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Alexander Schmid

Publications and source records attributed to Alexander Schmid.

6 recordsLinked to original sources

Uncovering Hidden Systematics in Neural Network Models for High Energy Physics

Neural networks (NNs) are inherently multidimensional classifiers that learn complex, non-linear relationships among input observables. While their flexibility enables unprecedented performance in high-energy physics (HEP) analyses, it also makes them sensitive to small variations in their inputs. Consequently, the propagation and estimation of systematic uncertainties in NN-based models remain an open challenge. There are indications that uncertainties derived in control regions or from nominal variations of input features can underestimate the true model uncertainty, potentially leaving biases unaccounted for. Inspired by insights from adversarial-attack studies in machine learning, we explore how subtle perturbations, fully consistent with the experimental uncertainties on the input observables, can lead to substantial changes in NN outputs, while keeping the one-dimensional and correlated input distributions nearly unchanged. Using a set of representative HEP tasks, including event classification and object identification, and testing across a variety of network architectures, we demonstrate that networks can be systematically "fooled" at significant rates within the allowed uncertainty envelopes. Building on this observation, we introduce a quantitative framework to probe and measure the hidden sensitivity of neural networks to realistic experimental variations, providing a practical path to evaluate and control their systematic uncertainty in physics analyses.

cs.LG

Bias-triggered conductivity relaxation (BCR): a unique tool to simultaneously investigate thermodynamics, kinetics and electrostatic effects of oxygen reactions in MIEC thin films

Mixed ionic electronic transfer (MIET) reactions, such as the oxygen reduction reaction (ORR) at oxide surfaces, are of paramount importance to manifold technologically highly relevant processes and fundamental understanding must be developed to improve performance and tailor highly efficient electrodes and catalysts. Understanding such complex multi-step reactions, requires the study of kinetic processes, underlying thermodynamic properties, i.e. ionic and electronic defect concentrations and electrostatic surface effects. However conventional techniques struggle to uncover the complete picture within the same sample/measurement. Here, we overcome this limitation by introducing bias-triggered conductivity relaxation (BCR) as a novel tool to investigate MIET reactions on oxides. It is based on alternating out-of-plane coulometric titration/polarization and in-plane electrical conductivity relaxation measurements, providing simultaneous electronic, ionic and extraordinarily rich surface kinetics information. This innovative combination of electrical and chemical driving forces synergizes information depth, with enhanced time resolution, versatility and speed, yet it lifts the weaknesses of the individual approaches, while remaining cost-effective and surprisingly simple. Furthermore, BCR allows to disentangle overpotential induced electrostatic modifications of the surface kinetics in a unique manner. We showcase the advantages of BCR in this work by studying the ORR in model (La,Sr)FeO$_{3-{\delta}}$ thin film electrodes and reporting on their thermodynamic and kinetic properties.

cond-mat.mtrl-sci

Investigating oxides by electrochemical projection of the oxygen off-stoichiometry diagram onto a single sample

The oxygen stoichiometry is an essential key to tune functional properties of advanced oxide materials and thus has motivated numerous studies of the oxygen off-stoichiometry diagram, with the aim to determine and control structural, electronic, ionic, electrochemical and optical properties, as well as thermodynamic quantities such as the oxygen storage capacity, among others. Here, a novel approach is developed, which allows to project a broad range of oxygen chemical potentials onto a single thin film sample with unprecedented control via electrochemical polarization. Therefore, a specifically designed electrochemical cell geometry is deployed, resulting in a well-defined, linear, 1D in-plane oxygen concentration gradient, independent of variations in the materials electrical resistivity, whose endpoints can be flexibly controlled via the external pO2 and applied overpotential. This allows for an unparalleled study of materials properties as a continuous function of the oxygen content using spatially resolved tools (spectroscopic, diffraction, microscopy, local electrical probes, etc.) and thereby greatly reduces experimental efforts while also avoiding sample-to-sample variability, multi-step treatments, sample evolution effects, etc. This work presents the proof-of-concept of in-plane oxygen gradients, based on spatially resolved ex/in situ and novel fixed-energy X-ray absorption near edge spectroscopy (XANES), X-ray diffraction, ellipsometry and electrical resistivity measurements in hyper-stoichiometric La2NiO4+{\delta} and sub-stoichiometric (La,Sr)FeO3-{\delta} thin films. It thereby demonstrates the readiness and wide applicability of this innovative approach, which can be highly relevant for fundamental as well as applied research.

