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Andreas M. Menzel

Publications and source records attributed to Andreas M. Menzel.

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Tuned, driven, and active soft matter

One characteristic feature of soft matter systems is their strong response to external stimuli. As a consequence they are comparatively easily driven out of their ground state and out of equilibrium, which leads to many of their fascinating properties. Here, we review illustrative examples. This review is structured by an increasing distance from the equilibrium ground state. On each level, examples of increasing degree of complexity are considered. In detail, we first consider systems that are quasi-statically tuned or switched to a new state by applying external fields. These are common liquid crystals, liquid crystalline elastomers, or ferrogels and magnetic elastomers. Next, we concentrate on systems steadily driven from outside e.g. by an imposed flow field. In our case, we review the reaction of nematic liquid crystals, of bulk-filling periodically modulated structures such as block copolymers, and of localized vesicular objects to an imposed shear flow. Finally, we focus on systems that are "active" and "self-driven". Here our range spans from idealized self-propelled point particles, via sterically interacting particles like granular hoppers, via microswimmers such as self-phoretically driven artificial Janus particles or biological microorganisms, via deformable self-propelled particles like droplets, up to the collective behavior of insects, fish, and birds. As we emphasize, similarities emerge in the features and behavior of systems that at first glance may not necessarily appear related. We thus hope that our overview will further stimulate the search for basic unifying principles underlying the physics of these soft materials out of their equilibrium ground state.

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Bridging from particle to macroscopic scales in uniaxial magnetic gels

Connecting the different length scales of characterization is an important, but often very tedious task for soft matter systems. Here we carry out such a procedure for the theoretical description of anisotropic uniaxial magnetic gels. The so-far undetermined material parameters in a symmetry-based macroscopic hydrodynamic-like description are determined starting from a simplified mesoscopic particle-resolved model. This mesoscopic approach considers chain-like aggregates of magnetic particles embedded in an elastic matrix. Our procedure provides an illustrative background to the formal symmetry-based macroscopic description. There are presently other activities to connect such mesoscopic models as ours with more microscopic polymer-resolved approaches; together with these activities, our study complements a first attempt of scale-bridging from the microscopic to the macroscopic level in the characterization of magnetic gels.

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Structural control of elastic moduli in ferrogels and the importance of non-affine deformations

One of the central appealing properties of magnetic gels and elastomers is that their elastic moduli can reversibly be adjusted from outside by applying magnetic fields. The impact of the internal magnetic particle distribution on this effect has been outlined and analyzed theoretically. In most cases, however, affine sample deformations are studied and often regular particle arrangements are considered. Here we challenge these two major simplifications by a systematic approach using a minimal dipole-spring model. Starting from different regular lattices, we take into account increasingly randomized structures, until we finally investigate an irregular texture taken from a real experimental sample. On the one hand, we find that the elastic tunability qualitatively depends on the structural properties, here in two spatial dimensions. On the other hand, we demonstrate that the assumption of affine deformations leads to increasingly erroneous results the more realistic the particle distribution becomes. Understanding the consequences of the assumptions made in the modeling process is important on our way to support an improved design of these fascinating materials.

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Tunable dynamic response of magnetic gels: impact of structural properties and magnetic fields

Ferrogels and magnetic elastomers feature mechanical properties that can be reversibly tuned from outside through magnetic fields. Here we concentrate on the question how their dynamic response can be adjusted. The influence of three factors on the dynamic behavior is demonstrated using appropriate minimal models: first, the orientational memory imprinted into one class of the materials during their synthesis; second, the structural arrangement of the magnetic particles in the materials; and third, the strength of an external magnetic field. To illustrate the latter point, structural data are extracted from a real experimental sample and analyzed. Understanding how internal structural properties and external influences impact the dominant dynamical properties helps to design materials that optimize the requested behavior.

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A deformable microswimmer in a swirl: capturing and scattering dynamics

Inspired by the classical Kepler and Rutherford problem, we investigate an analogous set-up in the context of active microswimmers: the behavior of a deformable microswimmer in a swirl flow. First we identify new steady bound states in the swirl flow and analyze their stability. Second we study the dynamics of a self-propelled swimmer heading towards the vortex center, and we observe the subsequent capturing and scattering dynamics. We distinguish between two major types of swimmers, those that tend to elongate perpendicularly to the propulsion direction and those that pursue a parallel elongation. While the first ones can get caught by the swirl, the second ones were always observed to be scattered, which proposes a promising escape strategy. This offers a route to design artificial microswimmers that show the desired behavior in complicated flow fields. It should be straightforward to verify our results in a corresponding quasi-two-dimensional experiment using self-propelled droplets on water surfaces.

