arXiv subjects

Alexandr Marunchenko

Publications and source records attributed to Alexandr Marunchenko.

5 recordsLinked to original sources

arXiv2026

Pulse-Burst Excitation Reveals Time-Dose Reciprocity Breakdown in Mixed-Halide Perovskites

Time-dose reciprocity, commonly associated with the Bunsen-Roscoe law, states that the response of a photosensitive system depends only on the total exposure dose, regardless of how that energy is delivered over time. Light-sensitive processes in mixed-halide perovskites, such as photoinduced halide segregation, often exhibit threshold-like behavior that may violate this principle and enable material-state control by photon timing. We test this using pulse-burst excitation, which introduces an additional temporal control dimension beyond conventional parameters such as pulse fluence, repetition rate, and average power. By redistributing the same photon dose over microsecond-to-millisecond timescales, we create distinct nonequilibrium excitation conditions and show that mixed-halide perovskites can evolve into different metastable states, revealing a breakdown of time-dose reciprocity in the combined processes of halide segregation and remixing. This additional temporal degree of freedom not only enables control of the material state but also provides a new experimental framework for disentangling the competing processes underlying photoinduced halide redistribution. Our findings establish photon timing as a control parameter for perovskite photochemistry and open additional opportunities for optical memory and neuromorphic photonic applications.

cond-mat.mtrl-sci↗

arXiv2026

Unraveling the Roles of Shallow, Deep and Auger Trapping in Charge Carrier Recombination in Triple-Cation Perovskites

Understanding charge-carrier recombination in metal halide perovskites is essential for accurately identifying the factors limiting solar cell efficiency, yet it remains challenging due to the interplay of multiple competing processes. Here, we combine time-resolved photoluminescence and excitation dependent photoluminescence quantum yield measurements over a wide range of fluences and repetition rates to investigate recombination dynamics in triple-cation perovskite thin films. By jointly analyzing these multidimensional datasets, we develop a unified model that quantitatively reproduces both photoluminescence decays and absolute quantum yields across all excitation conditions. Our results reveal the coexistence of deep and shallow traps, as well as a second-order nonradiative recombination pathway attributed to Auger-assisted trapping. Importantly, this mechanism dominates under one-sun illumination, making it a critical limiting factor for photovoltaic performance. These findings provide a comprehensive framework for understanding recombination in perovskites and highlight the importance of higher-order defect-mediated processes in determining their efficiency.

cond-mat.mtrl-sci↗

arXiv2024

Hidden photoexcitations probed by multi-pulse photoluminescence

Time-resolved photoluminescence is a validated method for tracking the photoexcited carrier dynamics in luminescent materials. This technique probes the photoluminescence decays upon a periodic excitation by short laser pulses. Herein, we demonstrate that this approach cannot directly detect hidden photoexcitations with much slower dynamics than the photoluminescence decay. We demonstrate a new method based on a multi-pulse excitation scheme that enables an unambiguous detection and an easily interpreted tracking of these hidden species. The multi-pulse excitation consists of a single pulse (Read) followed by a burst of many closely separated pulses (Write) and finally another single pulse (Read). To illustrate the efficacy of the Read-Write-Read excitation scheme, we apply it to metal halide perovskites to directly visualize carrier trapping, extract the concentration of trapped charges and determine the rate constant of trap depopulation. The developed approach allows studying performance-limiting processes in energy devices using a versatile, highly applicable all-optical method.

physics.optics↗

arXiv2023

Memlumor: a luminescent memory device for photonic neuromorphic computing

Neuromorphic computing promises to transform the current paradigm of traditional computing towards Non-Von Neumann dynamic energy-efficient problem solving. Thus, dynamic memory devices capable of simultaneously performing nonlinear operations (volatile) similar to neurons and also storing information (non-volatile) alike brain synapses are in the great demand. To satisfy these demands, a neuromorphic platform has to possess intrinsic complexity reflected in the built-in diversity of its physical operation mechanisms. Herein, we propose and demonstrate the novel concept of a memlumor - an all-optical device combining memory and luminophore, and being mathematically a full equivalence of the electrically-driven memristor. By utilizing metal halide perovskites as a memlumor material platform, we demonstrate the synergetic coexistence of both volatile and non-volatile memory effects within a broad timescale from ns to days. We elucidate the origin of such complex response to be related to the phenomena of photodoping and photochemistry activated by a tunable light input and explore several possible realizations of memlumor computing. Leveraging on the existence of a history-dependent photoluminescent quantum yield in various material platforms, the memlumor device concept will trigger multiple new research directions in both material science and optoelectronics. We anticipate that the memlumor, as a new optical dynamic computing element, will add a new dimension to existing optical technologies enabling their transition into application in photonic neuromorphic computing.

physics.optics↗

arXiv2023

Biorealistic Response in Optoelectrically-Driven Flexible Halide-Perovskite Single-Crystal Memristors

The transition to smart wearable and flexible optoelectronic devices communicating with each other and performing neuromorphic computing at the edge is a big goal in next-generation optoelectronics. These devices should perform their regular tasks supported by energy-efficient in-memory calculations. Here, we study the response of the CsPbBr$_3$ halide-perovskite single crystal fabricated on the flexible polymer substrate and integrated with the single-walled carbon nanotube thin film electrodes in a lateral geometry. We show both photodetection functions combined with the synaptic functionality in our device under the application of hybrid optoelectrical stimuli. Furthermore, we demonstrate that our device exhibits frequency-dependent bidirectional modification of synaptic weight with a sliding threshold similar to biologically plausible Bienenstock-Cooper-Munro learning. The demonstrated optoelectronic synaptic behavior in halide-perovskite single-crystals opens the opportunity for the development of hybrid organic-inorganic artificial visual systems.

cond-mat.mtrl-sci↗