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Andrea Banzatti

Publications and source records attributed to Andrea Banzatti.

At least 19 recordsLinked to original sources

Around the water snowline: I. Effects of dynamical and chemical interplay on mid-infrared water spectra of protoplanetary discs

Protoplanetary discs' infrared water spectra (e.g. as observed by JWST) encode information about the underlying water distribution and physical conditions. In this work, we examine and quantify the imprint of various dynamical processes (operating alone or in unison) on water abundances and emerging spectra using a new 2D model called Molecular emission Affected by Gas, Pebble, and Ice Evolution (MAGPIE). This model combines diffusion and advection for water (and associated species) and dust grains with aerodynamically decoupled pebbles, and photodissociation and a gas-phase water formation prescription. In general, we find that transport processes have a major impact on the inner disc's water content and can (re)plenish the layer above the ice reservoir which in static models is water-poor due to photodissociation. In particular, adding diffusion to a chemical model can result in strong changes in the spectrum (e.g. a flux increases of colder compared to warmer water lines) that recent work has associated with pebble drift. Adding pebble drift dramatically increases the inner disc water abundance but, surprisingly, does not readily lead to a further increase of cold water tracers as (1) efficient outward transport of water vapour is inhibited by a conveyor belt effect of incoming pebbles, and (2) the increase in hot water line fluxes overshadows smaller increases of colder lines. We conclude that dynamical processes have a significant but complex impact on water spectra. Future work should explore a range in stellar (e.g. UV irradiation) and disc properties to comprehensively understand the observed diversity of water emission.

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The JDISC Survey: Inner Disk Chemistry of Class I/FS Disks and Tentative Evidence for Early Pebble Drift

We present the first chemical survey of Class I and Flat-Spectrum (I/FS) disks using JWST MIRI/MRS, targeting sixteen sources in the Ophiuchus star-forming region. Through empirical line luminosity measurements and multi-component slab modeling, we characterize the molecular reservoir of these young systems and compare them to twelve Class II disks of similar stellar mass. Water, HCN, C$_2$H$_2$, and CO$_2$ are frequently detected in I/FS sources with inclinations $i < 70^{\circ}$, whereas edge-on systems show significantly suppressed emission. Compared to Class II disks, I/FS sources show suggestive---though not yet statistically significant---evidence for elevated cold water ($\sim$200\,K) mass and lower CO$_2$ excitation temperatures. Statistical analyses identify accretion luminosity as the primary correlate of molecular mass across both evolutionary stages. Once this dependence is removed, cold water and CO$_2$ masses anti-correlate with mm-dust disk radius, while hot water remains insensitive to disk size. These patterns are qualitatively consistent with pebble drift models that predict early water enrichment followed by delayed CO$_2$ delivery, suggesting an evolutionary progression from molecular-poor Class 0 sources, through water-rich Class I/FS disks, to Class II disks with reduced cold water excess. This work provides an initial evolutionary framework for disk chemistry that requires larger, multi-region samples to confirm.

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Chemical Divergence and Water Depletion: Gas Properties of Evolved Upper Scorpius Disks Revealed by JWST/MIRI

Tracing the chemical evolution of protoplanetary disks over time requires observations of disks at different ages. However, most JWST/MIRI surveys published to date have targeted younger ($\sim$1-3 Myr) rather than older systems. We present the results of a JWST/MIRI MRS survey of the inner regions of 10 protoplanetary disks (ages $\sim$2-6 Myr, spectral types M0-M4.5) in the Upper Scorpius region previously characterized by the ALMA AGE-PRO large program. Using MCMC slab modeling, we fit to a wide variety of detected molecules, including H$_2$O, CO, C$_2$H$_2$, $^{13}$CCH$_2$, HCN, HC$_3$N, CO$_2$, $^{13}$CO$_2$, C$_2$H$_6$, C$_4$H$_2$, and OH, as well as C$_6$H$_6$, CH$_3$, and H$_2$ visually. We classify each disk along two independent axes-a Water Classification based on H$_2$O line luminosity (Water-Rich, Water-Poor, or Water-Absent) and a Chemotype based on the dominant non-water chemistry (Organic-Rich, CO$_2$-Dominated, or Molecule-Absent)-and find an unexpectedly high diversity of distinct chemical compositions within our population. We leverage the heterogeneity of detected molecules in our sample to present new characteristic "diagnostic" wavelength regions for most species. We find that carbon-based molecules consistently exhibit markedly lower excitation temperatures ($\lesssim$300 K) compared to younger ($\sim$1-3 Myr) star-forming regions ($\sim$600-1000 K), hinting at relatively colder molecular reservoirs. We also determine that Upper Scorpius disks show systematically lower water luminosities by factors of 10-1000. In particular, disks with strong carbon-based molecular features but no observed H$_2$O defy expectations of an inner-disk dust cavity or a low ($\lesssim3$) $R_{\rm gas}/R_{\rm dust}$ ratio, instead suggesting that the presence of a strong outer-disk dust trap largely controls the chemical outcome of the terrestrial planet-forming region.

