arXiv subjects

Alicia Ruiz-Caridad

Publications and source records attributed to Alicia Ruiz-Caridad.

2 recordsLinked to original sources

arXiv2026

Structure-driven analog optical control in ion-pumped SrFeO$_{3-δ}$ thin-film devices

Electrochromic devices (ECDs) offer a compelling route toward low-power, non-emissive optical modulators with nonvolatile states. However, their widespread implementation is hindered by limitations in operating voltage, switching speed, color tunability, and long-term stability. Mixed ionic-electronic conductors (MIECs) provide a promising alternative platform, enabling optical modulation through ion-driven redox and structural transformations. Oxygen-based MIECs offer enhanced durability, environmental robustness, and compatibility with oxide electronics and silicon photonics, yet remain largely underexplored for electrochromic and photonic applications. Here, we demonstrate structure-driven analog optical control in an ion-pumped SrFeO$_{3-δ}$ thin-film device by undergoing reversible oxygen-driven phase transitions between brownmillerite and perovskite structures. Phase transition is accompanied by pronounced changes in its electronic structure and optical constants. By harnessing these ion-induced structural transformations and integrating an optically passive Al$_2$O$_3$ interference layer, we achieve continuous and reversible modulation of optical transmittance and color. These results provide a general framework for ion-driven analog photonic and electrochromic devices and highlight the potential of oxygen-based MIECs for next-generation ionochromic systems compatible with silicon-based photonic platforms.

physics.app-ph↗

arXiv2025

Phonon interference effects in GaAs-GaP superlattice nanowires

Fine-tuning the functional properties of nanomaterials is crucial for technological applications. Superlattices, characterized by periodic repetitions of two or more materials in different dimensions, have emerged as a promising area of investigation. We present a study of the phonon interference effect on thermal transport in GaAs-GaP superlattice nanowires with sharp interfaces between the GaAs and GaP layers, as confirmed by high-resolution transmission electron microscopy. We performed thermal conductivity measurements using the so-called thermal bridge method on superlattice nanowires with a period varying from 4.8 to 23.3 nm. The measurements showed a minimum of the thermal conductivity as a function of superlattice period up to room temperature, that we interpreted as an indication of the crossover from coherent to incoherent thermal transport. Notably, this effect is not destroyed by surface boundary or by phonon-phonon scattering, as the crossover trend is also observed at room temperature. Our results were corroborated by both ab initio lattice dynamics and semiclassical nonequilibrium molecular dynamics calculations. These findings provide insights into the wave-like and particle-like transport of phonons in superlattice nanowires and demonstrate the potential for engineering thermal properties through precise control of the superlattice structure.

cond-mat.mes-hall↗