SearcharxivSearch

arXiv subjects

Alex Lips

Publications and source records attributed to Alex Lips.

4 recordsLinked to original sources

Anomalous Scaling for Hydrodynamic Lubrication of Conformal Surfaces

The hydrodynamic regime of the Stribeck curve giving the friction coefficient $\mu$ as a function of the dimensionless relative sliding speed (the Sommerfeld number, $S$) of two contacting non-conformal surfaces is usually considered trivial, with $\mu \sim S$. We predict that for conformal surfaces contacting over large areas, a combination of independent length scales gives rise to a universal power-law with a non-trivial exponent, $\mu\sim S^{2/3}$, for a thick lubrication film. Deviations as the film thins (decreasing $S$) may superficially resemble the onset of elastohydrodynamic lubrication, but are due to a crossover between hydrodynamic regimes. Our experiments as well as recent measurements of chocolate lubrication confirm these predictions.

cond-mat.soft

Rheological design of thickened alcohol-based hand rubs

The handleability and sensory perception of hand sanitisers by consumers affect the hygiene outcome. Spillage may result in under-dosing and poor sensory properties can lead to under-utilisation. We first propose four principles (low run off, spreadability, smoothness and non-stickiness) for designing the rheology of thickened alcohol-based hand rubs with acceptable handleability and hand feel. We then evaluate a commercial hand gel and a variety of simplified formulations thickened with microgels (Carbopol 974P, Carbopol Ultrez 20 and Sepimax Zen), or linear polymers (Jaguar HP 120 COS), and evaluate them against these design criteria. All four additives provide acceptable spreadability by shear thinning to $\eta \approx 10^{-1} Pa \, s$ at $\dot\gamma \sim 10^3 s^{-1}$. Either the finite yield stress conferred by the microgels ($\sigma_y \gtrsim 10 Pa$) or the increase in low-shear viscosity provided by the linear polymer ($\eta \gtrsim 1 Pa \, s$ at $\dot\gamma \lesssim 0.1 s^{-1}$) give rise to acceptably low run-off. However, the formulation using the linear polymer shows a filament breakage time of $\tau_{\rm b} \approx 1 s$ in capillary rheology, which may result in stickiness and therefore a less than optimal hand feel.

cond-mat.soft

Soft matter science and the COVID-19 pandemic

Much of the science underpinning the global response to the COVID-19 pandemic lies in the soft matter domain. Coronaviruses are composite particles with a core of nucleic acids complexed to proteins surrounded by a protein-studded lipid bilayer shell. A dominant route for transmission is via air-borne aerosols and droplets. Viral interaction with polymeric body fluids, particularly mucus, and cell membranes control their infectivity, while their interaction with skin and artificial surfaces underpins cleaning and disinfection and the efficacy of masks and other personal protective equipment. The global response to COVID-19 has highlighted gaps in the soft matter knowledge base. We survey these gaps, especially as pertaining to the transmission of the disease, and suggest questions that can (and need to) be tackled, both in response to COVID-19 and to better prepare for future viral pandemics.

cond-mat.soft

Ultra-long range correlations of the dynamics of jammed soft matter

We use Photon Correlation Imaging, a recently introduced space-resolved dynamic light scattering method, to investigate the spatial correlation of the dynamics of a variety of jammed and glassy soft materials. Strikingly, we find that in deeply jammed soft materials spatial correlations of the dynamics are quite generally ultra-long ranged, extending up to the system size, orders of magnitude larger than any relevant structural length scale, such as the particle size, or the mesh size for colloidal gel systems. This has to be contrasted with the case of molecular, colloidal and granular ``supercooled'' fluids, where spatial correlations of the dynamics extend over a few particles at most. Our findings suggest that ultra long range spatial correlations in the dynamics of a system are directly related to the origin of elasticity. While solid-like systems with entropic elasticity exhibit very moderate correlations, systems with enthalpic elasticity exhibit ultra-long range correlations due to the effective transmission of strains throughout the contact network.

cond-mat.soft