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From Young to Older Disks: JWST/MIRI Evidence for Fading Molecular Emission and Hints for Elevated C/O in Upper Scorpius

We present JWST/MIRI spectroscopy of 14 disks in the older (~5-10 Myr) Upper Scorpius (USco) association and use slab of gas in local thermal equilibrium to infer basic gas properties. We find that half of these disks are molecular rich, with detections of H$_2$O, CO$_2$, HCN, C$_2$H$_2$, and H$_2$, while the other half are molecular poor, showing no molecular emission other than H$_2$. We further combine this sample with 10 other USco disks from the AGE-PRO program and compare the combined older sample to young (~1-3 Myr) JDISCS Cycle~1 systems, which are analyzed in a similar manner. We find that USco disks have lower detection rates of major molecular species but a significantly higher detection rate of rarer C-bearing molecules such as C$_4$H$_2$. At a given accretion luminosity, molecular line luminosities are systematically lower in USco than in young disks, and the scaling relations with accretion luminosity differ between the two populations. Moreover, we find that about half of the older disks, preferentially the millimeter faint, and likely more compact disks, have observable mass ratios of C- to O-bearing molecules that are higher than the maximum values in the young sample. These results point to reduced inner-disk molecular gas masses, cooler emitting layers, and higher inner gas C/O ratios in older disks, the latter being consistent with pebble drift. Taken together, our findings provide evidence for chemical evolution of inner disk gas from young to older systems, with important implications for the accretion of primordial planetary atmospheres.

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Molecular Similarity and Water Diversity in Coeval Binary Disks: JWST/MIRI Observations of Sz 65 and Sz 66

We present JWST/MIRI Medium Resolution Spectrometer spectra of the wide-separation (projected separation $= 980$ au) binary protoplanetary disks Sz 65 (K7; $0.68~M_{\odot}$) and Sz 66 (M3; $0.30~M_{\odot}$), reduced using the uniform pipeline of the JWST Disk Infrared Spectral Chemistry Survey. Both disks show rich molecular emission, including H$_2$O, CO$_2$, HCN, C$_2$H$_2$, and OH. The scaled spectra of the two disks exhibit remarkably similar H$_2$O, CO$_2$, and HCN line emission in the 13--18 $μ$m region, with the only notable difference being stronger C$_2$H$_2$ emission in the primary (Sz 65). Beyond 18 $μ$m, the difference in H$_2$O line emission between the two disks increases. Both the flux ratios and the slab-model-derived mass ratios of cold to hot H$_2$O ($\sim$200 K to $\sim$750 K) and warm to hot H$_2$O ($\sim$450 K to $\sim$750 K) are significantly higher in the secondary (Sz 66). Because binary stars share nearly the same age and metallicity, and as both disks appear compact in millimeter emission ($<30$ au), we suggest that the excess cold H$_2$O in the secondary is best explained by its unstructured dust disk, in contrast to the primary, which shows gaps at 6 and 20 au. The enhanced cold water in the secondary is consistent with efficient pebble drift across the water snow line and increased H$_2$O vapor from the sublimation of icy mantles. Our results demonstrate that wide-separation binaries can serve as powerful control samples for isolating the impact of individual disk properties on inner-disk chemistry and evolution.

