arXiv subjects

Ana López-Sepulcre

Publications and source records attributed to Ana López-Sepulcre.

At least 37 records · Page 2Linked to original sources

arXiv2021

Exploring the 100 au Scale Structure of the Protobinary System NGC 2264 CMM3 with ALMA

We have observed the young protostellar system NGC 2264 CMM3 in the 1.3 mm and 2.0 mm bands at a resolution of about 0.1$"$ (70 au) with ALMA. The structures of two distinct components, CMM3A and CMM3B, are resolved in the continuum images of both bands. CMM3A has an elliptical structure extending along the direction almost perpendicular to the known outflow, while CMM3B reveals a round shape. We have fitted two 2D-Gaussian components to the elliptical structure of CMM3A and CMM3B, and have separated the disk and envelope components for each source. The spectral index $α$ between 2.0 mm and 0.8 mm is derived to be 2.4-2.7 and 2.4-2.6 for CMM3A and CMM3B, respectively, indicating the optically thick dust emission and/or the grain growth. A velocity gradient in the disk/envelope direction is detected for CMM3A in the CH$_3$CN, CH$_3$OH, and $^{13}$CH$_3$OH lines detected in the 1.3 mm band, which can be interpreted as the rotation of the disk/envelope system. From this result, the protostellar mass of CMM3A is roughly evaluated to be $0.1- 0.5$ $M_\odot$ by assuming Keplerian rotation. The mass accretion rate is thus estimated to be $5\times10^{-5}$ - 4 $\times$ $10^{-3}$ $M_\odot$ yr$^{-1}$, which is higher than typical mass accretion rate of low-mass protostars. The OCS emission line shows a velocity gradient in both outflow direction and disk/envelope direction. A hint of outflow rotation is found, and the specific angular momentum of the outflow is estimated to be comparable to that of the disk. These results provide us with novel information on the initial stage of a binary/multiple system.

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arXiv2021

Rotating Motion of the Outflow of IRAS 16293-2422 A1 at its Origin Point near the Protostar

The Class 0 protostar IRAS 16293$-$2422 Source A is known to be a binary system (A1 and A2) or even a multiple system, which processes a complex outflow structure. We have observed this source in the C$^{34}$S, SO, and OCS lines at 3.1 mm with the Atacama Large Millimeter/submillimeter Array (ALMA). A substructure of this source is traced by our high angular-resolution observation (0\farcs12; 20 au) of the continuum emission. The northwest-southeast (NW-SE) outflow on a 2\arcsec\ scale is detected in the SO ($J_N$ = $2_2$--$1_1$) line. Based on the morphology of the SO distribution, this bipolar outflow structure seems to originate from the protostar A1 and its circumstellar disk, or the circummultiple structure of Source A. The rotation motion of the NW-SE outflow is detected in the SO and OCS emissions. We evaluate the specific angular momentum of the outflowing gas to be $(8.6 - 14.3) \times 10^{-4}$ km s$^{-1}$ pc. If the driving source of this outflow is the protostar A1 and its circumstellar disk, it can be a potential mechanism to extract the specific angular momentum of the disk structure. These results can be a hint for the outflow launching mechanism in this source. Furthermore, they provide us with an important clue to resolve the complicated structure of IRAS 16293$-$2422 Source A.

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arXiv2021

Properties of cold molecular gas in four type-1 active galaxies hosting outflows

Feedback from active galactic nuclei (AGN) has proven to be a critical ingredient in the current picture of galaxy assembly and growth. However, observational constraints on AGN-driven outflows face technical challenges and as a result, the cold molecular gas outflow properties of type-1 AGN are not well known. We present new IRAM NOrthern Extended Milimeter Array (NOEMA) observations of CO (1-0) in F07599+6508, Z11598$-$0112, F13342+3932, and PG1440+356, all nearby type-1 AGN and ultraluminous infrared galaxies (ULIRGs). We achieve spatial resolution of 1-3 arcsec corresponding to physical scales of 2--8~kpc and spectral resolution of 15-60 km s$^{-1}$ which enables updated CO (1-0) redshifts and a detailed morphological view of the cold molecular gas in these sources. The CO (1-0) luminosities, $L_{CO}^{\prime}$, are in the range 2-12$\times 10^9$ K km s$^{-1}$ pc$^{2}$ and inferred molecular gas masses, $M$(H$_2$), are in the range 2-9$\times 10^9$ M$_{\odot}$. The velocity fields and gas distributions do not unambiguously identify any of these sources as having outflows. However, Z11598$-$0112 has signs of infalling material and after the subtraction of a rotating disk model PG 1440+356 shows complex kinematics in the residuals that may indicate an outflow or warped disk.

