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Andrew Palmer

Publications and source records attributed to Andrew Palmer.

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Deterministic single-electron trapping on solid neon using engineered dielectric surface geometry

Levitating electron qubit on the surface of solid neon has recently emerged as a promising and intrinsically noise-resilient platform for quantum information processing. Their ultra-clean, inert environment suppresses conventional decoherence pathways associated with lattice disorder, charge traps, and nuclear-spin baths that limit coherence in semiconductor qubits. Yet, uncontrolled surface features such as bumps, valleys, and electrode-defined gaps can bind electrons unintentionally, contributing charge noise and inducing spin-orbit coupling mediated decoherence. To address this challenge, we propose an engineered interface in which a dielectric layer is deposited beneath the solid neon to provide an atomically smooth template, eliminating surface-roughness induced trapping. By selectively etching this dielectric layer at desired qubit locations, deterministic potential minima can be engineered to reliably capture electrons while suppressing unwanted surface bound states. We perform large-scale Schrodinger and Poisson simulation to compare the existing and proposed strategies of electron trapping on neon, obtaining good agreement with recent experimental measurements.

quant-ph

Characterizing Neon Thin Film Growth with an NbTiN Superconducting Resonator Array

Electrons levitating above the surface of solid neon have recently emerged as a promising platform for high-quality qubits. The morphology and uniformity of the neon growth in these systems is crucial for qubit performance in a scalable architecture. Here we report on the controlled growth and characterization of thin solid neon films using multiplexed superconducting microwave resonators. By monitoring changes in the resonant frequency and internal quality factor ($Q_i$) of an array of frequency multiplexed quarter-wave coplanar waveguide resonators, we quantify the spatial uniformity of the film. A pulsed gas deposition protocol near the neon triple point results in repeatable film formation, generating measurable shifts in frequency and variations in $Q_i$ across the resonator array. Notably, introducing a post-deposition anneal at 12 K for one hour improves the film homogeneity, as shown by the reduced resonator-to-resonator variance in frequency and $Q_i$, consistent with enhanced wetting. These results demonstrate resonator-based metrology as an in-situ tool for characterising neon film growth, directly supporting the development of electron on inert quantum solid qubit platforms.

cond-mat.mes-hall

Analyzing Learned Molecular Representations for Property Prediction

Advancements in neural machinery have led to a wide range of algorithmic solutions for molecular property prediction. Two classes of models in particular have yielded promising results: neural networks applied to computed molecular fingerprints or expert-crafted descriptors, and graph convolutional neural networks that construct a learned molecular representation by operating on the graph structure of the molecule. However, recent literature has yet to clearly determine which of these two methods is superior when generalizing to new chemical space. Furthermore, prior research has rarely examined these new models in industry research settings in comparison to existing employed models. In this paper, we benchmark models extensively on 19 public and 16 proprietary industrial datasets spanning a wide variety of chemical endpoints. In addition, we introduce a graph convolutional model that consistently matches or outperforms models using fixed molecular descriptors as well as previous graph neural architectures on both public and proprietary datasets. Our empirical findings indicate that while approaches based on these representations have yet to reach the level of experimental reproducibility, our proposed model nevertheless offers significant improvements over models currently used in industrial workflows.

cs.LG

Viscosity of Earth's Outer Core

A viscosity profile across the entire fluid outer core is found by interpolating between measured boundary values, using a differential form of the Arrhenius law governing pressure and temperature dependence. The discovery that both the retrograde and prograde free core nutations are in free decay (Palmer and Smylie, 2005) allows direct measures of viscosity at the top of the outer core, while the reduction in the rotational splitting of the two equatorial translational modes of the inner core allows it to be measured at the bottom. We find 2,371 plus/minus 1,530 Pa.s at the top and 1.247 plus/minus 0.035 x 10^11 Pa.s at the bottom. Following Brazhkin (1998) and Brazhkin and Lyapin (2000) who get 10^2 Pa.s at the top, 10^11 Pa.s at the bottom, by an Arrhenius extrapolation of laboratory experiments, we use a differential form of the Arrhenius law to interpolate along the melting temperature curve to find a viscosity profile across the outer core. We find the variation to be closely log-linear between the measured boundary values. The close agreement of the boundary values of viscosity, found by Arrhenius extrapolation of laboratory experiments, with those found from the free core nutations, and the inner core translational modes, suggests that core flows are laminar and that the returned viscosities are measures of their molecular values. This would not be the case in the presence of the vigorous turbulent convection sometimes postulated by dynamo theorists. The local Ekman number is found to range from 10^-2 at the bottom of the outer core to 10^-10 at the top. Except in the very lower part of the outer core, Ekman numbers are in the range 10^-4 to 10^-5, or below, in which the laminar flows of numerical dynamos and laboratory rotating fluids experiments occur.

physics.geo-ph