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Alpha Lee

Publications and source records attributed to Alpha Lee.

4 recordsLinked to original sources

Automatic virtual voltage extraction of a 2x2 array of quantum dots with machine learning

Spin qubits in quantum dots are a compelling platform for fault-tolerant quantum computing due to the potential to fabricate dense two-dimensional arrays with nearest neighbour couplings, a requirement to implement the surface code. However, due to the proximity of the surface gate electrodes, cross-coupling capacitances can be substantial, making it difficult to control each quantum dot independently. Increasing the number of quantum dots increases the complexity of the calibration process, which becomes impractical to do heuristically. Inspired by recent demonstrations of industrial-grade silicon quantum dot bilinear arrays, we develop a theoretical framework to mitigate the effect of cross-capacitances in 2x2 arrays of quantum dots and extend it to 2xN and NxN arrays. The method is based on extracting the gradients in gate-voltage space of different charge transitions in multiple two-dimensional charge stability diagrams to determine the system's virtual gates. To automate the process, we train an ensemble of regression models to extract the gradients from a Hough transformation of charge stability diagrams and validate the algorithm on simulated and experimental data of a 2x2 quantum dot array. Our method provides a completely automated tool to mitigate cross-capacitance effects in arrays of QDs which could be utilised to study variability in device electrostatics across large arrays.

cond-mat.dis-nn

Mechanistic Insight to the Chemical Treatments of Monolayer Transition Metal Disulfides for Photoluminescence Enhancement

There is a growing interest in obtaining high quality monolayer transition metal disulfides (TMDSs) for optoelectronic device applications. Surface chemical treatments using a range of chemicals on monolayer TMDSs have proven effective to improve their photoluminescence (PL) yield. However, the underlying mechanism for PL enhancement by these treatments is not clear, which prevents a rational design of passivation strategies. In this work, a simple and effective approach to significantly enhance PL of TMDSs is demonstrated by using a family of cation donors, which we show to be much more effective than commonly used p-dopants which achieve PL enhancement through electron transfer. We develop a detailed mechanistic picture for the action of these cation donors and demonstrate that one of them, Li-TFSI (bistriflimide), enhances the PL of both MoS2 and WS2 to a level double that compared to the widely discussed and currently best performing super acid H-TFSI treatment. In addition, the ionic salts used in chemical treatments are compatible with a range of greener solvents and are easier to handle than super-acids, which provides the possibility of directly treating TMDSs during device fabrication. This work sets up rational selection rules for ionic chemicals to passivate TMDSs and increases the potential of TMDSs in practical optoelectronic applications.

physics.app-ph

Switching the structural force in ionic liquid-solvent mixtures by varying composition

The structure and interactions in electrolytes at high concentration have implications from energy storage to biomolecular interactions. However many experimental observations are yet to be explained in these mixtures, which are far beyond the regime of validity of mean field models. Here, we study the structural forces in a mixture of ionic liquid and solvent that is miscible in all proportions at room temperature. Using the surface force balance to measure the force between macroscopic smooth surfaces across the liquid mixtures, we uncover an abrupt increase in the wavelength above a threshold ion concentration. Below the threshold concentration the wavelength is determined by the size of the solvent molecule, whereas above the threshold it is the diameter of a cation-anion pair that determines the wavelength.

cond-mat.soft

Describing Spin-Selective Reactions of Radical Pairs Using Quantum Jump Approaches

Recently, spin-selective radical pair reactions have been studied using concepts from quantum measurement theory. In this Article, we show that the approach taken by Kominis (Physical Review E, 83, 2011, 056118) leads to erroneous results due to a problematic treatment of quantum jumps. Correct consideration of quantum jumps leads to either the traditional master equation or the Jones-Hore master equation.

quant-ph