arXiv subjects

Andre C Barato

Publications and source records attributed to Andre C Barato.

9 recordsLinked to original sources

arXiv2022

Second law for active heat engines

Macroscopic cyclic heat engines have been a major motivation for the emergence of thermodynamics. In the last decade, cyclic heat engines that have large fluctuations and operate at finite time were studied within the more modern framework of stochastic thermodynamics. The second law for such heat engines states that the efficiency cannot be larger than the Carnot efficiency. The concept of cyclic active heat engines for a system in the presence of hidden dissipative degrees of freedom, also known as a nonequilibrium or active reservoir, has also been studied in theory and experiment. Such active engines show rather interesting behavior such as an ``efficiency'' larger than the Carnot bound. They are also likely to play an important role in future developments, given the ubiquitous presence of active media. However, a general second law for cyclic active heat engines has been lacking so far. Here, upon using a known inequality in stochastic stochastic thermodynamics for the excess entropy, we obtain a general second law for active heat engines, which does not involve the energy dissipation of the hidden degrees of freedom and is expressed in terms of quantities that can be measured directly from the observable degrees of freedom. Besides heat and work, our second law contains an information-theoretic term, which allows an active heat engine to extract work beyond the limits valid for a passive heat engine. To obtain a second law expressed in terms of observable variables in the presence of hidden degrees of freedom we introduce a coarse-grained excess entropy and prove a fluctuation theorem for this quantity.

cond-mat.stat-mech↗

arXiv2021

Skewness and Kurtosis in Stochastic Thermodynamics

The thermodynamic uncertainty relation is a prominent result in stochastic thermodynamics that provides a bound on the fluctuations of any thermodynamic flux, also known as current, in terms of the average rate of entropy production. Such fluctuations are quantified by the second moment of the probability distribution of the current. The role of higher order standardized moments such as skewness and kurtosis remains largely unexplored. We analyze the skewness and kurtosis associated with the first passage time of thermodynamic currents within the framework of stochastic thermodynamics. We develop a method to evaluate higher order standardized moments associated with the first passage time of any current. For systems with a unicyclic network of states, we conjecture upper and lower bounds on skewness and kurtosis associated with entropy production. These bounds depend on the number of states and the thermodynamic force that drives the system out of equilibrium. We show that these bounds for skewness and kurtosis do not hold for multicyclic networks. We discuss the application of our results to infer an underlying network of states.

cond-mat.stat-mech↗

arXiv2020

Precision and dissipation of a stochastic Turing pattern

Spontaneous pattern formation is a fundamental scientific problem that has received much attention since the seminal theoretical work of Turing on reaction-diffusion systems. In molecular biophysics, this phenomena often takes place under the influence of large fluctuations. It is then natural to inquire about the precision of such pattern. In particular, spontaneous pattern formation is a nonequilibrium phenomenon, and the relation between the precision of a pattern and the thermodynamic cost associated with it remains unexplored. Here, we analyze this relation with a paradigmatic stochastic reaction-diffusion model, the Brusselator in one spatial dimension. We find that the precision of the pattern is maximized for an intermediate thermodynamic cost, i.e., increasing the thermodynamic cost beyond this value makes the pattern less precise. Even though fluctuations get less pronounced with an increase in thermodynamic cost, we argue that larger fluctuations can also have a positive effect on the precision of the pattern.

cond-mat.stat-mech↗

arXiv2019

Oscillations in feedback driven systems: thermodynamics and noise

Oscillations in nonequilibrium noisy systems are important physical phenomena. These oscillations can happen in autonomous biochemical oscillators such as circadian clocks. They can also manifest as subharmonic oscillations in periodically driven systems such as time-crystals. Oscillations in autonomous systems and, to a lesser degree, subharmonic oscillations in periodically driven systems have been both thoroughly investigated, including their relation with thermodynamic cost and noise. We perform a systematic study of oscillations in a third class of nonequilibrium systems: feedback driven systems. In particular, we use the apparatus of stochastic thermodynamics to investigate the role of noise and thermodynamic cost in feedback driven oscillations. For a simple two-state model that displays oscillations, we analyze the relation between precision and dissipation, revealing that oscillations can remain coherent for an indefinite time in a finite system with thermal fluctuations in a limit of diverging thermodynamic cost. We consider oscillations in a more complex system with several degrees of freedom, an Ising model driven by feedback between the magnetization and the external field. This feedback driven system can display subharmonic oscillations similar to the ones observed in time-crystals. We illustrate the second law for feedback driven systems that display oscillations. For the Ising model, the oscillating dissipated heat can be negative. However, when we consider the total entropy that also includes an informational term related to measurements, the oscillating total entropy change is always positive. We also study the finite-size scaling of the dissipated heat, providing evidence for the existence of a first-order phase transition for certain parameter regimes.

