Alexander J. Knowles | Searcharxiv

arXiv2026

Precipitation induced recrystallisation (PIX) in a Ti-Fe-Mo bcc-superalloy driven by lattice misfit

Beta-Ti bcc-superalloys, comprising an A2 beta-Ti matrix reinforced by ordered intermetallic B2 beta-prime-TiFe precipitates, exhibit an unusual recrystallisation that occurs with no externally applied strain (i.e. no thermomechanical processing). Thermal ageing at 750 degrees Celsius for 72 h results in refinement of the grain size from 364 um to 30 um. This grain refinement is driven by discontinuous precipitation of beta-prime-TiFe lamellae with the beta-Ti matrix from grain/phase boundaries, which is associated with significant misorientation and increased dislocation density, attributed as precipitation induced recrystallisation (PIX).

cond-mat.mtrl-sci↗

arXiv2019

The Kinetics of Primary Alpha Plate Growth in Titanium Alloys

The kinetics of primary alpha-Ti colony/Widmanstatten plate growth from the beta are examined, comparing model to experiment. The plate growth velocity depends sensitively both on the diffusivity D(T) of the rate-limiting species and on the supersaturation around the growing plate. These result in a maxima in growth velocity around 40 K below the transus, once sufficient supersaturation is available to drive plate growth. In Ti-6246, the plate growth velocity was found to be around 0.32 um min-1 at 850 oC, which was in good agreement with the model prediction of 0.36 um min-1 . The solute field around the growing plates, and the plate thickness, was found to be quite variable, due to the intergrowth of plates and soft impingement. This solute field was found to extend to up to 30 nm, and the interface concentration in the beta was found to be around 6.4 at.% Mo. It was found that increasing O content will have minimal effect on the plate lengths expected during continuous cooling; in contrast, Mo approximately doubles the plate lengths obtained for every 2 wt.% Mo reduction. Alloys using V as the beta stabiliser instead of Mo are expected to have much faster plate growth kinetics at nominally equivalent V contents. These findings will provide a useful tool for the integrated design of alloys and process routes to achieve tailored microstructures.

cond-mat.mtrl-sci↗