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arXiv2021

The Perseus ALMA Chemistry Survey (PEACHES). I. The Complex Organic Molecules in Perseus Embedded Protostars

To date, about two dozen low-mass embedded protostars exhibit rich spectra with lines of complex organic molecule (COM). These protostars seem to possess different enrichment in COMs. However, the statistics of COM abundance in low-mass protostars are limited by the scarcity of observations. This study introduces the Perseus ALMA Chemistry Survey (PEACHES), which aims at unbiasedly characterizing the chemistry of COMs toward the embedded (Class 0/I) protostars in the Perseus molecular cloud. Of 50 embedded protostars surveyed, 58% of them have emission from COMs. A 56%, 32%, and 40% of the protostars have CH$_3$OH, CH$_3$OCHO, and N-bearing COMs, respectively. The detectability of COMs depends neither on the averaged continuum brightness temperature, a proxy of the H$_2$ column density, nor on the bolometric luminosity and the bolometric temperature. For the protostars with detected COMs, CH$_3$OH has a tight correlation with CH$_3$CN, spanning more than two orders of magnitude in column densities normalized by the continuum brightness temperature, suggesting a chemical relation between CH$_3$OH and CH$_3$CN and a large chemical diversity in the PEACHES samples at the same time. A similar trend with more scatter is also found between all identified COMs, hinting at a common chemistry for the sources with COMs. The correlation between COMs is insensitive to the protostellar properties, such as the bolometric luminosity and the bolometric temperature. The abundance of larger COMs (CH$_3$OCHO and CH$_3$OCH$_3$) relative to that of smaller COMs (CH$_3$OH and CH$_3$CN) increases with the inferred gas column density, hinting at an efficient production of complex species in denser envelopes.

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arXiv2021

FAUST II. Discovery of a Secondary Outflow in IRAS 15398-3359: Variability in Outflow Direction during the Earliest Stage of Star Formation?

We have observed the very low-mass Class 0 protostar IRAS 15398-3359 at scales ranging from 50 au to 1800 au, as part of the ALMA Large Program FAUST. We uncover a linear feature, visible in H2CO, SO, and C18O line emission, which extends from the source along a direction almost perpendicular to the known active outflow. Molecular line emission from H2CO, SO, SiO, and CH3OH further reveals an arc-like structure connected to the outer end of the linear feature and separated from the protostar, IRAS 15398-3359, by 1200 au. The arc-like structure is blue-shifted with respect to the systemic velocity. A velocity gradient of 1.2 km/s over 1200 au along the linear feature seen in the H2CO emission connects the protostar and the arc-like structure kinematically. SO, SiO, and CH3OH are known to trace shocks, and we interpret the arc-like structure as a relic shock region produced by an outflow previously launched by IRAS 15398-3359. The velocity gradient along the linear structure can be explained as relic outflow motion. The origins of the newly observed arc-like structure and extended linear feature are discussed in relation to turbulent motions within the protostellar core and episodic accretion events during the earliest stage of protostellar evolution.

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arXiv2020

Hot Corinos Chemical Diversity: Myth or Reality?

After almost 20 years of hunting, only about a dozen hot corinos, hot regions enriched in interstellar complex organic molecules (iCOMs), are known. Of them, many are binary systems with the two components showing drastically different molecular spectra. Two obvious questions arise. Why are hot corinos so difficult to find and why do their binary components seem chemically different? The answer to both questions could be a high dust opacity that would hide the molecular lines. To test this hypothesis, we observed methanol lines at centimeter wavelengths, where dust opacity is negligible, using the Very Large Array interferometer. We targeted the NGC 1333 IRAS 4A binary system, for which one of the two components, 4A1, has a spectrum deprived of iCOMs lines when observed at millimeter wavelengths, while the other component, 4A2, is very rich in iCOMs. We found that centimeter methanol lines are similarly bright toward 4A1 and 4A2. Their non-LTE analysis indicates gas density and temperature ($\geq2\times10^6$ cm$^{-3}$ and 100--190 K), methanol column density ($\sim10^{19}$ cm$^{-2}$) and extent ($\sim$35 au in radius) similar in 4A1 and 4A2, proving that both are hot corinos. Furthermore, the comparison with previous methanol line millimeter observations allows us to estimate the optical depth of the dust in front of 4A1 and 4A2, respectively. The obtained values explain the absence of iCOMs line emission toward 4A1 at millimeter wavelengths and indicate that the abundances toward 4A2 are underestimated by $\sim$30\%. Therefore, centimeter observations are crucial for the correct study of hot corinos, their census, and their molecular abundances.