cond-mat.stat-mech↗

arXiv2018

Bounds on current fluctuations in periodically driven systems

Small nonequilibrium systems in contact with a heat bath can be analyzed with the framework of stochastic thermodynamics. In such systems, fluctuations, which are not negligible, follow universal relations such as the fluctuation theorem. More recently, it has been found that, for nonequilibrium stationary states, the full spectrum of fluctuations of any thermodynamic current is bounded by the average rate of entropy production and the average current. However, this bound does not apply to periodically driven systems, such as heat engines driven by periodic variation of the temperature and artificial molecular pumps driven by an external protocol. We obtain a universal bound on current fluctuations for periodically driven systems. This bound is a generalization of the known bound for stationary states. In general, the average rate that bounds fluctuations in periodically driven systems is different from the rate of entropy production. We also obtain a local bound on fluctuations that leads to a trade-off relation between speed and precision in periodically driven systems, which constitutes a generalization to periodically driven systems of the so called thermodynamic uncertainty relation. From a technical perspective, our results are obtained with the use of a recently developed theory for 2.5 large deviations for Markov jump processes with time-periodic transition rates.

cond-mat.stat-mech↗

arXiv2018

Current fluctuations in periodically driven systems

Small nonequelibrium systems driven by an external periodic protocol can be described by Markov processes with time-periodic transition rates. In general, current fluctuations in such small systems are large and may play a crucial role. We develop a theoretical formalism to evaluate the rate of such large deviations in periodically driven systems. We show that the scaled cumulant generating function that characterizes current fluctuations is given by a maximal Floquet exponent. Comparing deterministic protocols with stochastic protocols, we show that, with respect to large deviations, systems driven by a stochastic protocol with an infinitely large number of jumps are equivalent to systems driven by deterministic protocols. Our results are illustrated with three case studies: a two-state model for a heat engine, a three-state model for a molecular pump, and a biased random walk with a time-periodic affinity.

cond-mat.stat-mech↗

arXiv2017

Coherence of Biochemical Oscillations is Bounded by Driving Force and Network Topology

Biochemical oscillations are prevalent in living organisms. Systems with a small number of constituents cannot sustain coherent oscillations for an indefinite time because of fluctuations in the period of oscillation. We show that the number of coherent oscillations that quantifies the precision of the oscillator is universally bounded by the thermodynamic force that drives the system out of equilibrium and by the topology of the underlying biochemical network of states. Our results are valid for arbitrary Markov processes, which are commonly used to model biochemical reactions. We apply our results to a model for a single KaiC protein and to an activator-inhibitor model that consists of several molecules. From a mathematical perspective, based on strong numerical evidence, we conjecture a universal constraint relating the imaginary and real parts of the first non-trivial eigenvalue of a stochastic matrix.

cond-mat.stat-mech↗

arXiv2017

Cost and Precision of Brownian Clocks

Brownian clocks are biomolecular networks that can count time. A paradigmatic example are proteins that go through a cycle thus regulating some oscillatory behaviour in a living system. Typically, such a cycle requires free energy often provided by ATP hydrolysis. We investigate the relation between the precision of such a clock and its thermodynamic costs. For clocks driven by a constant thermodynamic force, a given precision requires a minimal cost that diverges as the uncertainty of the clock vanishes. In marked contrast, we show that a clock driven by a periodic variation of an external protocol can achieve arbitrary precision at arbitrarily low cost. This result constitutes a fundamental difference between processes driven by a fixed thermodynamic force and those driven periodically. As a main technical tool, we map a periodically driven system with a deterministic protocol to one subject to an external protocol that changes in stochastic time intervals, which simplifies calculations significantly. In the non-equilibrium steady state of the resulting bipartite Markov process, the uncertainty of the clock can be deduced from the calculable dispersion of a corresponding current.

cond-mat.stat-mech↗

arXiv2016

Critical behavior of entropy production and learning rate: Ising model with an oscillating field

We study the critical behavior of the entropy production of the Ising model subject to a magnetic field that oscillates in time. The mean-field model displays a phase transition that can be either first or second-order, depending on the amplitude of the field and on the frequency of oscillation. Within this approximation the entropy production rate is shown to have a discontinuity when the transition is first-order and to be continuous, with a jump in its first derivative, if the transition is second-order. In two dimensions, we find with numerical simulations that the critical behavior of the entropy production rate is the same, independent of the frequency and amplitude of the field. Its first derivative has a logarithmic divergence at the critical point. This result is in agreement with the lack of a first-order phase transition in two dimensions. We analyze a model with a field that changes at stochastic time-intervals between two values. This model allows for an informational theoretic interpretation, with the system as a sensor that follows the external field. We calculate numerically a lower bound on the learning rate, which quantifies how much information the system obtains about the field. Its first derivative with respect to temperature is found to have a jump at the critical point.

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