arXiv subjects

Andrii V. Bodnaruk

Publications and source records attributed to Andrii V. Bodnaruk.

5 recordsLinked to original sources

arXiv2026

Magnetic properties and charge transport mechanisms in oxygen-deficient HfxZr1-xO2-y nanoparticles

Study of nanoscale hafnia-zirconia physical properties is the key topic in fundamental and applied science. However, charge transport mechanisms and magnetic properties of hafnia-zirconia nanoparticles are very poorly studied both theoretically and experimentally. In this work we observed a superparamagnetic-like and superparaelectric-like response of ultra-small hafnia-zirconia nanoparticles prepared by the solid-state organonitrate synthesis. The EPR spectra of hafnia-zirconia nanopowders reveal the presence of paramagnetic defect centers, which may be hafnium and/or zirconium ions, which trapped an electron near an oxygen vacancy and changed their valence state from the non-paramagnetic +4 to the paramagnetic +3 state. The Raman spectra indicate the decisive role of surface defects, presumably oxygen vacancies, for all studied Zr compositions.At the same time the EELS analysis does not reveal any noticeable concentration of magnetic impurities in the hafnia-zirconia nanopowders, and the X-ray diffraction analysis reveals the dominant presence of the orthorhombic phase. We observed that the quasi-static relative dielectric permittivity of the hafnia-zirconia nanopowders overcomes 10^6 - 10^7 and related the colossal values with the superparaelectric state of the nanoparticles cores induced by the flexo-electro-chemical strains. It has been found that ultra-small hafnia-zirconia nanoparticles reveal posistor effect and relatively large values of accumulated charge. Thus, obtained results open the way for creation of silicon-compatible ferroics oxygen-deficient hafnia-zirconia nanoparticles with superparamagnetic and superparaelectric properties, which may be used in advanced FETs and electronic logic elements.

cond-mat.mtrl-sci↗

arXiv2025

Coexistence of Ferroelectric and Relaxor-like Phases in a Multiferroic Solid Solution (1-x)Pb(Fe$_{1/2}$Nb$_{1/2}$)O$_3$-xPbMnO$_3$

Experimental and theoretical studies of unusual polar, dielectric and magnetic properties of room temperature multiferroics, such as perovskites Pb(Fe$_{1/2}$Nb$_{1/2}$)O$_3$ (PFN) and Pb(Fe$_{1/2}$Ta$_{1/2}$)O$_3$ (PFT), are very important. We study the phase composition, dielectric, ferroic properties of the solid solutions PFN and PFT substituted with 5, 10, 15, 20 and 30 % of Mn ions prepared by the solid-state synthesis. The XRD analysis confirmed the perovskite structure of sintered ceramics. Electric measurements revealed the ferroelectric-type hysteresis of electric charge in pure PFN ceramics and in PFN ceramics substituted with (10 - 30)% of Mn. At the same time, the PFN-5% Mn ceramics did not show any ferroelectric properties due to very high conductivity.Temperature dependences of the dielectric permittivity of PFN-10% Mn and PFN-15% Mn ceramics have two pronounced maxima, one of which is relatively sharp and has a weak frequency dispersion; another is diffuse and has a strong frequency dispersion. A further increase in the Mn content up to 20% leads to the right shift in the paraelectric-ferroelectric phase transition temperature, as well as to the strong suppression of the second wide maximum, which transforms into a small diffuse shoulder. An increase in the Mn substitution up to 30% leads to a significant decrease in the dielectric permittivity, left shift of its maximum, and induces a pronounced frequency dispersion of the paraelectric-ferroelectric transition temperature, which is inherent to relaxor-like ferroelectrics.Comparison of the model with experiments reveal the coexistence of the ordered ferroelectric-like and disordered relaxor-like phases in the multiferroic solid solutions PFN-Mn and PFT-Mn.

cond-mat.mtrl-sci↗

arXiv2024

Temperature-Induced Hexagonal-Orthorhombic Phase Transition in Lutetium Ferrite Nanoparticles

The X-ray diffraction, Raman and infrared spectroscopies and magnetic measurements were used to explore the correlated changes of the structure, lattice dynamics and magnetic properties of the LuFeO3 nanoparticles, which appear in dependence on their sintering temperature. We revealed a gradual substitution of the hexagonal phase by the orthorhombic phase in the nanoparticles, which sintering temperature increases from 700 C to 1100 C. The origin and stability of the hexagonal phase in the LuFeO3 nanoparticles is of the special interest, because the nanoparticle in the phase can be a room-temperature multiferroic with a weak ferromagnetic and pronounced structural and ferroelectric long-range ordering, while the antiferromagnetic and nonpolar orthorhombic phase is more stable in the bulk LuFeO3. To define the ranges of the hexagonal phase stability, we determine the bulk and interface energy densities of different phases from the comparison of the Gibbs model with experimental results. Using the Gibbs model parameters, we predict the influence of size effects and temperature on the structural and polar properties of the LuFeO3 nanoparticles. Analysis of the obtained results shows that the combination of the X-ray diffraction, Raman and infrared spectroscopy, magnetic measurements and theoretical modelling of structural and polar properties allows to establish the interplay between the phase composition, lattice dynamics and multiferroic properties of the LuFeO3 nanoparticles prepared in different conditions.

cond-mat.mtrl-sci↗

arXiv2018

Readout of field induced magnetic anisotropy in a magnetoactive elastomer

It is shown that in external magnetic fields, a uniaxial magnetic anisotropy comes into being in a magnetoactive elastomer (MAE). The magnitude of the induced uniaxial anisotropy grows with the increasing external magnetic field. The filler particles are immobilized in the matrix if the MAE sample is cooled below 220 K, where the anisotropy can be read out. The cooling of the sample is considered as an alternative methodological approach to the experimental investigation of the magnetized state of MAEs. The appearance of magnetic anisotropy in MAE is associated with restructuring of the filler during magnetization, which leads to an additional effective field felt by the magnetization. It is found that the magnitude of the effective magnetic anisotropy constant of the MAE is approximately two times larger than its effective shear modulus in the absence of magnetic field. It is proposed that the experimentally observed large (about 40) ratio of the magnetic anisotropy constant of the filler to the shear modulus of the matrix deserves attention for the explanation of magnetic and magnetoelastic properties of MAEs. It may lead to additional rigidity of the elastic subsystem increasing the shear modulus of the composite material through the magnetomechanical coupling.

cond-mat.mtrl-sci↗

arXiv2018

Temperature-dependent magnetic properties of a magnetoactive elastomer: immobilization of the soft-magnetic filler

Magnetic properties of a magnetoactive elastomer (MAE) filled with μm-sized soft-magnetic iron particles have been experimentally studied in the temperature range between 150 K and 310 K. By changing the temperature, the elastic modulus of the elastomer matrix was modified and it was possible to obtain magnetization curves for an invariable arrangement of particles in the sample as well as in the case when the particles were able to change their position within the MAE under the influence of magnetic forces. At low (less than 220 K) temperatures, when the matrix becomes rigid, the magnetization of the MAE does not show a hysteresis behavior and it is characterized by a negative value of the Rayleigh constant. At room temperature, when the polymer matrix is compliant, a magnetic hysteresis exists and exhibits local maxima of the field dependence of the differential magnetic susceptibility. The appearance of these maxima is explained by the elastic resistance of the matrix to the displacement of particles under the action of magnetic forces.

cond-mat.mtrl-sci↗