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Evidence for Systematically Larger Dust Grains in Upper Scorpius Relative to Taurus Disks

Infrared spectroscopy provides a powerful diagnostic for probing the mineralogical properties of dust grains in the terrestrial planet-forming regions of protoplanetary disks. The Upper Scorpius association offers an excellent laboratory for studying disk evolution because it represents an evolved stage (5-10 Myr) compared with younger star-forming regions such as the Taurus Molecular Cloud (1-3 Myr). In this work, we present mid-infrared spectra of 11 disks in Upper Scorpius that were obtained with the Mid-Infrared Instrument aboard the James Webb Space Telescope. We derive emission feature indices for crystalline olivine and pyroxene centered at about 9.2 micron and 11.1 micron, as well as perform spectral decomposition to quantify dust crystallinity and characteristic grain size. These results are compared with those measured from Spitzer/IRS spectra of 31 disks in Taurus with similar stellar types. We find no significant difference in dust crystallinity between the two groups, suggesting that crystallization is largely established at early stages of disk evolution. Our analysis indicates that the average grain size in Upper Scorpius disks is systematically larger than that in Taurus disks, aligning with theories of dust evolution. We also observe a trend of increasing grain size towards later-type stars, as well as a correlation between crystallinity, grain size and the flux ratio F24/F8, which serves as a measure of dust settling. These results suggest that dust processing proceeds in tandem with disk evolution.

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JWST-DECO: The Impact of Accretion on Mid-Infrared Observable Water in Planet-forming Disks

The inner few au of a protoplanetary disk hosts the majority of observed exoplanets and is the primary planet-forming zone of the disk. The mid-IR spectra of disks, with its rich forest of water lines, provides key insights into the composition of forming planets. One of the strongest trends seen with data from Spitzer and now JWST is a correlation between the increase in water line flux and accretion luminosity of a system. We set out to reproduce and understand this trend by adding an accretion module to the thermo-chemical code DALI, and explore how viscous accretion heating and the addition of accretion luminosity impacts the 2D temperature structure and the observable water reservoir. We reproduce the trend that the observed water mass increases with accretion rate, with hot, warm, and cool water being more to less strongly correlated, respectively. Our model suggests that these trends are due to an increased emitting area with accretion rate, with some of the cool and warm population becoming hidden underneath an optically thick dust surface and being constrained to a smaller disk volume. This trend is driven by the accretion-related increase in central luminosity, while viscous heating centralized to the midplane has no impact on observed water mass.

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Characterizing the Extended Molecular Hydrogen Winds in Protoplanetary Disks from the JWST Disk Infrared Spectroscopic Chemistry Survey

We present a comprehensive analysis of extended H$_2$ emission from 34 protoplanetary disks observed with the JWST Disk Infrared Spectroscopic Chemistry Survey (JDISCS), supplemented by archival data. We investigated the morphology, kinematics, excitation conditions, and mass dynamics of H$_2$. Extended emission from pure rotational H$_2$ lines is found to be common, with 16 sources exhibiting clear signatures of disk winds. These include monopolar and bipolar structures in inclined disks and ring-like or bubble-like morphologies in face-on systems features indicative of wide-angle disk winds. Our analysis shows that the H$_2$ is consistent with slow {(4.2$^{+6.7}_{-3.0}$ km s$^{-1}$)} MHD driven winds. For ten disks, we model the wind morphology and find a median half-opening angle of $45\arcdeg^{+5}_{-4}$ and a characteristic power-law index of $α\sim$ 1.6. Excitation analysis yields a median gas temperature of 624 $\pm$ 130 K and a column density of $\log(N_{\mathrm{tot}}\,[\mathrm{cm}^{-2}]) = 18.6 \pm 0.6$. The median wind mass-loss rate, ${\rm log_{10}}(\dot{\rm M}_{\rm wind}^{\rm tot}) = -9_{-0.4}^{+0.8}\,{\rm M_\odot\,yr^{-1}}$, implies that, if molecular winds are the dominant mechanism responsible for disk dispersal, a typical disk with a mass of $2-3\,M_{\rm Jup}$ would dissipate on a $\sim$2-3 Myr timescale, consistent with observed disk lifetimes. The $\dot{\rm M}_{\mathrm{\rm wind}}^{\rm tot}$ span a relatively narrow range ($\sim$2 dex) and do not correlate strongly with accretion rates onto the star, suggesting that the mass loss rate and the accretion rates are probing different timescales. Our findings demonstrate that spatially extended warm H$_2$ emission is a widespread and reliable tracer of molecular disk winds in protoplanetary systems.

