SearcharxivSearch

arXiv subjects

Andreas Jossen

Publications and source records attributed to Andreas Jossen.

8 recordsLinked to original sources

From Laboratory Aging Studies to Field Predictions: Quantifying Uncertainty in Battery Storage Lifetime Predictions

Predicting how long a battery energy storage system will last is critical for warranty design, maintenance planning and investment decisions, yet degradation models are mostly deterministic and rarely validated against real field data. We apply an open-source probabilistic degradation framework, combined with a cell-to-system approximation, to bridge the gap between cell-level laboratory aging models and system-level field predictions for residential battery energy storage systems with quantified uncertainty. The framework predicts cell-level state-of-health to within 0.4 % mean absolute error, roughly half the error of prior models for this dataset. When applied to field operation data, the framework's predictions are consistent with all three available system-level capacity measurements - a benchmark rarely available for open probabilistic degradation models. Cell-level heterogeneity is approximated by two bounding stress scenarios differing only slightly (a 5 % spread in temperature and a 9 % spread in current). The mean degradation trajectories of the two scenarios reach end-of-life 10 months apart, while the full predicted end-of-life range across both scenarios spans approximately three years, about a third of the expected system lifetime. We link this uncertainty to two drivers. One is a systematic mismatch between laboratory test conditions and field-representative operating stress. The other is variability in the training data itself. These insights translate into concrete, resource-efficient recommendations for future aging study design, supporting more confident predictions of battery lifetime under real-world conditions.

eess.SY

Estimating the Health and State of Charge of Each Cell in a Second-Life Battery System from Field Data

Effective use of battery storage depends on reliable estimation of its state of health (SOH) and state of charge (SOC). Model-based state estimation requires the open-circuit voltage (OCV) curve, which is typically unknown for second-life batteries. We present a framework that jointly estimates the states and parameters of an equivalent circuit model solely from field operation data, using Gaussian process regression to reconstruct the OCV curve. Applied to a real second-life battery system of 27 modules and 324 cells, it reveals SOH heterogeneity, a systematic SOC imbalance, and two faulty cells, all validated against a reference measurement. We aggregate the cell SOH and SOC to module level and benchmark them against a lumped-module model fitted without the individual cell voltages. The lumped-module model follows the average behavior and cannot capture the limiting cells, overestimating SOH by up to 31% and SOC by up to 23%.

eess.SY

Predicting BESS Degradation with Uncertainty Quantification: A Probabilistic Framework for Battery Energy Storage Systems

Accurate and uncertainty-aware prediction of battery degradation is essential for the reliable operation and lifecycle management of energy storage systems, yet traditional deterministic models fail to capture the inherent uncertainty in degradation processes. This study introduces a framework for probabilistic battery state-of-health prediction. The framework leverages deep learning models to generate predictive distributions for capacity loss, conditioned on stress factors. Uncertainty is propagated through stochastic degradation trajectories, enabling robust predictions even under dynamic operating conditions. A key advancement is the framework's scalability to full-system data: by integrating cell-level predictions with system topology and real-world operational variability, it provides probabilistic estimates for entire battery energy storage systems. The approach is tested using multi-year field data from residential storage systems, demonstrating its ability to mimic system-level degradation behavior. The framework predicts SOH degradation with 95\% prediction intervals that align well with remaining capacity measurements performed on the field system. This work bridges the gap between laboratory test derived battery cell aging models and full-system operational data evaluation for degradation estimation, offering a practical tool for data-driven asset management in modern energy systems.

eess.SY

Physics-based modeling of cyclic and calendar aging of LIBs with Si-Gr composite anodes

Higher energy density and longer lifetime are the requirements for next-generation lithium-ion batteries. A promising anode material is silicon, which offers high specific capacity, but its significant volume change during lithiation and delithiation enormously reduces battery lifetime. A physical understanding of the processes degrading the battery is key to mitigate this effect and advance in the field. We develop a physics-based model to describe degradation during battery cycling under various protocols and storage conditions, with varying check-up (CU) frequencies. The model can disentangle basic degradation mechanisms, such as the growth of the Solid-Electrolyte Interphase (SEI), from silicon mechanisms, such as particle cracking, SEI growth on cracks, and loss of active material (LAM). We investigate the impact of CUs on the observed storage degradation and the reason behind the increased degradation in batteries, including silicon in the anode. Additionally, we relate the observed degradation to operating conditions, enabling future optimization of battery use and design.