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Magnetomechanical response of bilayered magnetic elastomers

Magnetic elastomers are appealing materials from an application point of view: they combine the mechanical softness and deformability of polymeric substances with the addressability by external magnetic fields. In this way, mechanical deformations can be reversibly induced and elastic moduli can be reversibly adjusted from outside. So far, mainly the behavior of single-component magnetic elastomers and ferrogels has been studied. Here, we go one step further and analyze the magnetoelastic response of a bilayered material composed of two different magnetic elastomers. It turns out that, under appropriate conditions, the bilayered magnetic elastomer can show a strongly amplified deformational response in comparison to a single-component material. Furthermore, a qualitatively opposite response can be obtained, i.e.\ a contraction along the magnetic field direction (as opposed to an elongation in the single-component case). We hope that our results will further stimulate experimental and theoretical investigations directly on bilayered magnetic elastomers, or, in a further hierarchical step, on bilayered units embedded in yet another polymeric matrix.

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Active crystals and their stability

A recently introduced active phase field crystal model describes the formation of ordered resting and traveling crystals in systems of self-propelled particles. Increasing the active drive, a resting crystal can be forced to perform collectively ordered migration as a single traveling object. We demonstrate here that these ordered migrating structures are linearly stable. In other words, during migration, the single crystalline texture together with the globally ordered collective motion is preserved even on large length scales. Furthermore, we consider self-propelled particles on a substrate that are surrounded by a thin fluid film. We find that in this case the resulting hydrodynamic interactions can destabilize the order.

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Effective Cahn-Hilliard equation for the phase separation of active Brownian particles

The kinetic separation of repulsive active Brownian particles into a dense and a dilute phase is analyzed using a systematic coarse-graining strategy. We derive an effective Cahn-Hilliard equation on large length and time scales, which implies that the separation process can be mapped onto that of passive particles. A lower density threshold for clustering is found, and using our approach we demonstrate that clustering first proceeds via a hysteretic nucleation scenario and above a higher threshold changes into a spinodal-like instability. Our results are in agreement with particle-resolved computer simulations and can be verified in experiments of artificial or biological microswimmers.

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Unidirectional laning and migrating cluster crystals in confined self-propelled particle systems

One standard approach to describe the collective behaviour of self-propelled particles is the Vicsek model: point-like self-propelled particles tend to align their migration directions to the ones of their nearer neighbours at each time-step. Here we use a variant of the Vicsek model that includes pairwise repulsive interactions. Confining the system between parallel walls can qualitatively change its appearance: a laning state can emerge that is different from the ones previously reported. All lanes show on average the same migration direction of the contained particles with a finite separation distance between the lanes. Furthermore, in certain parameter ranges we observe collectively migrating clusters that arrange in an approximately hexagonal way. We suggest that the mechanism behind these regular textures is an overreaction in the alignment mechanism. Considering the more realistic scenario of non-point-like particles in the presence of confining surfaces is generally important for the comparison to experimental systems.

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Differently Shaped Hard Body Colloids in Confinement: From passive to active particles

We review recent progress in the theoretical description of anisotropic hard colloidal particles. The shapes considered range from rods and dumbbells to rounded cubes, polyhedra and to biaxial particles with arbitrary shape. Our focus is on both static and dynamical density functional theory and on computer simulations. We describe recent results for the structure, dynamics and phase behaviour in the bulk and in various confining geometries, e.g. established by two parallel walls which reduce the dimensionality of the system to two dimensions. We also include recent theoretical modelling for active particles, which are autonomously driven by some intrinsic motor, and highlight their fascinating nonequilibrium dynamics and collective behaviour.

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Dynamics of a deformable active particle under shear flow

The motion of a deformable active particle in linear shear flow is explored theoretically. Based on symmetry considerations, in two spatial dimensions, we propose coupled nonlinear dynamical equations for the particle position, velocity, deformation, and rotation. In our model, both, passive rotations induced by the shear flow as well as active spinning motions, are taken into account. Our equations reduce to known models in the two limits of vanishing shear flow and vanishing particle deformability. For varied shear rate and particle propulsion speed, we solve the equations numerically and obtain a manifold of different dynamical modes including active straight motion, periodic motions, motions on undulated cycloids, winding motions, as well as quasi-periodic and chaotic motions induced at high shear rates. The types of motion are distinguished by different characteristics in the real-space trajectories and in the dynamical behavior of the particle orientation and its deformation. Our predictions can be verified in experiments on self-propelled droplets exposed to a linear shear flow.