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How leaky? A large parameter study of leaky dust traps to quantify the transport of pebbles and ice in protoplanetary discs

In protoplanetary discs, the presence of dust traps can significantly alter the transport of solids from the outer to the inner regions, and hence they are often invoked as an explanation for the chemical diversity of inner discs observed with JWST (e.g., varying oxygen abundances and C/O ratios). As a detailed treatment of dust transport around dust traps is computationally expensive, earlier works investigating the impact of outer traps on the inner disc composition have often used simplified dust models representing the size distribution with a single effective size and drift speed. In this paper, we revisit the impact of outer traps on dust transport using the state-of-the-art one-dimensional dust evolution code \texttt{DustPy}, which simulates the transport and evolution of dust particles including detailed coagulation and fragmentation. We quantify and map the leakiness of dust traps across a broad parameter space, performing over 300 simulations while varying the disc viscosity, turbulence strength, planet mass and location, and dust fragmentation velocity. We find that dust traps are leakier than previously thought, on a broader parameter space, such that most outer traps (r > 5 au) will result in a long-lived O-rich inner disc with gas-phase C/O < 1. In similar conditions (e.g., carved by the same planet mass), we find inner traps are much leakier than outer traps, though their relative efficiency in reducing the pebble flux is time-dependent. Highly blocking traps altering the inner disc composition dramatically (leading, e.g., to C/O > 1) are possible to set up but necessitate low viscosity and weak turbulence, along with efficient planetesimal formation by the streaming instability. In that case, we find that is the formation of planetesimals, rather than the dust traps themselves, that is capable of significantly altering the inner disc composition.

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H$_2^{18}$O in the terrestrial planet-forming regions of protoplanetary disks

Isotopologues play an important role in solar system cosmochemistry studies, revealing details of early planet formation physics and chemistry. Oxygen isotopes, as measured in solar system materials, reveal evidence for both mass-dependent fractionation processes and a mass-independent process commonly attributed to isotope-selective photodissociation of CO in the solar nebula. The sensitivity of JWST's MIRI-MRS enables studies of isotopologues in the terrestrial planet-forming regions around nearby young stars. We report here on a search for H$_2^{18}$O in 22 disks from the JDISC Survey with evidence for substantial water vapor reservoirs, with the goal of measuring H$_2^{16}$O/H$_2^{18}$O ratios, and potentially revealing the predicted enhancement of H$_2^{18}$O caused by isotope-selective photodissociation. We find marginal detections of H$_2^{18}$O in six disks, and a more significant detection of H$_2^{18}$O in the disk around WSB 52. Modeling of the detected H$_2^{18}$O lines assuming an ISM ratio of H$_2^{16}$O/H$_2^{18}$O predicts H$_2^{18}$O features consistent with observations for four of the modeled disks, but stronger H$_2^{18}$O features than are observed in three of the modeled disks, which includes WSB 52. Therefore, these latter three disks require a higher H$_2^{16}$O/H$_2^{18}$O ratio than the ISM in the water-emitting region, in contrast to long-standing theoretical expectations. We suggest that either the H$_2^{18}$O-rich water has been removed from the emitting region and replaced by H$_2^{18}$O-poor water formed by reactions with $^{18}$O-poor CO, or that the gas-phase water is depleted in $^{18}$O via mass-dependent fractionation processes at the water snowline.

