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Andrea Marchetti

Publications and source records attributed to Andrea Marchetti.

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Emergence of information interference in stochastic systems with non-diagonal noise and switching environments

Stochastic forces in natural systems are rarely isotropic. From hydrodynamically coupled colloids to chemical reaction networks, noise contributions are inherently correlated. Together with internal interactions and changing environments, they shape the dependencies between the degrees of freedom of real-world systems, as quantified by their mutual information. In this work, we focus on linearized stochastic systems with both non-diagonal noise matrices and stochastically switching environments. We study how their presence leads to the emergence of information interference, so that the total mutual information cannot be decomposed as the sum of the contributions from deterministic interactions, noise anisotropy, and environmental switching alone. We identify two distinct sources of information interference: a static term, arising from the simultaneous presence of deterministic coupling and noise anisotropy; and a dynamic term, emerging from the interplay between internal processes and environmental switches. We then apply this framework to different physical systems. In the presence of switching temperatures, the mutual information disentangles exactly into internal and environmental contributions. When the noise anisotropy arises instead from hydrodynamic interactions, we find that the presence of a shared fluid can either mask or enhance the information stemming from a non-conservative force depending on its degree of non-reciprocity. Finally, in a fuel-driven chemical reaction network, we show that information interference is controlled by the non-equilibrium driving. These results establish a general information-theoretic perspective on how anisotropic noise and environmental variability shape statistical dependencies in stochastic systems.

cond-mat.stat-mech

Rate-Dependent Reversibility and Lithium Losses in Hybrid Anode-Collector Metal Electrodes

Understanding how practical lithium storage capacity varies with charge-discharge rate is crucial for designing durable anode free lithium batteries. We examine the lithiation behavior of single element metal electrodes-Al (alloying), Mg (solid solution intercalation), Ag (solid solution then alloying), and Cu (surface Li plating)-to determine how their mechanisms influence reversibility, measured by coulombic efficiency. Using electrochemistry combined with depth resolved ion beam profiling, we map local coulombic efficiency across current densities and identify dominant lithium loss pathways. Ag uniquely sustains fast kinetics and high reversibility at elevated rates due to rapid formation of gamma brass-type alloy phases. In contrast, Mg and Al show increasing irreversibility from kinetically or structurally driven Li trapping, while Cu exhibits the largest losses through porous, highly reactive plated lithium. These results reveal fundamental limits of anode free systems that depend on reversible Li plating without excess lithium and underscore the importance of metal selection for stable, high rate performance.

cond-mat.mtrl-sci

Directionality measures in evolutionary ecological networks: Insights from the Tangled Nature model

The myriad microscopic interactions among the individual organisms that constitute an ecological system collectively give rise, at the macroscopic scale, to evolutionary trends. The ability to detect the directionality of such trends is crucial for understanding and managing the dynamics of natural systems. Nevertheless, identifying the key observable quantities that capture such directional behaviour poses a major challenge. In this study, we propose that translating ecological data into a network framework is a valuable strategy to measure system stability and evolution. We examine the Tangled Nature model as a test case, evaluating network entropy, species diversity, and the clustering coefficient as metrics of network stability and directionality.

q-bio.PE

The Electrochemical Transistor: a device based on the Electrochemical control of a polymer Polaronic state. The PCPDT-BT as a case study

This work presents an original concept directed to implement an unconventional methodology where a device is produced by integrating a solid-state circuitry concept and an electrochemistry cell. In our experimental system an organic semiconductor, (PCPDT-BT), serves both as the gate and working electrode. Gating is obtained via electrochemical polarization exploiting a conventional three electrodes electrochemical cell placed on top of a traditional source/drain/gate solid-state device configuration. Source/drain conduction is probed via impedance measurement (electrochemical impedance spectroscopy, EIS) performed as a function of time at constant frequency, under constant potential control. The conductivity of the PCPDT-BT is due to the polaronic state induced via application of a suitable electrochemical potential (in the oxidation regime), as it is proved by infrared (IR) spectra recorded in-situ/in-operando (in attenuated under total reflection, ATR, mode) upon both electrochemical and chemical ionization/doping of the PCPDT-BT.

physics.app-ph

Spotting the diffusion of New Psychoactive Substances over the Internet

Online availability and diffusion of New Psychoactive Substances (NPS) represent an emerging threat to healthcare systems. In this work, we analyse drugs forums, online shops, and Twitter. By mining the data from these sources, it is possible to understand the dynamics of drugs diffusion and their endorsement, as well as timely detecting new substances. We propose a set of visual analytics tools to support analysts in tackling NPS spreading and provide a better insight about drugs market and analysis.

cs.CY