

arXiv2001

Curvature, hybridization, and STM images of carbon nanotubes

The curvature effects in carbon nanotubes are studied analytically as a function of chirality. The pi-orbitals are found to be significantly rehybridized in all tubes, so that they are never normal to the tubes' surface. This results in a curvature induced gap in the electronic band-structure, which turns out to be larger than previous estimates. The tilting of the pi-orbitals should be observable by atomic resolution scanning tunneling microscopy measurements.

cond-mat.str-el↗

arXiv2001

Band gaps of primary metallic carbon nanotubes

Primary metallic, or small gap semiconducting nanotubes, are tubes with band gaps that arise solely from breaking the bond symmetry due to the curvature. We derive an analytic expression for these gaps by considering how a general symmetry breaking opens a gap in nanotubes with a well defined chiral wrapping vector. This approach provides a straightforward way to include all types of symmetry breaking effects, resulting in a simple unified gap equation as a function of chirality and deformations.

cond-mat.mes-hall↗