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Protoplanetary disk cavities with JWST-MIRI: a dichotomy in molecular emission

The evolution of planet-forming regions in protoplanetary disks is of fundamental importance to understanding planet formation. Disks with a central deficit in dust emission, a "cavity", have long attracted interest as potential evidence for advanced disk clearing by protoplanets and/or winds. Before JWST, infrared spectra showed that these disks typically lack the strong molecular emission observed in full disks. In this work, we combine a sample of 12 disks with millimeter cavities of a range of sizes ($\sim2$-70 au) and different levels of millimeter and infrared continuum deficits. We analyze their molecular spectra as observed with MIRI on JWST, homogeneously reduced with the new JDISCS pipeline. This analysis demonstrates a stark dichotomy in molecular emission where "molecule-rich" (MR) cavities follow global trends between water, CO, and OH luminosity and accretion luminosity as in full disks, while "molecule-poor" (MP) cavities are significantly sub-luminous in all molecules except sometimes OH. Disk cavities generally show sub-luminous organic emission, higher OH/H$_2$O ratios, and suggest a lower water column density. The sub-thermal excitation of CO and water vibrational lines suggests a decreased gas density in the emitting layer in all cavities, supporting model expectations for C$_2$H$_2$ photodissociation. We discover a bifurcation in infrared index (lower in MR cavities) suggesting that the molecular dichotomy is linked to residual $μ$m-size dust within millimeter disk cavities. Put together, these results suggest a feedback process between dust depletion, gas density decrease, and molecule dissociation. Disk cavities may have a common evolutionary sequence where MR switch into MP over time.

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Coordinated Space- and Ground-based Monitoring of Accretion Bursts in a Protoplanetary Disk: The Orbital and Accretion Properties of DQ Tau

Multiplicity in pre-main-sequence (PMS) systems shapes circumstellar and circumbinary disks, often producing features such as inner cavities, spiral arms, and gas streamers that facilitate mass transfer between the disk and stars. Consequently, accretion in eccentric close binaries is highly variable and synchronized with their orbits, producing bursts near periastron passages. In this study, we examine the orbital and accretion properties of the eccentric Classical T-Tauri binary DQ Tau using medium- to high-resolution spectroscopy from the Very Large Telescope (VLT) X-Shooter and UVES instruments. The data were taken during a monitoring of inner disk chemistry with JWST, and our analysis is needed for correct interpretation of JWST data. We refine the orbital parameters and report an increment in the argument of periastron of 30 degrees. This apsidal motion may be caused by the massive disk acting as a third body. We also explore the possibility that it is due to a still undetected additional (sub-)stellar companion, estimating a lower limit of 15 MJ for its mass at the cavity edge (a=3 abin). We investigate accretion of the primary and secondary using the Ca II 849.8 nm emission line. The primary accretes more at periastron than in previous quiescent phases, while the secondary dominates post-periastron. Additionally, we report elevated Lacc at apastron, possibly due to interaction with irregularly shaped structures near the closest approach to the circumbinary disk. Finally, we derive each star's accretion luminosity across disentangled epochs and compare it to UV-excess-based results, finding good agreement. The individual Lacc values can be used as input for chemical models.

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Variability of the DG Tau Forbidden Emission Line Low Velocity Component

Optical Forbidden Emission Lines (FELs) come from transitions with long radiative decay times needing low density gas where collisions between atoms are rare. They are produced in the outflows driven by young stellar objects. These lines trace distinct velocity components, including a Low Velocity Component (LVC), which may be tracing a magneto hydrodynamic (MHD) or photoevaporative (PE) wind. We study the jet and LVC of the star DG Tau, whose jet velocity has decreased since 2006. We aim to investigate a link between the high velocity jet and the LVC and clarify the LVC origin as an MHD or PE wind by studying spectral \& spatial changes over time. Using kinematic fitting \& spectro-astrometry, we analyse three epochs of spectra spanning ~18 years. A ~100 km/s decrease in velocity from 2003 to 2021 aligns with known slowing of the jet. Fitting of the [O I] λ6300, [O I] λ5577, and [S II] λ6731 lines reveal complex FEL profiles, with up to six blue-shifted components and a redshifted wing, in agreement with Chou et al. (2025). We see three LVC sub-components (LVC-H, LVC-M, and LVC-L) that are consistent with entrained jet material, disk wind, and dense upper disk atmosphere respectively. While jet components vary in time, the LVC remains quite stable, with changes in the relative brightness of each sub-component. The results cannot distinguish between a MHD or PE wind origin for the LVC. A limit of less than 2 au is put on the de projected height of the LVC-M in [O I] λ5577, where there is no jet contribution. This supports a disk wind and may favor an MHD wind origin. The near constant peak velocity of LVC-M needs further study in context of a shared origin for jets and MHD winds. Future work needs observations with higher spectral resolution and time cadence to resolve blended components and examine a possible time lag between changes in the jet and LVC.

