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Angelo M. Gomes

Publications and source records attributed to Angelo M. Gomes.

3 recordsLinked to original sources

Giant Magnetic-Field-Induced Strain in Ni2MnGa-based polycrystal

Ferromagnetic Ni2MnGa-based alloys play an important role in technological fields, such as smart actuators, magnetic refrigeration and robotics. The possibility of obtaining large non-contact deformation induced by an external perturbation is one of its key strengths for applications. However, the search for materials with low cost, practical fabrication procedures and large signal output under small perturbing fields still poses challenges. In the present study we demonstrate that by judicial choice of substitution on the Mn site, an abrupt magnetostructural transition from a paramagnetic austenite phase to a ferromagnetic martensite one can be tuned to close to room temperature achieving large and reproducible strains. The required magnetic field to induce the strain varies from small values, as low as 0.25 T for 297.4 K and 1.6% of strain, to 8 T for 305 K and 2.6% of strain. Our findings point to encouraging possibilities for application of shape memory alloys in relatively inexpensive, scalable polycrystalline materials.

cond-mat.mtrl-sci

Magnetocaloric effect in Ni2(Mn,Cu)Ga0.84Al0.16 Heusler alloys

Polycrystalline Heusler compounds Ni2Mn0.75Cu0.25Ga0.84Al0.16 with a martensitic transition between ferromagnetic phases and Ni2Mn0.70Cu0.30Ga0.84Al0.16 with a magnetostructural transformation were investigated by magnetization and thermal measurements, both as a function of temperature and magnetic field. The compound Ni2Mn0.75Cu0.25Ga0.84Al0.16 presents a large magnetocaloric effect among magnetically aligned structures and its causes are explored. In addition, Ni2Mn0.70Cu0.30Ga0.84Al0.16 shows very high, although irreversible, entropy and adiabatic temperature change at room temperature under a magnetic field change 0-1 T. Improved refrigerant capacity is also a highlight of the 30% Cu material when compared to similar Ni2MnGa-based alloys.

cond-mat.mtrl-sci

Experimentally correlating thermal hysteresis and phase compatibility in multifunctional Heusler alloys

Thermal hysteresis is recognized as one of the main drawbacks for cyclical applications of magnetocaloric and ferromagnetic shape memory materials with first order transformations. As such, the challenge is to develop strategies that improve the compatibility between the phases involved in the transitions and study its influence on thermal hysteresis. With this purpose, we explore the thermal, structural and magnetic properties of the Ni2Mn1-xCuxGa0.84Al0.16 Heusler alloys. The alloys present a thermal hysteresis reduction of ~60% when the Cu content in the compound varies from x = 0.10 to x = 0.25, with a minimum hysteresis width of 6 K being achieved. We applied the geometric non-linear theory of martensite to address the phase compatibility, quantified by the parameter lambda2, the middle eigenvalue of the transformation stretch tensor, and found that the minimum of hysteresis is associated with a better crystallographic compatibility (lambda2 closer to 1) between the austenite and martensite phases. In addition, we show that the valley-like properties of hysteresis found in the Ni2Mn1-xCuxGa0.84Al0.16 compounds is present in several other alloys in the literature. These results provide new pathways to understand as well as to masters the phase compatibility and ultimately achieve a low thermal hysteresis in multifunctional Heusler alloys.

cond-mat.mtrl-sci