cond-mat.mtrl-sci

Exploring the potential of combining over- and under-stoichiometric MIEC materials for Oxygen-Ion Batteries

The increasing demand for energy storage solutions has spurred intensive research into next-generation battery technologies. Oxygen-ion batteries (OIBs), which leverage mixed ionic-electronic conducting (MIEC) oxides, have emerged as promising candidates due to their solid, non-flammable nature and potential for high power densities. This study investigates the use of over-stoichiometric La2NiO4+delta (L2NO4) as a cathode material for OIBs, exploring its capacity for electrochemical energy storage. Half-cell measurements reveal that L2NO4 with a closed-pore microstructure can store oxygen, achieving a volumetric charge of 63 mA.h.cm-3 at 400 {\deg}C with a current density of 3.6 uA.cm-2 and potentials up to 0.75 V vs. 1 bar O2. Additionally, a functional full cell combining over-stoichiometric L2NO4 and under-stoichiometric La0.5Sr0.5Cr0.2Mn0.8O3-delta (LSCrMn) has been successfully developed, demonstrating excellent cyclability and coulomb efficiency. The full cell reaches a maximum volumetric charge of 90 mA.h.cm-3 at 400 {\deg}C, 17.8 uA.cm-2, and a cut-off voltage of 1.8 V. This proof of concept underscores the viability of combining over- and under-stoichiometric MIEC materials in OIBs and provides critical insights into optimizing electrode materials and tuning oxygen content for improved performance. This research lays the groundwork for future advancements in OIB technology, aiming to develop materials with lower resistance and higher efficiency.

cond-mat.mtrl-sci

Combining Electron Spin Resonance Spectroscopy with Scanning Tunneling Microscopy at High Magnetic Fields

Magnetic media remain a key in information storage and processing. The continuous increase of storage densities and the desire for quantum memories and computers pushes the limits of magnetic characterisation techniques. Ultimately, a tool which is capable of coherently manipulating and detecting individual quantum spins is needed. The scanning tunnelling microscope (STM) is the only technique which unites the prerequisites of high spatial and energy resolution, low temperature and high magnetic fields to achieve this goal. Limitations in the available frequency range for electron spin resonance STM (ESR-STM) mean that many instruments operate in the thermal noise regime. We resolve challenges in signal delivery to extend the operational frequency range of ESR-STM by more than a factor of two and up to 100GHz, making the Zeeman energy the dominant energy scale at achievable cryogenic temperatures of a few hundred millikelvin. We present a general method for augmenting existing instruments into ESR-STMs to investigate spin dynamics in the high-field limit. We demonstrate the performance of the instrument by analysing inelastic tunnelling in a junction driven by a microwave signal and provide proof of principle measurements for ESR-STM.

cond-mat.mes-hall

Silicon-plasmonic integrated circuits for terahertz signal generation and coherent detection

Optoelectronic signal processing offers great potential for generation and detection of ultra-broadband waveforms in the THz range, so-called T-waves. However, fabrication of the underlying high-speed photodiodes and photoconductors still relies on complex processes using dedicated III-V semiconductor substrates. This severely limits the application potential of current T-wave transmitters and receivers, in particular when it comes to highly integrated systems that combine photonic signal processing with optoelectronic conversion to THz frequencies. In this paper, we demonstrate that these limitations can be overcome by plasmonic internal photoemission detectors (PIPED). PIPED can be realized on the silicon photonic platform and hence allow to leverage the enormous opportunities of the associated device portfolio. In our experiments, we demonstrate both T-wave signal generation and coherent detection at frequencies of up to 1 THz. To proof the viability of our concept, we monolithically integrate a PIPED transmitter and a PIPED receiver on a common silicon photonic chip and use them for measuring the complex transfer impedance of an integrated T-wave device.

physics.optics