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Cosmic cascades: How disk substructure regulates the flow of water to inner planetary systems

The influx of icy pebbles to the inner regions of protoplanetary disks constitutes a fundamental ingredient in most planet formation theories. The observational determination of the magnitude of this pebble flux and its dependence on disk substructure (disk gaps as pebble traps) would be a significant step forward. In this work we analyze a sample of 21 T Tauri disks (with ages $\approx 0.5{-}2\mathrm{~Myr}$) using JWST/MIRI spectra homogeneously reduced with the JDISCS pipeline and high-angular-resolution ALMA continuum data. We find that the 1500/6000 K water line flux ratio measured with JWST - a tracer of cold water vapor and pebble drift near the snowline - correlates with the radial location of the innermost dust gap in ALMA continuum observations (ranging from 8.7 to 69 au), confirming predictions from recent models that study connections between the inner and outer disk reservoirs. We develop a population synthesis exploration of pebble drift in gapped disks and find a good match to the observed trend for early and relatively effective gaps, while scenarios where pebble drift happens quickly, gaps are very leaky, or where gaps form late are disfavored on a population level. Inferred snowline pebble mass fluxes (ranging between $10^{-6}$ and $10^{-3}~M_\oplus/\mathrm{yr}$ depending on gap position) are comparable to fluxes used in pebble accretion studies and those proposed for the inner Solar System, while system-to-system variations suggest differences in the emerging planetary system architectures and water budgets.

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MINDS. Young binary systems with JWST/MIRI: Variable water-rich primaries and extended emission

As part of the JWST GTO program MINDS, we analyze the mid-infrared emission of three Class II binary systems: VW Cha, WX Cha, and RW Aur, to investigate the impact of stellar multiplicity on the chemistry and physics of their inner disk. We analyze the 1D spectrum from JWST/MIRI-MRS for primary and secondary disks separately, extracted by combining forward modeling with a theoretical PSF and aperture photometry. We modeled the molecular lines with 0D slab models. We interpret the results by comparing our JWST spectra to VLT/CRIRES+, Spitzer/IRS, and ALMA. Primary and secondary disks are dramatically different in their mid-infrared emission, with primary disks showing H2O-rich spectra, and secondary disks being mostly line poor to the sensitivity of our spectra. When comparing MIRI-MRS to Spitzer/IRS, we observe large variability in the line emission of VW Cha A, as well as in the continuum of RW Aur A. The disks around VW Cha BC and RW Aur B show evidence of ionizing radiation, and a further comparison with ALMA at high angular resolution dust continuum suggest that the spectrum of RW Aur B is well explained by its ~4 au cavity. All the systems show [Ne II] jet emission, and three of them also show spatially resolved emission structures in H2, likely originated by outflows and dynamical interactions. Many of the observed features in the primary disks, such as enhanced water emission, could be linked to the increased accretion and radial drift produced by dynamical disk truncation. However, additional mechanisms are needed to explain the large differences between primary and secondary disks, potentially inner disk substructures. This work is an example of the need for combining multiple facilities to fully understand the observations from JWST.

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The JDISC Survey: Linking the Physics and Chemistry of Inner and Outer Protoplanetary Disk Zones

