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Alfred Müller

Publications and source records attributed to Alfred Müller.

14 recordsLinked to original sources

Almost stochastic dominance via optimal transport

We study parametric classes of almost stochastic dominance on general Polish spaces as order relations for probability distributions with a parameter $\gamma \in [0,1]$. Larger values of $\gamma$ correspond to weaker order relations: $\gamma=0$ gives classical stochastic dominance $\le_{st}$, whereas $\gamma=1$ gives a complete preorder based on comparison of expectations of a fixed increasing function $g$. It is well known that $X \le_{st} Y$ can be characterized by the existence of a solution to an optimal transport problem with $\mathrm{OT}_c(X,Y)=0$ for a suitable cost function $c$. We generalize this idea so that the best possible parameter $\gamma$ for almost stochastic dominance can be determined from the solution of an optimal transport problem. Using a generalization of the classical Kantorovich--Rubinstein duality theorem to quasi-pseudo-metrics, we derive a dual characterization of the order in terms of expectation comparisons for a parametric class of test functions. Consequently, our relations are always transitive, in contrast to some other recent approaches to almost stochastic dominance based on optimal transport. A natural multivariate approach to almost stochastic dominance, based on classes of test functions with bounds on partial derivatives, was recently introduced by M\"uller et al. (2025). We show that this approach is a special case of our framework and derive the best possible parameters $\gamma$ for examples considered there, as well as for other examples from the literature. We also prove a robustness result showing that, under small perturbations of the distributions in a Wasserstein-type metric related to the optimal transport problem, the best possible $\gamma$ increases only slightly.

math.PR

Commissioning of a fast fine-step electron-energy-scan system for electron-ion crossed-beams experiments

We report on the commissioning of a fast electron-energy scan system for measurements of electron-impact ionization cross sections. The Giessen crossed-beams experiment employs a high-power electron gun which has been developed over recent years and which permits wide variations of the beam parameters. A multi-electrode design enables the decoupling of the electron energy from the electron density. The newly implemented control system, which governs the various electrode potentials, is described together with the salient technical features.

physics.atom-ph

Some remarks on the effect of risk sharing and diversification for infinite mean risks

The basic principle of any version of insurance is the paradigm that exchanging risk by sharing it in a pool is beneficial for the participants. In case of independent risks with a finite mean this is the case for risk averse decision makers. The situation may be very different in case of infinite mean models. In that case it is known that risk sharing may have a negative effect, which is sometimes called the nondiversification trap. This phenomenon is well known for infinite mean stable distributions. In a series of recent papers similar results for infinite mean Pareto and Fr\'echet distributions have been obtained. We further investigate this property by showing that many of these results can be obtained as special cases of a simple result demonstrating that this holds for any distribution that is more skewed than a Cauchy distribution. We also relate this to the situation of deadly catastrophic risks, where we assume a positive probability for an infinite value. That case gives a very simple intuition why this phenomenon can occur for such catastrophic risks. We also mention several open problems and conjectures in this context.

q-fin.RM

Experimental and theoretical total cross sections for single and double ionization of the open-$4d$-shell ions Xe$^{12+}$, Xe$^{13+}$, and Xe$^{14+}$ by electron impact

We present new experimental and theoretical cross sections for electron-impact single ionization of Xe$^{12+}$ and Xe$^{13+}$ ions, and double ionization of Xe$^{12+}$, Xe$^{13+}$ and Xe$^{14+}$ ions for collision energies from the respective ionization thresholds up to 3500 eV. The calculations use the fully relativistic subconfiguration-averaged distorted-wave (SCADW) approach and, partly, the more detailed level-to-level distorted wave (LLDW) method. We find that, unlike in previous work, our theoretical cross sections agree with our experimental ones within the experimental uncertainties, except for the near-threshold double-ionization cross sections. We attribute this remaining discrepancy to the neglect of direct-double ionization in the present theoretical treatment.

physics.atom-ph

$L_p$-norm spherical copulas

In this paper we study $L_p$-norm spherical copulas for arbitrary $p \in [1,\infty]$ and arbitrary dimensions. The study is motivated by a conjecture that these distributions lead to a sharp bound for the value of a certain generalized mean difference. We fully characterize conditions for existence and uniqueness of $L_p$-norm spherical copulas. Explicit formulas for their densities and correlation coefficients are derived and the distribution of the radial part is determined. Moreover, statistical inference and efficient simulation are considered.