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arXiv2020

Seeds of Life in Space (SOLIS). VI. Chemical evolution of sulfuretted species along the outflows driven by the low-mass protostellar binary NGC1333-IRAS4A

Context. Low-mass protostars drive powerful molecular outflows that can be observed with mm and sub-mm telescopes. Various sulfuretted species are known to be bright in shocks and could be used to infer the physical and chemical conditions throughout the observed outflows. Aims. The evolution of sulfur chemistry is studied along the outflows driven by the NGC1333-IRAS4A protobinary system located in the Perseus cloud to constrain the physical and chemical processes at work in shocks. Methods. We observed various transitions from OCS, CS, SO, and SO$_2$ towards NGC1333-IRAS4A in the 1.3, 2, and 3mm bands using the IRAM NOEMA array and we interpreted the observations through the use of the Paris-Durham shock model. Results. The targeted species clearly show different spatial emission along the two outflows driven by IRAS4A. OCS is brighter on small and large scales along the south outflow driven by IRAS4A1, whereas SO$_2$ is detected rather along the outflow driven by IRAS4A2 that is extended along the north east - south west (NE-SW) direction. Column density ratio maps estimated from a rotational diagram analysis allowed us to confirm a clear gradient of the OCS/SO$_2$ column density ratio between the IRAS4A1 and IRAS4A2 outflows. SO is detected at extremely high radial velocity up to 25 km/s relative to the source velocity, clearly allowing us to distinguish the two outflows on small scales. Conclusions. The observed chemical differentiation between the two outflows of the IRAS4A system could be explained by a different chemical history. The outflow driven by IRAS4A1 is likely younger and more enriched in species initially formed in interstellar ices, such as OCS, and recently sputtered into the shock gas. In contrast, the longer and likely older outflow triggered by IRAS4A2 is more enriched in species that have a gas phase origin, such as SO$_2$.

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arXiv2019

Exploring the formation pathways of formamide near young O-type stars

Context. As a building block for amino acids, formamide (NH$_2$CHO) is an important molecule in astrobiology and astrochemistry, but its formation path in the interstellar medium is not understood well. Aims. We aim to find empirical evidence to support the chemical relationships of formamide to HNCO and H$_2$CO. Methods. We examine high angular resolution (~0.2") Atacama Large Millimeter/submillimeter Array (ALMA) maps of six sources in three high-mass star-forming regions and compare the spatial extent, integrated emission peak position, and velocity structure of HNCO and H$_2$CO line emission with that of NH$_2$CHO by using moment maps. Through spectral modeling, we compare the abundances of these three species. Results. In these sources, the emission peak separation and velocity dispersion of formamide emission is most often similar to HNCO emission, while the velocity structure is generally just as similar to H$_2$CO and HNCO (within errors). From the spectral modeling, we see that the abundances between all three of our focus species are correlated, and the relationship between NH$_2$CHO and HNCO reproduces the previously demonstrated abundance relationship. Conclusions. In this first interferometric study, which compares two potential parent species to NH$_2$CHO, we find that all moment maps for HNCO are more similar to NH$_2$CHO than H$_2$CO in one of our six sources (G24 A1). For the other five sources, the relationship between NH$_2$CHO, HNCO, and H$_2$CO is unclear as the different moment maps for each source are not consistently more similar to one species as opposed to the other.

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arXiv2019

Interstellar formamide (NH$_2$CHO), a key prebiotic precursor

Formamide (NH$_2$CHO) has been identified as a potential precursor of a wide variety of organic compounds essential to life, and many biochemical studies propose it likely played a crucial role in the context of the origin of life on our planet. The detection of formamide in comets, which are believed to have --at least partially-- inherited their current chemical composition during the birth of the Solar System, raises the question whether a non-negligible amount of formamide may have been exogenously delivered onto a very young Earth about four billion years ago. A crucial part of the effort to answer this question involves searching for formamide in regions where stars and planets are forming today in our Galaxy, as this can shed light on its formation, survival, and chemical re-processing along the different evolutionary phases leading to a star and planetary system like our own. The present review primarily addresses the chemistry of formamide in the interstellar medium, from the point of view of (i) astronomical observations, (ii) experiments, and (iii) theoretical calculations. While focusing on just one molecule, this review also more generally reflects the importance of joining efforts across multiple scientific disciplines in order to make progress in the highly interdisciplinary science of astrochemistry.

