arXiv subjects

Amirhosein Amini

Publications and source records attributed to Amirhosein Amini.

3 recordsLinked to original sources

arXiv2026

Many-Body Second Order Green's Function Theory for Ab Initio Molecular Quantum Electrodynamics

In this work, we develop two many-body quantum electrodynamic methods to calculate the ground-state energies of strongly coupled light-matter molecular systems. Specifically, we extend the second-order many-body Green's function theory (GF2) for electronic systems to incorporate electron-boson couplings. We employ two ansätze to treat the bosonic part of the system, namely the coherent-state (CS) and Lang-Firsov (LF) transformed vacuum state. These are combined with the GF2 method to construct two new approaches, which we refer to as CS-GF2 and LF-GF2. We benchmark CS- and LF-GF2 by studying various molecular systems inside an optical cavity. We investigate $\mathrm{H}_2$ and $\mathrm{LiH}$ potential energy surfaces, keto-eneol tautomerization energy barrier, van-der Waals interactions between two $\mathrm{H_2}$ molecules and the torsional potential energy surface of the ethylene molecule, $\mathrm{C_2H_4}$. Both methods provide highly accurate energies, with only modest additional improvement observed in LF-GF2.

quant-ph↗

arXiv2026

Giant optical spin-orbit interactions in ferroelectric van der Waals waveguides

Optical spin-orbit interactions (SOI) link photonic spin to momentum, offering a route toward on-chip polarization control and beam steering. Nevertheless, achieving sufficient optical SOI and nonlinearities on sub-micrometer scales - a prerequisite for dense photonic integration - remains an outstanding challenge. Here, we show that highly birefringent van der Waals (vdW) waveguides provide an ideal, chip-compatible platform to address this limitation. We focus on the ferroelectric semiconductor NbOI2, which exhibits record optical nonlinearities and dielectric anisotropy. Using femtosecond optical microscopy, we image light propagation and harmonic conversion beyond the total internal reflection barrier over tens of micrometers in NbOI2 slab waveguides. We report giant optical spin-splitting through the optical spin Hall effect, which facilitates spatial separation of optical spin currents on sub-micrometer scales, in quantitative agreement with a microscopic light-matter interaction model. We further leverage optical spin-momentum locking to realize polarization-controlled waveguide steering. We generalize these observations across various vdW waveguides and empirically confirm a scaling law linking dielectric anisotropy to geometric spin-splitting. Our results establish highly anisotropic vdW waveguides as an ideal platform for densely integrated opto-spintronic technologies.

cond-mat.mtrl-sci↗

arXiv2025

On-the-Fly Cavity-Molecular Dynamics of Vibrational Polaritons

In this work, we combine the density functional tight-binding (DFTB) approach with a light-matter Hamiltonian beyond the long-wavelength approximation to propagate the dynamics of vibrational polaritons formed by coupling molecular vibrations to confined radiation inside a Fabry-Pérot optical cavity. Here, we develop a parallelized propagation scheme with lightweight inter-CPU communication by exploiting the sparse nature of the light-matter interactions in the real space representation. We find that the computationally expensive Born charges required for our propagation can be replaced with the computationally inexpensive Mulliken charges to obtain qualitatively accurate linear spectra especially when the nonlinearity (arising from molecular vibrations) of the light-matter interaction term is not substantial. However, the same approach may not be suitable to be used for studying cavity modification of energy transport or chemical dynamics as this approximation leads to spurious heating of the light-matter hybrid system. We demonstrate the utility of this on-the-fly approach to compute angle resolved polaritonic spectra of water. We implement our approach as an open-source computational package, CavOTF, which is available on GitHub.

physics.chem-ph↗