math.ST

A Model for Multiple Metal Spheres in Oscillating Magnetic Fields using Displaced Dipoles

In this article, we derive a magnetic dipole model for two identical, electrically conducting, and permeable spheres that are exposed to an oscillating homogeneous magnetic field. Our model predicts both amplitude and phase of the induced field outside the spheres. The description is provided for parallel and transverse excitation relative to the axis through the sphere centers. This geometric decomposition allows the application of arbitrary excitation field directions. Our approach is based on one dipole per sphere. The origins of these secondary dipole fields are proposed to be found at positions slightly displaced from the sphere centers to consider the mutual interaction. This displacement and the resulting phase of the dipole moments strongly depend on the distance between the spheres as well as on complex-valued first and second order response factors, which contain material properties and the oscillation frequency. We demonstrate the usefulness of our displaced dipole model in terms of efficiency and accuracy compared to other computationally simple approaches.

physics.class-ph

Near L-Edge Single and Multiple Photoionization of Doubly Charged Iron Ions

Using the photon-ion merged-beams technique at a synchrotron light source, we have measured relative cross sections for single and up to five-fold photoionization of Fe$^{2+}$ ions in the energy range 690--920 eV. This range contains thresholds and resonances associated with ionization and excitation of $2p$ and $2s$ electrons. Calculations were performed to simulate the total absorption spectra. The theoretical results show very good agreement with the experimental data, if overall energy shifts of up to 2.5 eV are applied to the calculated resonance positions and assumptions are made about the initial experimental population of the various levels of the Fe$^{2+}$([Ar]$3d^6$) ground configuration. Furthermore, we performed extensive calculations of the Auger cascades that result when an electron is removed from the $2p$ subshell of Fe$^{2+}$. These computations lead to a better agreement with the measured product-charge-state distributions as compared to earlier work. We conclude that the $L$-shell absorption features of low-charged iron ions are useful for identifying gas-phase iron in the interstellar medium and for discriminating against the various forms of condensed-phase iron bound to composite interstellar dust grains.

physics.atom-ph

Photoionization of astrophysically relevant atomic ions at PIPE

We review recent work on the photoionization of atomic ions of astrophysical interest that has been carried out at the photon-ion merged-beams setup PIPE, a permanently installed end station at the XUV beamline P04 of the PETRAIII synchrotron radiation source operated by DESY in Hamburg, Germany. Our results on single and multiple L-shell photoionization of Fe+, Fe2+, and Fe3+ ions and on single and multiple K-shell photoionization of C-, C+, C4+, Ne+, and Si2+ ions are discussed in astrophysical contexts. Moreover, these experimental results bear witness of the fact, that the implementation of the photon-ion merged-beams method at one of the world's brightest synchrotron light sources has led to a breakthrough for the experimental study of atomic inner-shell photoionization processes with ions.

physics.atom-ph

Dependence uncertainty bounds for the energy score and the multivariate Gini mean difference

The energy distance and energy scores became important tools in multivariate statistics and multivariate probabilistic forecasting in recent years. They are both based on the expected distance of two independent samples. In this paper we study dependence uncertainty bounds for these quantities under the assumption that we know the marginals but do not know the dependence structure. We find some interesting sharp analytic bounds, where one of them is obtained for an unusual spherically symmetric copula. These results should help to better understand the sensitivity of these measures to misspecifications in the copula.

math.ST

A copula-based time series model for global horizontal irradiation

The increasing importance of solar power for electricity generation leads to an increasing demand for probabilistic forecasting of local and aggregated PV yields. In this paper we use an indirect modeling approach for hourly medium to long term local PV yields based on publicly available irradiation data. We suggest a time series model for global horizontal irradiation for which it is easy to generate an arbitrary number of scenarios and thus allows for multivariate probabilistic forecasts for arbitrary time horizons. In contrast to many simplified models that have been considered in the literature so far it features several important stylized facts. Sharp time dependent lower and upper bounds of global horizontal irradiations are estimated that improve the often used physical bounds. The parameters of the beta distributed marginals of the transformed data are allowed to be time dependent. A copula-based time series model is introduced for the hourly and daily dependence structure based on a simple graphical structure known from the theory of vine copulas. Non-Gaussian copulas like Gumbel and BB1 copulas are used that allow for the important feature of so-called tail dependence. Evaluation methods like the continuous ranked probability score (CRPS), the energy score (ES) and the variogram score (VS) are used to compare the power of the model for multivariate probabilistic forecasting with other models used in the literature showing that our model outperforms other models in many respects.

