arXiv subjects

Alexander Boeschoten

Publications and source records attributed to Alexander Boeschoten.

8 recordsLinked to original sources

arXiv2026

Multiparameter estimation for the superresolution of two incoherent sources

We experimentally demonstrate the simultaneous estimation of the three parameters characterizing a pair of incoherent optical sources in the sub-Rayleigh regime, enabling super-resolved scene characterization. Using spatial-mode demultiplexing (SPADE) with two demultiplexers--one deliberately shifted--we determine separations well below the diffraction limit and achieve sensitive joint estimation of separation, centroid, and relative brightness over a broad range of scene configurations in a single experimental setting. We benchmark our performance using Fisher-information-based Cramér-Rao bounds, and discuss the corresponding quantum limits. We investigate two complementary scenarios: a realistic case with slightly non-identical sources, and an idealized case of indistinguishable sources.

quant-ph↗

arXiv2026

Experimental Evidence-Based Sub-Rayleigh Source Discrimination

We propose a Bayesian evidence-based inference framework based on relative belief ratios and apply it to discriminating between one and two incoherent optical point sources using spatial-mode demultiplexing (SPADE). Unlike the Helstrom measurement, SPADE require no collective detection and its optimal for asymptotically large samples. Our method avoids ad hoc statistical constructs and relies solely on the information contained in the data, with all assumptions entering only through the likelihood model and prior beliefs. Using experimental evidence, we demonstrate the superior resolving performance of SPADE over direct imaging from a new and extensible perspective; one that naturally generalizes to multiple sources and offers a practical robust approach to analyzing quantum-enhanced superresolution.

quant-ph↗

arXiv2025

Estimation of multiple parameters encoded in the modal structure of light

We investigate the problem of estimating simultaneously multiple parameters encoded in the shape of the modes on which the light is expanded. For this, we generalize the mode-encoded parameter estimation theory as introduced in Ref.[1] to a multi-parameter scenario. We derive the general expression for the Quantum Fisher information matrix and establish the conditions under which the multi-parameter Quantum Cramér-Rao bound is attainable. In specific scenarios, we find that each parameter can be associated with a mode -- the detection mode -- that is proportional to the derivative of either a single non-vacuum mode or the mean-field mode. For a single non-vacuum mode, the correlation between parameters is determined by the real part of the overlap of these detection modes, while in the case of a strong mean-field by the covariance of the quadrature operators of the derivative modes. In both cases, the attainability of the Quantum Cramér-Rao bound is determined by the imaginary part of the overlap of the detection modes. Our findings provide clear criteria for optimal joint estimation of parameters encoded in the modal structure of light, and can be used to benchmark experimental multi-parameter estimations and find optimal measurement strategies by carefully shaping the modes and populating them with non-classical light.

quant-ph↗

arXiv2024

Manipulating a beam of barium fluoride molecules using an electrostatic hexapole

An electrostatic hexapole lens is used to manipulate the transverse properties of a beam of barium fluoride molecules from a cryogenic buffer gas source. The spatial distribution of the beam is measured by recording state-selective laser-induced fluorescence on an emccd camera, providing insight into the intensity and transverse position spread of the molecular beam. Although the high mass and unfavorable Stark shift of barium fluoride pose a considerable challenge, the number of molecules in the low-field seeking component of the N=1 state that pass a 4 mm diameter aperture 712 mm behind the source is increased by a factor of 12. Furthermore, it is demonstrated that the molecular beam can be displaced by up to +/-5 mm by moving the hexapole lens. Our measurements agree well with numerical trajectory simulations. We discuss how electrostatic lenses may be used to increase the sensitivity of beam experiments such as the search for the electric dipole moment of the electron.

physics.atom-ph↗

arXiv2024

A novel method to determine the phase-space distribution of a pulsed molecular beam

We demonstrate a novel method to determine the longitudinal phase-space distribution of a cryogenic buffer gas beam of barium-fluoride molecules based on a two-step laser excitation scheme. The spatial resolution is achieved by a transversely aligned laser beam that drives molecules from the ground state $X^2Σ^+$ to the $A^2Π_{1/2}$ state around 860 nm, while the velocity resolution is obtained by a laser beam that is aligned counter-propagating with respect to the molecular beam and that drives the Doppler shifted $A^2Π_{1/2}$ to $D^2Σ^+$ transition around 797 nm. Molecules in the $D$-state are detected virtually background-free by recording the fluorescence from the $D-X$ transition at 413 nm. As molecules in the ground state do not absorb light at 797 nm, problems due to due to optical pumping are avoided. Furthermore, as the first step uses a narrow transition, this method can also be applied to molecules with hyperfine structure. The measured phase-space distributions, reconstructed at the source exit, show that the average velocity and velocity spread vary significantly over the duration of the molecular beam pulse. Our method gives valuable insight into the dynamics in the source and helps to reduce the velocity and increase the intensity of cryogenic buffer gas beams. In addition, transition frequencies are reported for the $X-A$ and $X-D$ transitions in barium fluoride with an absolute accuracy below 0.3 MHz.