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arXiv2019

Interferometric observations of warm deuterated methanol in the inner regions of low-mass protostars

Methanol is a key species in astrochemistry since it is the most abundant organic molecule in the ISM and is thought to be the mother molecule of many complex organic species. Estimating the deuteration of methanol around young protostars is of crucial importance because it highly depends on its formation mechanisms and the physical conditions during its moment of formation. We analyse dozens of transitions from deuterated methanol isotopologues coming from various existing observational datasets from the IRAM-PdBI and ALMA sub-mm interferometers to estimate the methanol deuteration surrounding three low-mass protostars on Solar System scales. A population diagram analysis allows us to derive a [CH$_2$DOH]/[CH$_3$OH] abundance ratio of 3-6 % and a [CH$_3$OD]/[CH$_3$OH] ratio of 0.4-1.6 % in the warm inner protostellar regions. These values are ten times lower than those derived with previous single-dish observations towards these sources but they are 10-100 times higher than the methanol deuteration measured in massive hot cores. Dust temperature maps obtained from Herschel and Planck observations show that massive hot cores are located in warmer molecular clouds than low-mass sources, with temperature differences of $\sim$10 K. Comparison with the predictions of the gas-grain astrochemical model GRAINOBLE shows that such a temperature difference is sufficient to explain the different deuteration observed in low- to high-mass sources, suggesting that the physical conditions of the molecular cloud at the origin of the protostars mostly govern the present observed deuteration of methanol. The methanol deuteration measured in this work is higher by a factor of 5 than the upper limit in methanol deuteration estimated in comet Hale-Bopp, implying that an important reprocessing of the organic material would have occurred in the solar nebula during the formation of the Solar System.

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arXiv2019

Sulfur-Bearing Species Tracing the Disk/Envelope System in the Class I Protostellar Source Elias 29

We have observed the Class I protostellar source Elias 29 with Atacama Large Millimeter/submillimeter Array (ALMA). We have detected CS, SO, $^{34}$SO, SO$_2$, and SiO line emissions in a compact component concentrated near the protostar and a ridge component separated from the protostar by 4\arcsec\ ($\sim 500$ au). The former component is found to be abundant in SO and SO$_2$ but deficient in CS. The abundance ratio SO/CS is as high as $3^{+13}_{-2} \times 10^2$ at the protostar, which is even higher than that in the outflow-shocked region of L1157 B1. However, organic molecules (HCOOCH$_3$, CH$_3$OCH$_3$, CCH, and c-C$_3$H$_2$) are deficient in Elias 29. We attribute the deficiency in organic molecules and richness in SO and SO$_2$ to the evolved nature of the source or the relatively high dust temperature (\protect\raisebox{-0.7ex}{$\:\stackrel{\textstyle >}{\sim}\:$} 20 K) in the parent cloud of Elias 29. The SO and SO$_2$ emissions trace rotation around the protostar. Assuming a highly inclined configuration ($i \geq 65$\degr; 0\degr\ for a face-on configuration) and Keplerian motion for simplicity, the protostellar mass is estimated to be (0.8 -- 1.0) \Msun. The $^{34}$SO and SO$_2$ emissions are asymmetric in their spectra; the blue-shifted components are weaker than the red-shifted ones. Although this may be attributed to the asymmetric molecular distribution, other possibilities are also discussed.

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arXiv2018

Seeds of Life in Space (SOLIS). III. Zooming into the methanol peak of the pre-stellar core L1544

Towards the pre-stellar core L1544, the methanol (CH$_3$OH) emission forms an asymmetric ring around the core centre, where CH$_3$OH is mostly in solid form, with a clear peak 4000~au to the north-east of the dust continuum peak. As part of the NOEMA Large Project SOLIS (Seeds of Life in Space), the CH$_3$OH peak has been spatially resolved to study its kinematics and physical structure and to investigate the cause behind the local enhancement. We find that methanol emission is distributed in a ridge parallel to the main axis of the dense core. The centroid velocity increases by about 0.2~km~s$^{-1}$ and the velocity dispersion increases from subsonic to transonic towards the central zone of the core, where the velocity field also shows complex structure. This could be indication of gentle accretion of material onto the core or interaction of two filaments, producing a slow shock. We measure the rotational temperature and show that methanol is in local thermodynamic equilibrium (LTE) only close to the dust peak, where it is significantly depleted. The CH$_3$OH column density, $N_{tot}({\rm CH_3OH})$, profile has been derived with non-LTE radiative transfer modelling and compared with chemical models of a static core. The measured $N_{tot}({\rm CH_3OH})$ profile is consistent with model predictions, but the total column densities are one order of magnitude lower than those predicted by models, suggesting that the efficiency of reactive desorption or atomic hydrogen tunnelling adopted in the model may be overestimated; or that an evolutionary model is needed to better reproduce methanol abundance.