stat.AP

Near L-edge photoionization of triply charged iron ions

Relative cross sections for $m$-fold photoionization ($m=1,\ldots,5$) of Fe$^{3+}$ by single photon absorption were measured employing the photon-ion merged-beams setup PIPE at the PETRA III synchrotron light source operated at DESY in Hamburg, Germany. The photon energies used spanned the range of $680-950\,\mathrm{eV}$, covering both the photoexcitation resonances from the $2p$ and $2s$ shells as well as the direct ionization from both shells. Multiconfiguration Dirac-Hartree-Fock (MCDHF) calculations were performed to simulate the total photoexcitation spectra. Good agreement was found with the experimental results. These computations helped to assign several strong resonance features to specific transitions. We also carried out Hartree-Fock calculations with relativistic extensions taking into account both photoexcitation and photoionization. Furthermore, we performed extensive MCDHF calculations of the Auger cascades that result when an electron is removed from the $2p$ and $2s$ shells of Fe$^{3+}$. Our theoretically predicted charge-state fractions are in good agreement with the experimental results, representing a substantial improvement over previous theoretical calculations. The main reason for the disagreement with the previous calculations is their lack of inclusion of slow Auger decays of several configurations that can only proceed when accompanied by de-excitation of two electrons. In such cases, this additional shake-down transition of a (sub-)valence electron is required to gain the necessary energy for the release of the Auger electron.

physics.atom-ph

Near L-Edge Single and Multiple Photoionization of Singly Charged Iron Ions

Absolute cross sections for m-fold photoionization (m=1,...,6) of Fe+ by a single photon were measured employing the photon-ion merged-beams setup PIPE at the PETRA III synchrotron light source, operated by DESY in Hamburg, Germany. Photon energies were in the range 680-920 eV which covers the photoionization resonances associated with 2p and 2s excitation to higher atomic shells as well as the thresholds for 2p and 2s ionization. The corresponding resonance positions were measured with an uncertainty of +- 0.2 eV. The cross section for Fe+ photoabsorption is derived as the sum of the individually measured cross-sections for m-fold ionization. Calculations of the Fe+ absorption cross sections have been carried out using two different theoretical approaches, Hartree-Fock including relativistic extensions and fully relativistic Multi-Configuration Dirac Fock. Apart from overall energy shifts of up to about 3 eV, the theoretical cross sections are in good agreement with each other and with the experimental results. In addition, the complex deexcitation cascades after the creation of inner-shell holes in the Fe+ ion have been tracked on the atomic fine-structure level. The corresponding theoretical results for the product charge-state distributions are in much better agreement with the experimental data than previously published configuration-average results. The present experimental and theoretical results are valuable for opacity calculations and are expected to pave the way to a more accurate determination of the iron abundance in the interstellar medium.

astro-ph.IM

Recombination of open-f-shell tungsten ions

We review experimental and theoretical efforts aimed at a detailed understanding of the recombination of electrons with highly-charged tungsten ions characterised by an open 4f sub-shell. Highly-charged tungsten occurs as a plasma contaminant in ITER-like tokamak experiments, where it acts as an unwanted cooling agent. Modelling of the charge state populations in a plasma requires reliable thermal rate coefficients for charge-changing electron collisions. The electron recombination of medium-charged tungsten species with open 4f sub-shells is especially challenging to compute reliably. Storage-ring experiments have been conducted that yielded recombination rate coefficients at high energy resolution and well-understood systematics. Significant deviations compared to simplified, but prevalent, computational models have been found. A new class of ab-initio numerical calculations has been developed that provides reliable predictions of the total plasma recombination rate coefficients for these ions.

physics.atom-ph

PAMOP: Petascale Atomic, Molecular and Optical Collision Calculations

Petaflop architectures are currently being utilized efficiently to perform large scale computations in Atomic, Molecular and Optical Collisions. We solve the Schrödinger or Dirac equation for the appropriate collision problem using the R-matrix or R-matrix with pseudo-states approach. We briefly outline the parallel methodology used and implemented for the current suite of Breit-Pauli and DARC codes. In this report, various examples are shown from our theoretical results compared with experimental results obtained from Synchrotron Radiation facilities where the Cray architecture at HLRS is playing an integral part in our computational projects.

physics.atom-ph