physics.atom-ph↗

arXiv2022

Benchmarking of the Fock space coupled cluster method and uncertainty estimation: Magnetic hyperfine interaction in the excited state of BaF

We present an investigation of the performance of the relativistic multi-reference Fock-space coupled cluster (FSCC) method for predicting molecular hyperfine structure (HFS) constants, including a thorough computational study to estimate the associated uncertainties. In particular, we considered the $^{19}$F HFS constant in the ground and excited states of BaF. Due to a larger basis set dependence, the uncertainties on the excited state results (16-85%) were found to be significantly larger than those on the ground state constants ($\sim$2%). The ab initio values were compared to the recent experimental results, and good overall agreement within the theoretical uncertainties was found. This work demonstrates the predictive power of the FSCC method and the reliability of the established uncertainty estimates, which can be crucial in cases where the calculated property cannot be directly compared to experiment.

physics.atom-ph↗

arXiv2021

Systematic study and uncertainty evaluation of $P,T$-odd molecular enhancement factors in BaF

A measurement of the magnitude of the electric dipole moment of the electron (eEDM) larger than that predicted by the Standard Model (SM) of particle physics is expected to have a huge impact on the search for physics beyond the SM. Polar diatomic molecules containing heavy elements experience enhanced sensitivity to parity ($P$) and time-reversal ($T$)-violating phenomena, such as the eEDM and the scalar-pseudoscalar (S-PS) interaction between the nucleons and the electrons, and are thus promising candidates for measurements. The NL-\textit{e}EDM collaboration is preparing an experiment to measure the eEDM and S-PS interaction in a slow beam of cold BaF molecules [Eur. Phys. J. D, 72, 197 (2018)]. Accurate knowledge of the electronic structure parameters, $W_d$ and $W_s$, connecting the eEDM and the S-PS interaction to the measurable energy shifts is crucial for the interpretation of these measurements. In this work we use the finite field relativistic coupled cluster approach to calculate the $W_d$ and $W_s$ parameters in the ground state of the BaF molecule. Special attention was paid to providing a reliable theoretical uncertainty estimate based on investigations of the basis set, electron correlation, relativistic effects and geometry. Our recommended values of the two parameters, including conservative uncertainty estimates, are 3.13 $\pm$ $0.12 \times 10^{24}\frac{\text{Hz}}{e\cdot \text{cm}}$ for $W_d$ and 8.29 $\pm$ 0.12 kHz for $W_s$.

physics.atom-ph↗

arXiv2019

High accuracy theoretical investigations of CaF, SrF, and BaF and implications for laser-cooling

The NL-eEDM collaboration is building an experimental setup to search for the permanent electric dipole moment of the electron in a slow beam of cold barium fluoride molecules [Eur. Phys. J. D, 72, 197 (2018)]. Knowledge of molecular properties of BaF is thus needed to plan the measurements and in particular to determine an optimal laser-cooling scheme. Accurate and reliable theoretical predictions of these properties require incorporation of both high-order correlation and relativistic effects in the calculations. In this work theoretical investigations of the ground and the lowest excited states of BaF and its lighter homologues, CaF and SrF, are carried out in the framework of the relativistic Fock-space coupled cluster (FSCC) and multireference configuration interaction (MRCI) methods. Using the calculated molecular properties, we determine the Franck-Condon factors (FCFs) for the $A^2Π_{1/2} \rightarrow X^2Σ^{+}_{1/2}$ transition, which was successfully used for cooling CaF and SrF and is now considered for BaF. For all three species, the FCFs are found to be highly diagonal. Calculations are also performed for the $B^2Σ^{+}_{1/2} \rightarrow X^2Σ^{+}_{1/2}$ transition recently exploited for laser-cooling of CaF; it is shown that this transition is not suitable for laser-cooling of BaF, due to the non-diagonal nature of the FCFs in this system. Special attention is given to the properties of the $A'^2Δ$ state, which in the case of BaF causes a leak channel, in contrast to CaF and SrF species where this state is energetically above the excited states used in laser-cooling. We also present the dipole moments of the ground and the excited states of the three molecules and the transition dipole moments (TDMs) between the different states.

physics.atom-ph↗