arXiv subjects

Ali Can Günhan

Publications and source records attributed to Ali Can Günhan.

3 recordsLinked to original sources

arXiv2026

Catalytic quantum thermodynamics beyond additivity and reduced-state monotones

The generalized second laws of quantum thermodynamics are usually formulated in terms of Rényi divergences and the associated family of generalized free energies. In catalytic thermal transformations, this framework typically certifies the existence of a suitable catalyst but does not make the catalytic contribution explicit in the resulting system-level inequalities. Here we develop a complementary formulation based on non-additive divergences, whose pseudo-additive structure yields a family of generalized free energies with an explicit catalyst-dependent correction term. For uncorrelated catalytic thermal transformations, we show that this leads to non-additive second-law relations providing nontrivial constraints on admissible catalysts when the catalyst is returned only approximately. We also analyze correlated catalytic thermal transformations and show, through explicit finite-dimensional examples, that reduced-state data are generally insufficient to characterize thermodynamic accessibility: the thermo-majorization behavior of the joint transformation can change while the system and catalyst marginals remain fixed, and even states with identical marginals and the same mutual information can exhibit different thermo-majorization accessibility.

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arXiv2026

Contextuality from the Projector Overlap Matrix

We place several known indicators of Kochen--Specker contextuality -- the KCBS correlator $χ$, the contextual fraction $\CF$, the Shannon-entropic $n$-cycle inequality of Chaves and Fritz, and the operational commutator witness $D$ of Paper~I -- into a single projector-geometric framework organized around the overlap matrix $\Tcal_{ij} = d^{-1}\tr[(\hat P_i \hat Q_j)^2]$, where $\hat P_i$ and $\hat Q_j$ are the joint-eigenspace projectors of the two compatible observable pairs within a measurement context. The state-independent scalar content of $\Tcal$ is carried by two independent contractions: the mutual information energy $E = \sum_{ij}\Tcal_{ij}$ of Paper~I (equivalently, its logarithmic form $S_2 = -\log_2 E$), and the Maassen--Uffink extremal overlap $c_\MU = \max_{i,j}|\langle a_i,b_i | c_j,b_j\rangle|$. We prove that $S_2$ is non-increasing under coarse-graining, that $S_2(\Gcal) > 0$ is a necessary configuration-level condition for observable contextuality, and that the additive composition $S_2(\Gcal) = \sum_αS_2(\Gcal_α)$ is exact for the KCBS pentagon. We further show that in the spin-$1$ realization of the KCBS pentagon, a shared $m_s=0$ eigenstate in each context forces $c_\MU = 1$, rendering every Maassen--Uffink-type bound trivial -- a structural mechanism that makes explicit why outcome-entropic uncertainty relations based on $c_\MU$ are silent on KCBS contextuality, while $S_2 \approx 2.7266$~bits throughout. Applied to KCBS and CHSH, the framework identifies regimes in which every state-dependent witness considered here is silent yet $S_2(\Gcal) > 0$ by an amount set by the projector geometry alone.

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arXiv2025

Information-Theoretic and Operational Measures of Quantum Contextuality

We propose an information -- theoretic framework for quantifying Kochen-Specker contextuality. Two complementary measures are introduced: the mutual information energy, a state-independent quantity inspired by Onicescu's information energy that captures the geometric overlap between joint eigenspaces within a context; and an operational measure based on commutator expectation values that reflects contextual behavior at the level of measurement outcomes. We establish a hierarchy of bounds connecting these measures to the Robertson uncertainty relation, including spectral, purity-corrected, and operator norm estimates. The framework is applied to the Klyachko-Can-Binicioğlu-Shumovsky (KCBS) scenario for spin-1 systems, where all quantities admit closed-form expressions. The Majorana-stellar representation furnishes a common geometric platform on which both the operational measure and the uncertainty products can be analyzed. For spin-1, this representation yields a three-dimensional Euclidean-like visualization of the Hilbert space in which, states lying on a plane exhibit maximum uncertainty for the observable along the perpendicular direction; simultaneous optimization across all KCBS contexts singles out a unique state on the symmetry axis. Notably, states achieving the optimal sum of uncertainty products exhibit vanishing operational contextuality, while states with substantial operational contextuality satisfy a nontrivial Robertson bound -- the two extremes are achieved by distinct quantum states.

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