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arXiv2018

Chemical and Physical Picture of IRAS 16293-2422 Source B at a Sub-arcsecond Scale Studied with ALMA

We have analyzed the OCS, H$_2$CS, CH$_3$OH, and HCOOCH$_3$ data observed toward the low-mass protostar IRAS 16293--2422 Source B at a sub-arcsecond resolution with ALMA. A clear chemical differentiation is seen in their distributions; OCS and H$_2$CS are extended with a slight rotation signature, while CH$_3$OH and HCOOCH$_3$ are concentrated near the protostar. Such a chemical change in the vicinity of the protostar is similar to the companion (Source A) case. The extended component is interpreted by the infalling-rotating envelope model with a nearly face-on configuration. The radius of the centrifugal barrier of the infalling-rotating envelope is roughly evaluated to be ($30-50$) au. The observed lines show the inverse P-Cygni profile, indicating the infall motion with in a few 10 au from the protostar. The nearly pole-on geometry of the outflow lobes is inferred from the SiO distribution, and thus, the infalling and outflowing motions should coexist along the line-of-sight to the protostar. This implies that the infalling gas is localized near the protostar and the current launching points of the outflow have an offset from the protostar. A possible mechanism for this configuration is discussed.

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arXiv2017

Chemical complexity induced by efficient ice evaporation in the Barnard 5 molecular cloud

Cold gas-phase water has recently been detected in a cold dark cloud, Barnard 5 located in the Perseus complex, by targeting methanol peaks as signposts for ice mantle evaporation. Observed morphology and abundances of methanol and water are consistent with a transient non-thermal evaporation process only affecting the outermost ice mantle layers, possibly triggering a more complex chemistry. We present the detection of the Complex Organic Molecules (COMs) acetaldehyde and methyl formate as well as formic acid and ketene, and the tentative detection of di-methyl ether towards the methanol hotspot of Barnard 5 located between two dense cores using the single dish OSO 20m, IRAM 30m, and NRO 45m telescopes. The high energy cis- conformer of formic acid is detected, suggesting that formic acid is mostly formed at the surface of interstellar grains and then evaporated. The detection of multiple transitions for each species allows us to constrain their abundances through LTE and non-LTE methods. All the considered COMs show similar abundances between $\sim 1$ and $\sim 10$ % relative to methanol depending on the assumed excitation temperature. The non-detection of glycolaldehyde, an isomer of methyl formate, with a [glycolaldehyde]/[methyl formate] abundance ratio lower than 6 %, favours gas phase formation pathways triggered by methanol evaporation. According to their excitation temperatures derived in massive hot cores, formic acid, ketene, and acetaldehyde have been designated as "lukewarm" COMs whereas methyl formate and di-methyl ether were defined as "warm" species. Comparison with previous observations of other types of sources confirms that "lukewarm" and "warm" COMs show similar abundances in low-density cold gas whereas the "warm" COMs tend to be more abundant than the "lukewarm" species in warm protostellar cores.

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arXiv2017

Vertical Structure of the Transition Zone from Infalling Rotating Envelope to Disk in the Class 0 Protostar, IRAS04368+2557

We have resolved for the first time the radial and vertical structure of the almost edge-on envelope/disk system of the low-mass Class 0 protostar L1527. For that, we have used ALMA observations with a spatial resolution of 0.25$^{\prime\prime}$$\times$0.13$^{\prime\prime}$ and 0.37$^{\prime\prime}$$\times$0.23$^{\prime\prime}$ at 0.8 mm and 1.2 mm, respectively. The L1527 dust continuum emission has a deconvolved size of 78 au $\times$ 21 au, and shows a flared disk-like structure. A thin infalling-rotating envelope is seen in the CCH emission outward of about 150 au, and its thickness is increased by a factor of 2 inward of it. This radius lies between the centrifugal radius (200 au) and the centrifugal barrier of the infalling-rotating envelope (100 au). The gas stagnates in front of the centrifugal barrier and moves toward vertical directions. SO emission is concentrated around and inside the centrifugal barrier. The rotation speed of the SO emitting gas is found to be decelerated around the centrifugal barrier. A part of the angular momentum could be extracted by the gas which moves away from the mid-plane around the centrifugal barrier. If this is the case, the centrifugal barrier would be related to the launching mechanism of low velocity outflows, such as disk winds.

