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Andrij Kuzmak

Publications and source records attributed to Andrij Kuzmak.

4 recordsLinked to original sources

Quantum Hamiltonian simulation of linearised Euler equations in complex geometries

Quantum computing promises exponential improvements in solving large systems of partial differential equations (PDE), which forms a bottleneck in high-resolution simulations of, among others, computational fluid dynamics (CFD) in aerospace applications and weather forecasting. One approach is via mapping classical PDE problems to a quantum Hamiltonian evolution, for which recently an explicit quantum circuit construction has been shown in simple cases, allowing proof-of-concept execution on quantum processors. Here we extended this method to more complex and practically relevant cases. We first demonstrate how arbitrary complex-shaped geometrical obstacles with Dirichlet, Neumann or mixed boundary conditions can be introduced in the quantum representations of elementary difference operators used to implement the PDE, either directly or using Linear Combination of Unitaries (LCU). We provide their explicit and efficient circuit constructions, and analyze the Trotter errors and asymptotic gate complexities, which in the Dirichlet case do not grow compared to the free space equation. Using these methods we then derive quantum circuits for the linearized Euler equations in the presence of a background fluid flow and obstacles, both in the conservative and non-conservative regimes. We illustrate our results by simulating the obtained quantum circuits for different boundary conditions and geometries, comparing their error to a classical finite difference scheme.

quant-ph

Optimising nanoporous supercapacitors for heat-to-electricity conversion

Innovative ways of harnessing sustainable energy are needed to meet the world's ever-increasing energy demands. Supercapacitors may contribute, as they can convert waste heat to electricity through cyclic charging and discharging at different temperatures. Herein, we use an analytically-solvable model of a cylindrical pore filled with a single file of ions to identify optimal conditions for heat-to-electricity conversion with supercapacitors. We consider Stirling and Ericsson-like charging cycles and show that the former or latter yields more work when a supercapacitor operates under charge or voltage limitations, respectively. Both cycles yield the most work for pores almost as narrow as the size of the ions they contain, as is the case for energy storage with supercapacitors. In contrast to energy storage, which can be maximised by ionophobic pores, such pores do not yield the best heat-to-electricity conversion, independently of the applied potential. Instead, we find that for a given pore size, a moderately ionophilic pore harvests more work than ionophobic and strongly ionophilic pores.

cond-mat.soft

Capacitive energy storage in single-file pores: Exactly-solvable models and simulations

Understanding charge storage in low-dimensional electrodes is crucial for developing novel ecologically friendly devices for capacitive energy storage and conversion, water desalination, etc. Exactly-solvable models allow in-depth analyses and essential physical insights into the charging mechanisms. So far, however, such analytical approaches have been mainly limited to lattice models. Herein, we develop a versatile, exactly-solvable, one-dimensional off-lattice model for charging single-file pores. Unlike the lattice model, this model shows an excellent quantitative agreement with three-dimensional Monte Carlo simulations. With analytical calculations and simulations, we show that the differential capacitance can be bell-shaped (one peak), camel-shaped (two peaks), or have four peaks. Transformations between these capacitance shapes can be induced by changing pore ionophilicity, cation-anion size asymmetry, or by adding solvent. We find that the camel-shaped capacitance, characteristic of dilute electrolytes, appears for strongly ionophilic pores with high ion densities, which we relate to charging mechanisms specific to narrow pores. We also derive a large-voltage asymptotic expression for the capacitance, showing that the capacitance decays to zero as the inverse square of the voltage, $C \sim u^{-2}$. This dependence follows from hard-core interactions and is not captured by the lattice model.

cond-mat.soft

Probing the geometry of two-qubit state space by evolution

We derive an explicit expressions for geometric description of state manifold obtained from evolution governed by a three parameter family of Hamiltonians covering most cases related to real interacting two-qubit systems. We discuss types of evolution in terms of the defining parameters and obtain relevant explicit description of the pure state spaces and their Remannian geometry with the Fubini-Study metric . In particular, there is given an analysis of the modification of known geometry of quantum state manifold by the linear noncommuting perturbation of the Hamiltonian. For families of states resulting from the unitary evolution, we characterize a degree of entanglement using the squared concurrence as its measure.

quant-ph