Mid-infrared spectroscopy of protoplanetary disks provides a chemical inventory of gas within a few au, where planets are readily detected around older stars. With the JWST Disk Infrared Spectral Chemistry Survey (JDISCS), we explore demographic trends among 31 disks observed with MIRI (MRS) and with previous ALMA millimeter continuum imaging at high angular resolution (5-10 au). With these S/N $\sim$200-450 spectra, we report emission from H$_2$O, OH, CO, C$_2$H$_2$, HCN, CO$_2$, [Ne II], [Ne III], and [Ar II]. Emission from H$_2$O, OH and CO is nearly ubiquitous for low-mass stars, and detection rates of all molecules are higher than for similar disks observed with Spitzer-IRS. Slab model fits to the molecular emission lines demonstrate that emission from C$_2$H$_2$, HCN, and possibly CO$_2$ is optically thin; thus since column densities and emitting radii are degenerate, observations are actually sensitive to the total molecular mass. C$_2$H$_2$ and HCN emission also typically originate in a hotter region ($920^{+70}_{-130}$, $820^{+70}_{-130}$ K, respectively) than CO$_2$ ($600^{+200}_{-160}$ K). The HCN to cold H$_2$O luminosity ratios are generally smaller in smooth disks, consistent with more efficient water delivery via icy pebbles in the absence of large dust substructures. The molecular emission line luminosities are also correlated with mass accretion rates and infrared spectral indices, similar to trends reported from Spitzer-IRS surveys. This work demonstrates the power of combining multi-wavelength observations to explore inner disk chemistry as a function of outer disk and stellar properties, which will continue to grow as the sample of observed Class II systems expands in the coming JWST observation cycles.

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JWST's sharper view of EX Lup: cold water from ice sublimation during accretion outbursts

The unstable accretion phases during pre-main-sequence evolution of T Tauri stars produce variable irradiation and heating of planet-forming regions. A strong accretion outburst was observed with Spitzer-IRS in 2008 in EX Lup, the prototype of EXor variables, and found to increase the mid-infrared water and OH emission and decrease organic emission, suggesting large chemical changes. We present here two JWST-MIRI epochs of quiescent EX Lup in 2022 and 2023 obtained over a decade after the 2008 outburst and several months after a moderate burst in 2022. With JWST's sharper spectral view, we can now analyze water emission as a function of temperature in the two MIRI epochs and, approximately, also in the previous Spitzer epochs. This new analysis shows a strong cold water vapor ``burst" in low-energy lines during the 2008 outburst, which we consider clear evidence for enhanced ice sublimation due to a recession of the snowline, as found in protostellar envelopes. JWST shows that EX Lup still has an unusually strong emission from cold water in comparison to other T Tauri disks, suggesting > 10-yr-long freeze-out timescales in the inner disk surface. EX Lup demonstrates that outbursts can significantly change the observed organic-to-water ratios and increase the cold water reservoir, providing chemical signatures to study the recent accretion history of disks. This study provides an unprecedented demonstration of the chemical evolution triggered by accretion outbursts in the Class II phase and of the high potential of time-domain experiments to reveal processes that may have fundamental implications on planet-forming bodies near the snowline.

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Coordinated Space and Ground-Based Monitoring of Accretion Bursts in a Protoplanetary Disk: Establishing Mid-Infrared Hydrogen Lines as Accretion Diagnostics for JWST-MIRI

In this paper, we establish and calibrate mid-infrared hydrogen recombination lines observed with JWST as accretion tracers for pre-main-sequence stars that accrete from circumstellar disks. This work is part of a coordinated, multi-observatory effort that monitored the well-known binary system DQ Tau over three orbital periods, capturing its periodic accretion bursts. In this first paper, we present 9 epochs of MIRI-MRS spectra with near-simultaneous LCO photometry and VLT X-Shooter spectroscopy. This program caught exceptional accretion variability, spanning almost two orders of magnitude between the peak of the first periastron accretion burst and the following quiescent phases. The MIRI spectra show H I line luminosities that vary in step with the accretion-luminosity time series measured with LCO and X-Shooter. The tight correlation with accretion and the large line widths, which MIRI resolves for the first time, support an accretion-flow origin for mid-infrared H I transitions. Combining these three exceptional datasets, we derive accurate relations between mid-infrared line and accretion luminosities for three H I transitions (10-7, 7-6, 8-7), and improve upon a previous relation based on Spitzer spectra. These new relations equip the community with a direct measurement of the accretion luminosity from MIRI-MRS spectra. A MIRI-derived accretion luminosity is fundamental for time-domain chemistry studies, as well as for studies of accretion in embedded/distant sources that are currently inaccessible in the optical. With these new relations, we provide accretion luminosities for an archival sample of 38 MRS spectra of protoplanetary disks published to date.

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