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arXiv2017

L483: Warm Carbon-Chain Chemistry Source Harboring Hot Corino Activity

The Class 0 protostar, L483, has been observed in various molecular lines in the 1.2 mm band at a sub-arcsecond resolution with ALMA. An infalling-rotating envelope is traced by the CS line, while a very compact component with a broad velocity width is observed for the CS, SO, HNCO, NH$_2$CHO, and HCOOCH$_3$ lines. Although this source is regarded as the warm carbon-chain chemistry (WCCC) candidate source at a 1000 au scale, complex organic molecules characteristic of hot corinos such as NH$_2$CHO and HCOOCH$_3$ are detected in the vicinity of the protostar. Thus, both hot corino chemistry and WCCC are seen in L483. Although such a mixed chemical character source has been recognized as an intermediate source in previous single-dish observations, we here report the first spatially-resolved detection. A kinematic structure of the infalling-rotating envelope is roughly explained by a simple ballistic model with the protostellar mass of 0.1--0.2 $M_\odot$ and the radius of the centrifugal barrier (a half of the centrifugal radius) of 30--200 au, assuming the inclination angle of 80\degr\ (0\degr\ for a face-on). The broad line emission observed in the above molecules most likely comes from the disk component inside the centrifugal barrier. Thus, a drastic chemical change is seen around the centrifugal barrier.

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arXiv2016

Discovery of a Hot Corino in the Bok Globule B335

We report the first evidence of a hot corino in a Bok globule. This is based on the ALMA observations in the 1.2 mm band toward the low-mass Class 0 protostar IRAS 19347+0727 in B335. Saturated complex organic molecules (COMs), CH$_3$CHO, HCOOCH$_3$, and NH$_2$CHO, are detected in a compact region within a few 10 au around the protostar. Additionally, CH$_3$OCH$_3$, C$_2$H$_5$OH, C$_2$H$_5$CN, and CH$_3$COCH$_3$ are tentatively detected. Carbon-chain related molecules, CCH and c-C$_3$H$_2$, are also found in this source, whose distributions are extended over a few 100 au scale. On the other hand, sulfur-bearing molecules CS, SO, and SO$_2$, have both compact and extended components. Fractional abundances of the COMs relative to H$_2$ are found to be comparable to those in known hot-corino sources. Though the COMs lines are as broad as 5-8 km s$^{-1}$, they do not show obvious rotation motion in the present observation. Thus, the COMs mainly exist in a structure whose distribution is much smaller than the synthesized beam (0."58 x 0."52).

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arXiv2016

Infalling-Rotating Motion and Associated Chemical Change in the Envelope of IRAS 16293-2422 Source A Studied with ALMA

We have analyzed rotational spectral line emission of OCS, CH3OH, HCOOCH3, and H2CS observed toward the low-mass Class 0 protostellar source IRAS 16293-2422 Source A at a sub-arcsecond resolution (~0".6 x 0".5) with ALMA. Significant chemical differentiation is found at a 50 AU scale. The OCS line is found to well trace the infalling-rotating envelope in this source. On the other hand, the CH3OH and HCOOCH3 distributions are found to be concentrated around the inner part of the infalling-rotating envelope. With a simple ballistic model of the infalling-rotating envelope, the radius of the centrifugal barrier (a half of the centrifugal radius) and the protostellar mass are evaluated from the OCS data to be from 40 to 60 AU and from 0.5 to 1.0 Msun, respectively, assuming the inclination angle of the envelope/disk structure to be 60 degrees (90 degrees for the edge-on configuration). Although the protostellar mass is correlated with the inclination angle, the radius of the centrifugal barrier is not. This is the first indication of the centrifugal barrier of the infalling-rotating envelope in a hot corino source. CH3OH and HCOOCH3 may be liberated from ice mantles due to weak accretion shocks around the centrifugal barrier, and/or due to protostellar heating. The H2CS emission seems to come from the disk component inside the centrifugal barrier in addition to the envelope component. The centrifugal barrier plays a central role not only in the formation of a rotationally-supported disk but also in the chemical evolution from the envelope to the protoplanetary disk.

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