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Traveling and resting crystals in active systems

A microscopic field theory for crystallization in active systems is proposed which unifies the phase-field-crystal model of freezing with the Toner-Tu theory for self-propelled particles. A wealth of different active crystalline states are predicted and characterized. In particular, for increasing strength of self-propulsion, a transition from a resting crystal to a traveling crystalline state is found where the particles migrate collectively while keeping their crystalline order. Our predictions, which are verifiable in experiments and in particle-resolved computer simulations, provide a starting point for the design of new active materials.

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Soft deformable self-propelled particles

In this work we investigate the collective behavior of self-propelled particles that deform due to local pairwise interactions. We demonstrate that this deformation alone can induce alignment of the velocity vectors. The onset of collective motion is analyzed. Applying a Gaussian-core repulsion between the particles, we find a transition to disordered non-collective motion under compression. We here explain that this reflects the reentrant fluid behavior of the general Gaussian-core model now applied to a self-propelled system. Truncating the Gaussian potential can lead to cluster crystallization or more disordered cluster states. For intermediate values of the Gaussian-core potential we for the first time observe laning for deformable self-propelled particles. Finally, without the core potential, but including orientational noise, we connect our description to the Vicsek approach for self-propelled particles with nematic alignment interactions.

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Collective motion of binary self-propelled particle mixtures

In this study, we investigate the phenomenon of collective motion in binary mixtures of self-propelled particles. We consider two particle species, each of which consisting of pointlike objects that propel with a velocity of constant magnitude. Within each species, the particles try to achieve polar alignment of their velocity vectors, whereas we analyze the cases of preferred polar, antiparallel, as well as perpendicular alignment between particles of different species. Our focus is on the effect that the interplay between the two species has on the threshold densities for the onset of collective motion and on the nature of the solutions above onset. For this purpose, we start from suitable Langevin equations in the particle picture, from which we derive mean field equations of the Fokker-Planck type and finally macroscopic continuum field equations. We perform particle simulations of the Langevin equations, linear stability analyses of the Fokker-Planck and macroscopic continuum equations, and we numerically solve the Fokker-Planck equations. Both, spatially homogeneous and inhomogeneous solutions are investigated, where the latter correspond to stripe-like flocks of collectively moving particles. In general, the interaction between the two species reduces the threshold density for the onset of collective motion of each species. However, this interaction also reduces the spatial organization in the stripe-like flocks. The most interesting behavior is found for the case of preferred perpendicular alignment between different species. There, a competition between polar and truly nematic orientational ordering of the velocity vectors takes place within each particle species. Finally, depending on the alignment rule for particles of different species and within certain ranges of particle densities, identical and inverted spatial density profiles can be found for the two particle species.

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Density and concentration field description of nonperiodic structures

We propose a simple nonlocal energy functional that is suitable for the continuum field characterization of nonperiodic and localized textures. The phenomenological functional is based on the pairwise direction-dependent interaction of field gradients that are separated by a fixed distance. In an appendix, we describe the numerical minimization of our functional. On that basis, we investigate the kinetic evolution of thread-like stripe patterns that are created by the functional when we start from an initially disordered state. At later stages, we find a coarse-graining that shows the same scaling behavior as was obtained for the Cahn-Hilliard equation. In fact, the Cahn-Hilliard model is contained in our characterization as a limiting case. A slight modification of our model omits this coarse-graining and leads to nonperiodic stripe phases. For the latter case, we investigate the temporal evolution of the defects (end points) of the thread-like stripes. In view of possible applications of this functional, we discuss a possible characterization of polymeric systems and vesicles. The statistics of the growth of the thread-like structures is compared to the case of step-growth polymerization reactions. Furthermore, we demonstrate that the functional may be applied for the study of vesicles in a continuum field description. Basic features, such as the tendency of tank-treading in simple shear flows and parachute folding in pipe flows, are reproduced.

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The effect of Coulombic friction on spatial displacement statistics

The phenomenon of Coulombic friction enters the stochastic description of dry friction between two solids and the statistic characterization of vibrating granular media. Here we analyze the corresponding Fokker-Planck equation including both velocity and spatial components, exhibiting a formal connection to a quantum mechanical harmonic oscillator in the presence of a delta potential. Numerical solutions for the resulting spatial displacement statistics show a crossover from exponential to Gaussian displacement statistics. We identify a transient intermediate regime that exhibits multiscaling properties arising from the contribution of Coulombic friction. The possible role of these effects during observations in diffusion experiments is shortly discussed.

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