physics.chem-ph

Accounting for Subsystem Aging Variability in Battery Energy Storage System Optimization

This paper presents a degradation-cost-aware optimization framework for multi-string battery energy storage systems, emphasizing the impact of inhomogeneous subsystem-level aging in operational decision-making. We evaluate four scenarios for an energy arbitrage scenario, that vary in model precision and treatment of aging costs. Key performance metrics include operational revenue, power schedule mismatch, missed revenues, capacity losses, and revenue generated per unit of capacity loss. Our analysis reveals that ignoring heterogeneity of subunits may lead to infeasible dispatch plans and reduced revenues. In contrast, combining accurate representation of degraded subsystems and the consideration of aging costs in the objective function improves operational accuracy and economic efficiency of BESS with heterogeneous aged subunits. The fully informed scenario, which combines aging-cost-aware optimization with precise string-level modeling, achieves 21% higher revenue per unit of SOH loss compared to the baseline scenario. These findings highlight that modeling aging heterogeneity is not just a technical refinement but may become a crucial enabler for maximizing both short-term profitability and long-term asset value in particular for long BESS usage scenarios.

eess.SY

Evaluating the Impact of Model Accuracy for Optimizing Battery Energy Storage Systems

This study investigates two models of varying complexity for optimizing intraday arbitrage energy trading of a battery energy storage system using a model predictive control approach. Scenarios reflecting different stages of the system's lifetime are analyzed. The findings demonstrate that the equivalent-circuit-model-based non-linear optimization model outperforms the simpler linear model by delivering more accurate predictions of energy losses and system capabilities. This enhanced accuracy enables improved operational strategies, resulting in increased roundtrip efficiency and revenue, particularly in systems with batteries exhibiting high internal resistance, such as second-life batteries. However, to fully leverage the model's benefits, it is essential to identify the correct parameters.

eess.SY

Time-dependent global sensitivity analysis of the Doyle-Fuller-Newman model

The Doyle-Fuller-Newman model is arguably the most ubiquitous electrochemical model in lithium-ion battery research. Since it is a highly nonlinear model, its input-output relations are still poorly understood. Researchers therefore often employ sensitivity analyses to elucidate relative parametric importance for certain use cases. However, some methods are ill-suited for the complexity of the model and appropriate methods often face the downside of only being applicable to scalar quantities of interest. We implement a novel framework for global sensitivity analysis of time-dependent model outputs and apply it to a drive cycle simulation. We conduct a full and a subgroup sensitivity analysis to resolve lowly sensitive parameters and explore the model error when unimportant parameters are set to arbitrary values. Our findings suggest that the method identifies insensitive parameters whose variations cause only small deviations in the voltage response of the model. By providing the methodology, we hope research questions related to parametric sensitivity for time-dependent quantities of interest, such as voltage responses, can be addressed more easily and adequately in simulative battery research and beyond.

cond-mat.mtrl-sci

The Influence of Frequency Containment Reserve Flexibilization on the Economics of Electric Vehicle Fleet Operation

In recent years, the market for frequency containment reserve (FCR) has become a relevant source of revenue for stationary battery storage systems in Germany. During this period, prices for FCR have decreased, while the market has become increasingly flexible with shorter service periods and lower minimum power requirements. This flexibility makes the market attractive for pools of electric vehicles (EVs). Their idle times are now often longer than FCR service periods, providing the opportunity to earn additional revenue. In this paper, multi-year measurement data from 22 commercial EVs are used to develop a simulation model for FCR commercialization. In addition, the driving logbooks of more than 460 vehicles from different commercial fleets are analyzed. Based on our simulations, the impact of FCR flexibilization on the economics of an EV pool is analyzed using the German FCR market design from 2011 to 2020. It is shown that depending on the fleet, especially the recent change in service periods from one week to four hours generates the largest increase in available pool power. Further reductions in FCR service periods will like produce minor benefits, as idle times are often longer than service periods. Overall, the increase in flexibility greatly offsets the decreasing FCR prices and leads to higher revenues for most fleets analyzed. According to our model, revenues of about 250 EUR/a to 400 EUR/a could have been achieved per EV in the German FCR market in 2020.

eess.SY